Templated-synthesisofhighlyefficientCO2sorbentmaterialOutlines1.Background2.Templatemethod3.Templated-synthesismaterial4.Conclusion1.Background2.Templatemethod3.Templated-synthesismaterial4.Conclusion1.BackgroundCCS---CarbondioxideCaptureandStorageB.Lietal.AppliedEnergy102(2013)1439–14471.BackgroundAdvantageslargecapacitiesfastkineticsmetaloxidezeolitecarbon-basedmaterialmetal-organicframeworksincludingIn

broadsense,templatemeansastencil,patternoroverlayusedingraphicartsandsewingtoreplicateletters,shapesordesigns.Innanoporousregime,templaterepresentsthatparticularmolecule,whichhelpstogenerateordesignporosityinthematrix.

Atemplateactsasstructuredirectingagent(SDA)inthesynthesisofporousmaterials.2.Templatemethod2.TemplatemethodInbroadsense,templatemeansastencil,patternoroverlayusedingraphicartsandsewingtoreplicateletters,shapesordesigns.Innanoporousregime,templaterepresentsthatparticularmolecule,whichhelpstogenerateordesignporosityinthematrix.

Atemplateactsasstructuredirectingagent(SDA)inthesynthesisofporousmaterials.2.TemplatemethodAtemplateisastructure(usuallyorganic,thoughhardtemplatemaybeinorganic)aroundwhichamaterial(ofteninorganic)nucleatesandgrowsina“skin-tight”fashion,sothatupontheremovalofthetemplatingstructure,itsgeometricandelectroniccharacteristicsarereplicatedinthe(inorganic)materials.2.1hardtemplatemethod2.2softtemplatemethodYusukeYamauchietal.Chem.AsianJ.2008,3,664–6762.Templatemethod2.1Hardtemplate

Fig.1

Acompilationofimagesforcertaincategoriesofhardtemplates.a)plantstem;b)freeze-driedstarch'c)apolymericcolloidalcrystal;d)a3Dorderedmacroporousstructure;e)apolyurethanefoam;f)anAAOmembraneg)aninsituNaClcrystaltemplate;h)apolymerproducedfromanAOOmembrane;i)individualcolloidalspheres;j)rod-shapednanoparticles.D.Petkovichetal.Chem.Soc.Rev.,2013,42,3721--3739Templatematerials2.1.1SynthesisofHardtemplateN.V.Roik,L.A.Belyakova/JournalofSolidStateChemistry207(2013)194–202MCM-41silicasFig.2

Sol–gelsynthesisofMCM-41andCl-MCM-41silicas.Fig.3

Postsyntheticchemicalmodificationoftemplate-filledMCM-41andCl-MCM-41with(3-chloropropyl)triethoxysilaneand1,2-ethylenediamineinvaporphaseN.V.Roik,L.A.Belyakova/JournalofSolidStateChemistry207(2013)194–202Fig.4ТЕМimagesofporestructureofMCM-41(а),Cl-МСМ-41(b),ClVP-МСМ-41(c),NH2VP-Cl-МСМ-41(d),andNH2VP-ClVP-МСМ-41(e),enhancement1×SynthesisofHardtemplateMCM-41silicas2.1.2hardtemplatingprocessFig.5Schemesdetailingthehardtemplatingprocess.Left:Anexampleofhardtemplatingconductedusinganinfiltrationprocess.Right:Anexampleofhardtemplatingconductedviaacoatingprocess.D.Petkovichetal.Chem.Soc.Rev.,2013,42,3721--3739HardTemplatingwithInfiltrationHardTemplatingwithCoating2.2SofttemplateN.Paletal.AdvancesinColloidandInterfaceScience(2013)21–41Fig.6SchematicrepresentationofvariouscategoriesofsofttemplatesTemplateclassification2.2.1softtemplatingprocessD.Petkovichetal.Chem.Soc.Rev.,2013,42,3721--3739Fig.7

Schemesdetailingthesofttemplatingprocess..Top:thesequenceofstepsincooperativeassemblyMiddle:thesequenceofstepsinliquidcrystaltemplatingBottom:thesequenceofstepsinevaporation-inducedself-assembly.2.2.2Interactionpathways(A)Theamphiphilicsurfactantmoleculecanarrangeitselfatthesurfaceofthewatersuchthatthepolarpartinteractswiththewater;(B)thenon-polarpartisheldabovethesurface;(C)moleculescanalloweachcomponenttointeractwithitsfavoredenvironment.N.Paletal.AdvancesinColloidandInterfaceScience(2013)21–41(A)Theamphiphilicsurfactantmoleculecanarrangeitselfatthesurfaceofthewatersuchthatthepolarpartinteractswiththewater;(B)thenon-polarpartisheldabovethesurface;(C)moleculescanalloweachcomponenttointeractwithitsfavoredenvironment.Fig.8Surfactantmoleculeanditsbehaviorinaqueousmedia.

Fig.9Syntheticpathwaysoforganic–inorganichybridmesoporoussilica:1.Post-synthesisfunctionalizationorpostgrafting,2.Co-condensationorinsitugrafting,and3.Organicbridgedperodicmesoporoussilca.2.2.3

?N.Paletal.AdvancesinColloidandInterfaceScience(2013)21–41123Fig.10Surfactantdirectedsynthesisofamesoporousphenol–formaldehydepolymerfromoligomerbuildingblocks.Mesoporouscarbonisobtainedaftercarbonization.N.Paletal.AdvancesinColloidandInterfaceScience(2013)21–412.2.3

?N.Paletal.AdvancesinColloidandInterfaceScience(2013)21–41Fig.5.Differenttypesofmetalsurfactantinteractions2.2.4AffectingfactorsofsofttemplatetemplatemoleculetemperatureroleofsolventsionsinthereactionmediaconcentrationofsurfactantsN.Paletal.AdvancesinColloidandInterfaceScience(2013)21–41surfactantsconcentrationtemplatemoleculetemperatureroleofsolventsionsinthereactionmedia2.2.4AffectingfactorsofsofttemplateN.Paletal.AdvancesinColloidandInterfaceScience(2013)21–41Fig.11SilicaprecursoratvariablepHcondition.PHvariate2.2.4AffectingfactorsofsofttemplateFig.12Differenttypesofsurfactantstructures.N.Paletal.AdvancesinColloidandInterfaceScience(2013)21–41surfactantstructures3.1.1TemplatesynthesisM.Brodaetal.Adv.Mater.2012,24,3059–3064Fig.13SchematicoftheindividualsynthesisstepstoproducetheCa-based,Al2O3stabilizedCO2sorbent.reactionequationreactionstepsFig.14

SEMimagesofsynthesizedmaterials:(a)purecarbongel,(b)Ca:Al_90:10_80℃_5min,(c)Ca:Al_90:10_80℃_10min,(d)Ca:Al_90:10_80℃_1h,(e)Ca:Al_90:10_80℃_3days,(f)Ca:Al_90:10_500℃,(g,h)Ca:Al_90:TemplatesynthesisM.Brodaetal.Adv.Mater.2012,24,3059–3064SEMImagesFig.15

CO2uptakeof