4224422424224224《機(jī)學(xué)應(yīng)程》寫習(xí)一取反1.鹵代應(yīng)(1)CH與Cl在光照下反應(yīng)_________________________________________________。(2)苯液溴在鐵屑催化下反應(yīng)(3)苯溶液中加入過量濃溴水2.硝化應(yīng)由苯制硝基苯：______________________________________________________。由甲苯制TNT：______________________________________________________3.磺化應(yīng)由苯和濃硫酸共熱制苯磺酸：。4.醇與鹵共下應(yīng)例如：乙醇與氫溴酸反應(yīng)_________________________________________________5.醇分間水醚例如：由乙醇制乙醚。6.鹵代的解例如：溴乙烷與溶液共熱：___________________________________________。7.酯的解(1)乙乙酯與稀HSO共：。(2)乙乙酯與溶共熱：_____________________________________________。8.酯化應(yīng)(1)乙與乙醇在濃硫酸下共熱制乙酸乙酯_____________________________________(2)苯酸、甲醇、濃硫酸三者混合后共熱。二加反1.烯烴加C加：_______________________________________________________。C加HO：_______________________________________________________。C通溴水中；現(xiàn)象為：。1222222222222222223715xyxyk2.炔烴加(1)CH與足量H加成：。(2)CH通入溴水中。(3)CH水化法制乙醛____________________________________________________。(4)CH與制乙烯：。3.芳香的H

例如：苯加成H：_________________________________________________。乙加氫：。丙(CHCOCH)加氫：。油的化(或化)：_________________________________________________。三消反1.部分代的去應(yīng)結(jié)構(gòu)要為：__________________________條件為_____________________。例如：溴乙烷、乙醇NaOH三混合共熱：。2.部分的去應(yīng)結(jié)構(gòu)要為：___________________________；件為__________________________。例如：由醇制乙烯。(2)符分子組成為、能發(fā)生消去反應(yīng)的物質(zhì)_種其結(jié)構(gòu)簡式為：__________________________________________________________________________四氧反

1.有機(jī)物燃反(1)(H完全燃燒的通式為____________________________________________天然氣的完全燃燒：____________________________________________________。乙烯完全燃燒：_______________________________；象為_____________________。乙炔完全燃燒：______________________________；現(xiàn)象為______________________。④苯完全燃燒：；象為：。(2)含衍生物CH)完燃燒的通式為_______________________________________。例如：酒精作燃料完全燃燒：。葡萄糖的生理氧化：。22.得氧失方的化反(1)乙氧化法制乙醛。(2)由醇制乙醛：。(3)乙發(fā)生銀鏡反應(yīng)。(4)乙與新制氫氧化銅懸濁液共熱________________________________________。(5)乙與氧氣的催化氧化________________________________________________。(6)葡糖發(fā)生銀鏡反應(yīng)：。(7)葡糖與新制氫氧化銅懸濁液共熱。(8)由二醇制乙二醛。(9)由二醛制乙二酸。(10)苯甲醇制苯甲醛。五還反1.加成H

注：能加氫的幾類結(jié)構(gòu)_____________________________________._______________________________________________________________________。六水反1.鹵代的解如：1,2―二乙烷的水解反應(yīng)___________________________。2.酯的解應(yīng)阿斯匹林

與溶共熱_____________________________。(2)化合物

與NaOH溶共_________________________。(3)硬酸甘油酯在稀硫酸催化下的水解反應(yīng)______________________________________。(4)硬酸甘油酯在NaOH溶液中的水解反應(yīng)______________________________________。3.二糖多與白的水反蔗糖的水解反應(yīng)。淀粉的水解反應(yīng)。33610536361053684332222(3)纖素的水解反應(yīng)________________________________________________________。七酯反由酸與乙二醇制二乙酸乙二酯_____________________________________________。由油與硝酸制三硝酸甘油酯_______________________________________________乙醇與乙二酸發(fā)生完全酯化反應(yīng)制乙二酸二酯。由(CH制CH的化反應(yīng)________________________________由(CH制酯CH)的化反應(yīng)_____________________________。由(CH制乳酸_____________________________________________乙酸與乙二醇酯化生成聚酯_______________________________________________對(duì)二甲酸與乙二醇制聚酯：。由維素制硝酸纖維。八加與聚應(yīng)由烯制聚乙烯__________________________________________________________。由乙烯制聚氯乙烯______________________________________________________。苯與甲醛反應(yīng)制酚醛樹脂：。由醛制“人造象牙_____________________________________________________。nCHCH(OH)COOH+HOCHCOOH→__________________+____甲丙烯酸甲酯的加聚反應(yīng)：。7.2―甲基1,3―二烯的加聚反應(yīng)。乙的加聚反應(yīng)為：_______________________________________________________。九其有反由電石與飽和食鹽水作用制乙炔_____________________________________________鈉與乙醇的置換反應(yīng)___________________