PAGE3關(guān)于金屬有機(jī)骨架的研究文獻(xiàn)綜述1.1金屬有機(jī)框架及其衍生物金屬有機(jī)骨架（MOFs）是一種由過(guò)渡金屬離子和有機(jī)配體通過(guò)配位鍵組成的多孔有機(jī)化合物ADDINEN.CITEADDINEN.CITE.DATA[48,49]。它因其不同的金屬離子的配體而具有不同的排列，所以有較大的比表面積、豐富的孔隙體系和可控的化學(xué)特性，因此在吸附ADDINEN.CITEADDINEN.CITE.DATA[50,51]傳感ADDINEN.CITE<EndNote><Cite><Author>Kreno</Author><Year>2012</Year><RecNum>59</RecNum><DisplayText><styleface="superscript">[52]</style></DisplayText><record><rec-number>59</rec-number><foreign-keys><keyapp="EN"db-id="0f9r9eszqzvs02edwtpptwwwxw2e5sasa5r0"timestamp="1575288064">59</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Kreno,L.E.</author><author>Leong,K.</author><author>Farha,O.K.</author><author>Allendorf,M.</author><author>VanDuyne,R.P.</author><author>Hupp,J.T.</author></authors></contributors><auth-address>DepartmentofChemistry,NorthwesternUniversity,2145SheridanRoad,Evanston,Illinois60208,USA.</auth-address><titles><title>Metal-organicframeworkmaterialsaschemicalsensors</title><secondary-title>ChemRev</secondary-title></titles><periodical><full-title>ChemRev</full-title></periodical><pages>1105-25</pages><volume>112</volume><number>2</number><keywords><keyword>ChemistryTechniques,Analytical/instrumentation/*methods</keyword><keyword>Electrodes</keyword><keyword>LuminescentAgents/*chemistry</keyword><keyword>OrganometallicCompounds/*chemistry</keyword><keyword>ParticleSize</keyword><keyword>SurfaceProperties</keyword></keywords><dates><year>2012</year><pub-dates><date>Feb8</date></pub-dates></dates><isbn>1520-6890(Electronic) 0009-2665(Linking)</isbn><accession-num>22070233</accession-num><urls><related-urls><url>/pubmed/22070233</url></related-urls></urls><electronic-resource-num>10.1021/cr200324t</electronic-resource-num></record></Cite></EndNote>[52]、催化ADDINEN.CITEADDINEN.CITE.DATA[53,54]和儲(chǔ)能ADDINEN.CITEADDINEN.CITE.DATA[5,8,49]等方面有著廣泛的應(yīng)用。IRMOF首先由Yaghi等人提出，這是一種由對(duì)苯二甲酸和過(guò)渡金屬Zn構(gòu)成的二維配位化合物（MOF-5)ADDINEN.CITE<EndNote><Cite><Author>Jin</Author><Year>2019</Year><RecNum>75</RecNum><DisplayText><styleface="superscript">[55]</style></DisplayText><record><rec-number>75</rec-number><foreign-keys><keyapp="EN"db-id="0f9r9eszqzvs02edwtpptwwwxw2e5sasa5r0"timestamp="1575366843">75</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Jin,Jun</author><author>Zheng,Yun</author><author>Huang,Shao-zhuan</author><author>Sun,Ping-ping</author><author>Srikanth,Narasimalu</author><author>Kong,LingBing</author><author>Yan,Qingyu</author><author>Zhou,Kun</author></authors></contributors><titles><title>Directlyanchoring2DNiCometal–organicframeworksonfew-layerblackphosphorusforadvancedlithium-ionbatteries</title><secondary-title>JournalofMaterialsChemistryA</secondary-title></titles><periodical><full-title>JournalofMaterialsChemistryA</full-title></periodical><pages>783-790</pages><volume>7</volume><number>2</number><section>783</section><dates><year>2019</year></dates><isbn>2050-7488 2050-7496</isbn><urls></urls><electronic-resource-num>10.1039/c8ta09327j</electronic-resource-num></record></Cite></EndNote>[55]。MOF根據(jù)形貌可以分為一維、二維、三維。一維MOFs朝著空間一個(gè)方向，常見(jiàn)的的結(jié)構(gòu)有棒狀、針狀A(yù)DDINEN.CITEADDINEN.CITE.DATA[55,56]。二維MOFs是朝著空間內(nèi)一個(gè)無(wú)限延展，常見(jiàn)形狀有超薄納米片ADDINEN.CITEADDINEN.CITE.DATA[3,55,57,58]。三維MOFs在空間上三個(gè)方向發(fā)展形狀各異，常見(jiàn)的類(lèi)型有球形、方形、沸石型ADDINEN.CITEADDINEN.CITE.DATA[53,59]等等。相比于其他MOFs,二維MOF具有更大的比表面積為暴露更多的活性位點(diǎn)做了充足的準(zhǔn)備，同時(shí)二維平面具有更快速的電子轉(zhuǎn)移通達(dá)ADDINEN.CITEADDINEN.CITE.DATA[2,60]。然而，MOFs的配位鍵相對(duì)不穩(wěn)定，其骨架在化學(xué)或機(jī)械條件下表現(xiàn)出較低的穩(wěn)定性，這可能是MOFs工業(yè)化發(fā)展的主要障礙ADDINEN.CITE<EndNote><Cite><Author>Liu</Author><Year>2018</Year><RecNum>85</RecNum><DisplayText><styleface="superscript">[8]</style></DisplayText><record><rec-number>85</rec-number><foreign-keys><keyapp="EN"db-id="0f9r9eszqzvs02edwtpptwwwxw2e5sasa5r0"timestamp="1575383366">85</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Liu,Lin</author><author>Yan,Yang</author><author>Cai,Zihe</author><author>Lin,Shengxuan</author><author>Hu,Xiaobin</author></authors></contributors><titles><title>Growth-OrientedFe-BasedMOFsSynergizedwithGrapheneAerogelsforHigh-PerformanceSupercapacitors</title><secondary-title>AdvancedMaterialsInterfaces</secondary-title></titles><periodical><full-title>AdvancedMaterialsInterfaces</full-title></periodical><volume>5</volume><number>8</number><section>1701548</section><dates><year>2018</year></dates><isbn>21967350</isbn><urls></urls><electronic-resource-num>10.1002/admi.201701548</electronic-resource-num></record></Cite><Cite><Author>Liu</Author><Year>2018</Year><RecNum>85</RecNum><record><rec-number>85</rec-number><foreign-keys><keyapp="EN"db-id="0f9r9eszqzvs02edwtpptwwwxw2e5sasa5r0"timestamp="1575383366">85</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Liu,Lin</author><author>Yan,Yang</author><author>Cai,Zihe</author><author>Lin,Shengxuan</author><author>Hu,Xiaobin</author></authors></contributors><titles><title>Growth-OrientedFe-BasedMOFsSynergizedwithGrapheneAerogelsforHigh-PerformanceSupercapacitors</title><secondary-title>AdvancedMaterialsInterfaces</secondary-title></titles><periodical><full-title>AdvancedMaterialsInterfaces</full-title></periodical><volume>5</volume><number>8</number><section>1701548</section><dates><year>2018</year></dates><isbn>21967350</isbn><urls></urls><electronic-resource-num>10.1002/admi.201701548</electronic-resource-num></record></Cite></EndNote>[8]。為了有利于MOFs的發(fā)展，提高骨架的穩(wěn)定性已經(jīng)成為一個(gè)主要的焦點(diǎn)。例如，控制合成和后改性處理。例如，ZhouADDINEN.CITE<EndNote><Cite><Author>Zhou</Author><Year>2016</Year><RecNum>11</RecNum><DisplayText><styleface="superscript">[61]</style></DisplayText><record><rec-number>11</rec-number><foreign-keys><keyapp="EN"db-id="0f9r9eszqzvs02edwtpptwwwxw2e5sasa5r0"timestamp="1537674341">11</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Zhou,Y.</author><author>Mao,Z.</author><author>Wang,W.</author><author>Yang,Z.</author><author>Liu,X.</author></authors></contributors><auth-address>DepartmentofMaterialsPhysics,SchoolofPhysicsandOptoelectronicEngineering,NanjingUniversityofInformationScience&Technology,219NingliuRoad,Nanjing,Jiangsu210044,China. KeyLaboratoryofFlexibleElectronics(KLOFE)&InstituteofAdvancedMaterials(IAM),NationalJiangsuSynergisticInnovationCenterforAdvancedMaterials(SICAM),NanjingTechUniversity(NanjingTech),30SouthPuzhuRoad,Nanjing,Jiangsu211816,China.</auth-address><titles><title>In-SituFabricationofGrapheneOxideHybridNi-BasedMetal-OrganicFramework(Ni-MOFs@GO)withUltrahighCapacitanceasElectrochemicalPseudocapacitorMaterials</title><secondary-title>ACSApplMaterInterfaces</secondary-title></titles><periodical><full-title>ACSApplMaterInterfaces</full-title></periodical><pages>28904-28916</pages><volume>8</volume><number>42</number><keywords><keyword>graphiteoxide</keyword><keyword>metal-organicframework(MOFs)</keyword><keyword>nanocomposites</keyword><keyword>nickel</keyword><keyword>pseudocapacitor</keyword></keywords><dates><year>2016</year><pub-dates><date>Oct26</date></pub-dates></dates><isbn>1944-8252(Electronic) 1944-8244(Linking)</isbn><accession-num>27696813</accession-num><urls><related-urls><url>/pubmed/27696813</url></related-urls></urls><electronic-resource-num>10.1021/acsami.6b10640</electronic-resource-num></record></Cite></EndNote>[61]等人通過(guò)控制加入GO的量控制Ni-MOF的結(jié)構(gòu)形貌；GaoADDINEN.CITE<EndNote><Cite><Author>Gao</Author><Year>2018</Year><RecNum>15</RecNum><DisplayText><styleface="superscript">[56]</style></DisplayText><record><rec-number>15</rec-number><foreign-keys><keyapp="EN"db-id="0f9r9eszqzvs02edwtpptwwwxw2e5sasa5r0"timestamp="1544783583">15</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Gao,S.</author><author>Sui,Y.</author><author>Wei,F.</author><author>Qi,J.</author><author>Meng,Q.</author><author>Ren,Y.</author><author>He,Y.</author></authors></contributors><auth-address>SchoolofMaterialsScienceandEngineering,ChinaUniversityofMiningandTechnology,Xuzhou221116,People'sRepublicofChina. SchoolofMaterialsScienceandEngineering,ChinaUniversityofMiningandTechnology,Xuzhou221116,People'sRepublicofChina.Electronicaddress:hyz0217@.</auth-address><titles><title>Dandelion-likenickel/cobaltmetal-organicframeworkbasedelectrodematerialsforhighperformancesupercapacitors</title><secondary-title>JColloidInterfaceSci</secondary-title></titles><periodical><full-title>JColloidInterfaceSci</full-title></periodical><pages>83-90</pages><volume>531</volume><keywords><keyword>Ni-MOF</keyword><keyword>Ni/Co-MOF</keyword><keyword>Supercapacitors</keyword></keywords><dates><year>2018</year><pub-dates><date>Dec1</date></pub-dates></dates><isbn>1095-7103(Electronic) 0021-9797(Linking)</isbn><accession-num>30025331</accession-num><urls><related-urls><url>/pubmed/30025331</url></related-urls></urls><electronic-resource-num>10.1016/j.jcis.2018.07.044</electronic-resource-num></record></Cite></EndNote>[56]等人通過(guò)加入雙金屬離子得到了蒲公英狀的NiCo-MOF；ZhouADDINEN.CITE<EndNote><Cite><Author>Zhu</Author><Year>2018</Year><RecNum>12</RecNum><DisplayText><styleface="superscript">[49]</style></DisplayText><record><rec-number>12</rec-number><foreign-keys><keyapp="EN"db-id="0f9r9eszqzvs02edwtpptwwwxw2e5sasa5r0"timestamp="1539164594">12</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Zhu,G.</author><author>Wen,H.</author><author>Ma,M.</author><author>Wang,W.</author><author>Yang,L.</author><author>Wang,L.</author><author>Shi,X.</author><author>Cheng,X.</author><author>Sun,X.</author><author>Yao,Y.</author></authors></contributors><auth-address>CollegeofMaterialsScienceandEngineering,SichuanUniversity,Chengdu610064,Sichuan,China.yaoyd523@163.com.</auth-address><titles><title>Aself-supportedhierarchicalCo-MOFasasupercapacitorelectrodewithultrahigharealcapacitanceandexcellentrateperformance</title><secondary-title>ChemCommun(Camb)</secondary-title></titles><periodical><full-title>ChemCommun(Camb)</full-title></periodical><pages>10499-10502</pages><volume>54</volume><number>74</number><dates><year>2018</year><pub-dates><date>Sep13</date></pub-dates></dates><isbn>1364-548X(Electronic) 1359-7345(Linking)</isbn><accession-num>30159557</accession-num><urls><related-urls><url>/pubmed/30159557</url></related-urls></urls><electronic-resource-num>10.1039/c8cc03669a</electronic-resource-num></record></Cite></EndNote>[49]等人通過(guò)加入泡沫鎳，在泡沫鎳長(zhǎng)出了刀刃型的Co-MOF大多數(shù)原始MOFs的電導(dǎo)率和穩(wěn)定性較差，嚴(yán)重限制了其在儲(chǔ)能領(lǐng)域的應(yīng)用。近年來(lái)，越來(lái)越多的研究對(duì)MOF進(jìn)行了研究，如MOFs熱解獲得活性氧化物ADDINEN.CITEADDINEN.CITE.DATA[53,62-65]、氮化物ADDINEN.CITE<EndNote><Cite><Author>Dilpazir</Author><Year>2018</Year><RecNum>42</RecNum><DisplayText><styleface="superscript">[63]</style></DisplayText><record><rec-number>42</rec-number><foreign-keys><keyapp="EN"db-id="0f9r9eszqzvs02edwtpptwwwxw2e5sasa5r0"timestamp="1555416832">42</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Dilpazir,Sobia</author><author>He,Hongyan</author><author>Li,Zehui</author><author>Wang,Meng</author><author>Lu,Peilong</author><author>Liu,Rongji</author><author>Xie,Zhujun</author><author>Gao,Denglei</author><author>Zhang,Guangjin</author></authors></contributors><titles><title>CobaltSingleAtomsImmobilizedN-DopedCarbonNanotubesforEnhancedBifunctionalCatalysistowardOxygenReductionandOxygenEvolutionReactions</title><secondary-title>ACSAppliedEnergyMaterials</secondary-title></titles><periodical><full-title>ACSAppliedEnergyMaterials</full-title></periodical><pages>3283-3291</pages><volume>1</volume><number>7</number><dates><year>2018</year></dates><isbn>2574-0962 2574-0962</isbn><urls></urls><electronic-resource-num>10.1021/acsaem.8b00490</electronic-resource-num></record></Cite></EndNote>[63]和硫化物ADDINEN.CITEADDINEN.CITE.DATA[66]等等。例如SuADDINEN.CITEADDINEN.CITE.DATA[67]等人通過(guò)將沸石型ZIF-8得到了多孔的ZnO用于電解水析氫反應(yīng)；DilpazirADDINEN.CITE<EndNote><Cite><Author>Dilpazir</Author><Year>2018</Year><RecNum>42</RecNum><DisplayText><styleface="superscript">[63]</style></DisplayText><record><rec-number>42</rec-number><foreign-keys><keyapp="EN"db-id="0f9r9eszqzvs02edwtpptwwwxw2e5sasa5r0"timestamp="1555416832">42</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Dilpazir,Sobia</author><author>He,Hongyan</author><author>Li,Zehui</author><author>Wang,Meng</author><author>Lu,Peilong</author><author>Liu,Rongji</author><author>Xie,Zhujun</author><author>Gao,Denglei</author><author>Zhang,Guangjin</author></authors></contributors><titles><title>CobaltSingleAtomsImmobilizedN-DopedCarbonNanotubesforEnhancedBifunctionalCatalysistowardOxygenReductionandOxygenEvolutionReactions</title><secondary-title>ACSAppliedEnergyMaterials</secondary-title></titles><periodical><full-title>ACSAppliedEnergyMaterials</full-title></periodical><pages>3283-3291</pages><volume>1</volume><number>7</number><dates><year>2018</year></dates><isbn>2574-0962 2574-0962</isbn><urls></urls><electronic-resource-num>10.1021/acsaem.8b00490</electronic-resource-num></record></Cite></EndNote>[63]等人將ZIF-67做犧牲模板經(jīng)過(guò)雙氰胺(DCD)處理，合成了新型Co原子固定碳納米管，在酸性電解質(zhì)下觀察到良好的催化能力；HeADDINEN.CITE<EndNote><Cite><Author>He</Author><Year>2019</Year><RecNum>169</RecNum><DisplayText><styleface="superscript">[68]</style></DisplayText><record><rec-number>169</rec-number><foreign-keys><keyapp="EN"db-id="0f9r9eszqzvs02edwtpptwwwxw2e5sasa5r0"timestamp="1618144159">169</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>He,P.</author><author>Xie,Y.</author><author>Dou,Y.</author><author>Zhou,J.</author><author>Zhou,A.</author><author>Wei,X.</author><author>Li,J.R.</author></authors></contributors><auth-address>BeijingKeyLaboratoryforGreenCatalysisandSeparationandDepartmentofChemistryandChemicalEngineering,CollegeofEnvironmentalandEnergyEngineering,BeijingUniversityofTechnology,Beijing100124,P.R.China.</auth-address><titles><title>PartialSulfurizationofa2DMOFArrayforHighlyEfficientOxygenEvolutionReaction</title><secondary-title>ACSApplMaterInterfaces</secondary-title></titles><periodical><full-title>ACSApplMaterInterfaces</full-title></periodical><pages>41595-41601</pages><volume>11</volume><number>44</number><edition>2019/10/12</edition><keywords><keyword>electrocatalysis</keyword><keyword>hierarchicalstructure</keyword><keyword>metal-organicframeworks(MOFs)</keyword><keyword>oxygenevolutionreaction</keyword><keyword>partialsulfurization</keyword></keywords><dates><year>2019</year><pub-dates><date>Nov6</date></pub-dates></dates><isbn>1944-8252(Electronic) 1944-8244(Linking)</isbn><accession-num>31603301</accession-num><urls><related-urls><url>/pubmed/31603301</url></related-urls></urls><electronic-resource-num>10.1021/acsami.9b16224</electronic-resource-num></record></Cite></EndNote>[68]等人通過(guò)TAA部分硫化Ni-BDC陣列，Ni-BDC@NiS復(fù)合材料在電流密度為20mAcm-2時(shí)過(guò)電位為330mV，表現(xiàn)出最佳的電化學(xué)活性，優(yōu)于之前報(bào)道的大多數(shù)鎳基硫化物。1.2金屬有機(jī)框架及其衍生物在超級(jí)電容器中的應(yīng)用MOFs基的超級(jí)電容器應(yīng)用有四種不同的途徑:（1）利用原始MOF作為電極材料：（2）MOFs作為合成金屬化化物的犧牲模板;（3）高溫?zé)峤庵频枚嗫滋蓟衔铩＃?）利用原始MOF作為電極材料：自從DincaADDINEN.CITE<EndNote><Cite><Author>Díaz</Author><Year>2012</Year><RecNum>60</RecNum><DisplayText><styleface="superscript">[69]</style></DisplayText><record><rec-number>60</rec-number><foreign-keys><keyapp="EN"db-id="0f9r9eszqzvs02edwtpptwwwxw2e5sasa5r0"timestamp="1575290616">60</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Díaz,Raül</author><author>Orcajo,M.Gisela</author><author>Botas,JuanA.</author><author>Calleja,Guillermo</author><author>Palma,Jesús</author></authors></contributors><titles><title>Co8-MOF-5aselectrodeforsupercapacitors</title><secondary-title>MaterialsLetters</secondary-title></titles><periodical><full-title>MaterialsLetters</full-title></periodical><pages>126-128</pages><volume>68</volume><dates><year>2012</year></dates><isbn>0167577X</isbn><urls></urls><electronic-resource-num>10.1016/j.matlet.2011.10.046</electronic-resource-num></record></Cite></EndNote>[69]等人首先合成了高導(dǎo)電性的Ni3(HITP)2作為超級(jí)電容器的電極材料，表現(xiàn)出優(yōu)異的面積電容和循環(huán)穩(wěn)定性。ZhuADDINEN.CITE<EndNote><Cite><Author>Zhu</Author><Year>2018</Year><RecNum>12</RecNum><DisplayText><styleface="superscript">[49]</style></DisplayText><record><rec-number>12</rec-number><foreign-keys><keyapp="EN"db-id="0f9r9eszqzvs02edwtpptwwwxw2e5sasa5r0"timestamp="1539164594">12</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Zhu,G.</author><author>Wen,H.</author><author>Ma,M.</author><author>Wang,W.</author><author>Yang,L.</author><author>Wang,L.</author><author>Shi,X.</author><author>Cheng,X.</author><author>Sun,X.</author><author>Yao,Y.</author></authors></contributors><auth-address>CollegeofMaterialsScienceandEngineering,SichuanUniversity,Chengdu610064,Sichuan,China.yaoyd523@163.com.</auth-address><titles><title>Aself-supportedhierarchicalCo-MOFasasupercapacitorelectrodewithultrahigharealcapacitanceandexcellentrateperformance</title><secondary-title>ChemCommun(Camb)</secondary-title></titles><periodical><full-title>ChemCommun(Camb)</full-title></periodical><pages>10499-10502</pages><volume>54</volume><number>74</number><dates><year>2018</year><pub-dates><date>Sep13</date></pub-dates></dates><isbn>1364-548X(Electronic) 1359-7345(Linking)</isbn><accession-num>30159557</accession-num><urls><related-urls><url>/pubmed/30159557</url></related-urls></urls><electronic-resource-num>10.1039/c8cc03669a</electronic-resource-num></record></Cite></EndNote>[49]等人通過(guò)加入泡沫鎳，在泡沫鎳長(zhǎng)出了刀刃型的Co-MOF，所得的Co-MOF/NF在2MKOH中，2mAcm-2的比電容達(dá)到了13.6Fcm-2，超過(guò)了之前報(bào)道的MOF基材料。在電流密度為20mAcm-2時(shí)，該器件的導(dǎo)電率達(dá)到79.4%。以Co-MOF/NF為正電極、活性炭(AC)為負(fù)極的非對(duì)稱超級(jí)電容器(ASC)器件,該器件循環(huán)2000次后電容保持率為69.7%。（2）MOFs作為合成金屬化合物的犧牲模板：金屬有機(jī)骨架材料(MOF)利用其多孔的納米結(jié)構(gòu)和有限的金屬位，作為多用途的前驅(qū)體被廣泛應(yīng)用于制備各種功能納米材料(金屬氧化物ADDINEN.CITEADDINEN.CITE.DATA[17,70]、磷化物ADDINEN.CITE<EndNote><Cite><Author>Pan</Author><Year>2018</Year><RecNum>40</RecNum><DisplayText><styleface="superscript">[53]</style></DisplayText><record><rec-number>40</rec-number><foreign-keys><keyapp="EN"db-id="0f9r9eszqzvs02edwtpptwwwxw2e5sasa5r0"timestamp="1555416681">40</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Pan,Y.</author><author>Sun,K.</author><author>Liu,S.</author><author>Cao,X.</author><author>Wu,K.</author><author>Cheong,W.C.</author><author>Chen,Z.</author><author>Wang,Y.</author><author>Li,Y.</author><author>Liu,Y.</author><author>Wang,D.</author><author>Peng,Q.</author><author>Chen,C.</author><author>Li,Y.</author></authors></contributors><auth-address>DepartmentofChemistry,TsinghuaUniversity,Beijing100084,China. StateKeyLaboratoryofHeavyOilProcessing,CollegeofChemicalEngineering,ChinaUniversityofPetroleum(EastChina),Qingdao,Shandong266580,China. CollegeofChemistryandMaterialsScience,AnhuiNormalUniversity,Wuhu,Anhui241000,China.</auth-address><titles><title>Core-ShellZIF-8@ZIF-67-DerivedCoPNanoparticle-EmbeddedN-DopedCarbonNanotubeHollowPolyhedronforEfficientOverallWaterSplitting</title><secondary-title>JAmChemSoc</secondary-title></titles><periodical><full-title>JAmChemSoc</full-title></periodical><pages>2610-2618</pages><volume>140</volume><number>7</number><dates><year>2018</year><pub-dates><date>Feb21</date></pub-dates></dates><isbn>1520-5126(Electronic) 0002-7863(Linking)</isbn><accession-num>29341596</accession-num><urls><related-urls><url>/pubmed/29341596</url></related-urls></urls><electronic-resource-num>10.1021/jacs.7b12420</electronic-resource-num></record></Cite></EndNote>[53]和硫化物ADDINEN.CITEADDINEN.CITE.DATA[40,62])，這些材料通常具有優(yōu)異的電化學(xué)性能ADDINEN.CITE<EndNote><Cite><Author>Ou</Author><Year>2018</Year><RecNum>35</RecNum><DisplayText><styleface="superscript">[18]</style></DisplayText><record><rec-number>35</rec-number><foreign-keys><keyapp="EN"db-id="0f9r9eszqzvs02edwtpptwwwxw2e5sasa5r0"timestamp="1548060121">35</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Ou,X.</author><author>Wang,Y.</author><author>Lei,S.</author><author>Zhou,W.</author><author>Sun,S.</author><author>Fu,Q.</author><author>Xiao,Y.</author><author>Cheng,B.</author></authors></contributors><auth-address>SchoolofMaterialsScienceandEngineering,NanchangUniversity,Nanchang,Jiangxi330031,China.shjlei@.</auth-address><titles><title>Terephthalate-basedcobalthydroxide:anewelectrodematerialforsupercapacitorswithultrahighcapacitance</title><secondary-title>DaltonTrans</secondary-title></titles><periodical><full-title>DaltonTrans</full-title></periodical><pages>14958-14967</pages><volume>47</volume><number>42</number><dates><year>2018</year><pub-dates><date>Oct30</date></pub-dates></dates><isbn>1477-9234(Electronic) 1477-9226(Linking)</isbn><accession-num>30298882</accession-num><urls><related-urls><url>/pubmed/30298882</url></related-urls></urls><electronic-resource-num>10.1039/c8dt03231a</electronic-resource-num></record></Cite></EndNote>[18]。LiADDINEN.CITE<EndNote><Cite><Author>Li</Author><Year>2019</Year><RecNum>171</RecNum><DisplayText><styleface="superscript">[71]</style></DisplayText><record><rec-number>171</rec-number><foreign-keys><keyapp="EN"db-id="0f9r9eszqzvs02edwtpptwwwxw2e5sasa5r0"timestamp="1618149771">171</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Li,Shuting</author><author>Duan,Yanan</author><author>Teng,Ying</author><author>Fan,Na</author><author>Huo,Yuqiu</author></authors></contributors><titles><title>MOF-derivedtremelliformCo3O4/NiO/Mn2O3withexcellentcapacitiveperformance</title><secondary-title>AppliedSurfaceScience</secondary-title></titles><periodical><full-title>AppliedSurfaceScience</full-title></periodical><pages>247-254</pages><volume>478</volume><section>247</section><dates><year>2019</year></dates><isbn>01694332</isbn><urls></urls><electronic-resource-num>10.1016/j.apsusc.2019.01.140</electronic-resource-num></record></Cite></EndNote>[71]等人對(duì)CoNiMn-MOF采用簡(jiǎn)單的水熱法制備了晶狀Co3O4/NiO/Mn2O3。Co3O4/NiO/Mn2O3結(jié)合三組分的優(yōu)勢(shì)，由于協(xié)同效應(yīng)，表現(xiàn)出優(yōu)越的比電容和優(yōu)異的倍率性能。同時(shí)，采用rGO和Co3O4/NiO/Mn2O3分別作為正極和負(fù)極制備了非對(duì)稱超級(jí)電容器，該超級(jí)電容器具有優(yōu)異的能量密度和功率密度。這表明它在儲(chǔ)能方面具有廣闊的應(yīng)用前景。YilmazeADDINEN.CITEADDINEN.CITE.DATA[66]等人利用犧牲ZIF模板實(shí)現(xiàn)了鎳鈷層狀雙氫化物(NiCo-LDHs)向NiCo-LDH/Co9S8雜化體系的原位均勻晶體化學(xué)轉(zhuǎn)化。NiCo-LDH/Co9S8復(fù)合體系總體具有多體系的多孔結(jié)構(gòu)、豐富的氧化還原化學(xué)和高導(dǎo)電性基體。NiCo-LDH/Co9S8具有1653Fg-1的比電容。組成的非對(duì)稱電容器在8Ag-1下循環(huán)10000圈，依然保留90.9%的初始電容。（3）高溫?zé)峤庵频枚嗫滋蓟衔?。近年?lái)，基于高孔隙率和有機(jī)連接劑構(gòu)成的碳骨架，包括ZIFs在內(nèi)的MOFs被認(rèn)為是應(yīng)用于超級(jí)電容器的多孔碳的理想前驅(qū)體。此外，作為ZIFs特殊有機(jī)連接劑的咪唑含有氮元素，直接炭化后也能帶來(lái)?yè)诫s氮。因此，煅燒ZIFs已被證明是一種簡(jiǎn)單的合成N摻雜多孔碳材料的方法ADDINEN.CITE<EndNote><Cite><Author>Pan</Author><Year>2018</Year><RecNum>40</RecNum><DisplayText><styleface="superscript">[53]</style></DisplayText><record><rec-number>40</rec-number><foreign-keys><keyapp="EN"db-id="0f9r9eszqzvs02edwtpptwwwxw2e5sasa5r0"timestamp="1555416681">40</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Pan,Y.</author><author>Sun,K.</author><author>Liu,S.</author><author>Cao,X.</author><author>Wu,K.</author><author>Cheong,W.C.</author><author>Chen,Z.</author><author>Wang,Y.</author><author>Li,Y.</author><author>Liu,Y.</author><author>Wang,D.</author><author>Peng,Q.</author><author>Chen,C.</author><author>Li,Y.</author></authors></contributors><auth-address>DepartmentofChemistry,TsinghuaUniversity,Beijing100084,China. StateKeyLaboratoryofHeavyOilProcessing,CollegeofChemicalEngineering,ChinaUniversityofPetroleum(EastChina),Qingdao,Shandong266580,China. CollegeofChemistryandMaterialsScience,AnhuiNormalUniversity,Wuhu,Anhui241000,China.</auth-address><titles><title>Core-ShellZIF-8@ZIF-67-DerivedCoPNanoparticle-EmbeddedN-DopedCarbonNanotubeHollowPolyhedronforEfficientOverallWaterSplitting</title><secondary-title>JAmChemSoc</secondary-title></titles><periodical><full-title>JAmChemSoc</full-title></periodical><pages>2610-2618</pages><volume>140</volume><number>7</number><dates><year>2018</year><pub-dates><date>Feb21</date></pub-dates></dates><isbn>1520-5126(Electronic) 0002-7863(Linking)</isbn><accession-num>29341596</accession-num><urls><related-urls><url>/pubmed/29341596</url></related-urls></urls><electronic-resource-num>10.1021/jacs.7b12420</electronic-resource-num></record></Cite></EndNote>[53]。ZhangADDINEN.CITE<EndNote><Cite><Author>Pan</Author><Year>2018</Year><RecNum>40</RecNum><DisplayText><styleface="superscript">[53]</style></DisplayText><record><rec-number>40</rec-number><foreign-keys><keyapp="EN"db-id="0f9r9eszqzvs02edwtpptwwwxw2e5sasa5r0"timestamp="1555416681">40</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Pan,Y.</author><author>Sun,K.</author><author>Liu,S.</author><author>Cao,X.</author><author>Wu,K.</author><author>Cheong,W.C.</author><author>Chen,Z.</author><author>Wang,Y.</author><author>Li,Y.</author><author>Liu,Y.</author><author>Wang,D.</author><author>Peng,Q.</author><author>Chen,C.</author><author>Li,Y.</author></authors></contributors><auth-address>DepartmentofChemistry,TsinghuaUniversity,Beijing100084,China. StateKeyLaboratoryofHeavyOilProcessing,CollegeofChemicalEngineering,ChinaUniversityofPetroleum(EastChina),Qingdao,Shandong266580,China. CollegeofChemistryandMaterialsScience,AnhuiNormalUniversity,Wuhu,Anhui241000,China.</auth-address><titles><title>Core-ShellZIF-8@ZIF-67-DerivedCoPNanoparticle-EmbeddedN-DopedCarbonNanotubeHollowPolyhedronforEfficientOverallWaterSplitting</title><secondary-title>JAmChemSoc</secondary-title></titles><periodical><full-title>JAmChemSoc</full-title></periodical><pages>2610-2618</pages><volume>140</volume><number>7</number><dates><year>2018</year><pub-dates><date>Feb21</date></pub-dates></dates>