energycrisisWeNeedRenewableenergy！Environment

pollutionamaterialtorestoreit！WealsoNeedMetalOrganicFrameworks（MOFs）Teammembers：QinMengYeTingSongYixuanGaiLinlinMoJiameiLiuYongyingZhouJinlingLiQianruSunTianDuYinaCONTENTSynthetic

ChemistryofMaterials123IntroductionSynthesisofMOFsApplicationofMOFsIntroduction1Synthetic

ChemistryofMaterialsIntroductionmorethan20,000differentMOFsIntroductionSynthetic

ChemistryofMaterialsProperities:

intriguingtopologies

highersurfacearea

Designablechannelandfounctionalized

framworksIsoreticularMetal–

OrganicFramework(IRMOF)wasfabricatedbyYaghiOM,realizingthetransitionfromstaticmicroporousmaterialstotheperfectcrystalinemesoporousmaterials.19891995202319992023202320232023ThetopologytheorywasappliedtothecoordinationcompoundbyRobsonR.Thecoordinationcompoundwith2d

structure,

firstlynamedMOFs,

waspreparedbyYaghiOM.MOF-5withsimplecubicstructurewaspreparedbyYaghiOM.MIL-100

and

MIL-101materials

withmacroporousmolecularsievestructureweresynthesisedbyFérey’steam.MIL-53(X)withasuperiorperformanceingasseparationwassynthesisedbytheFérey’steam.ZeoliticImidazolateFrameworks(ZIFs)withexcellentthermalandchemicalstabilityweresynthesisedbyYaghiOM.TheconceptionofdiversefunctionalMetal-OrganicSkeletonmaterials(MVT-MOFS)wasputforward.IntroductionSynthetic

ChemistryofMaterialsSynthesis2SynthesisofMOFs3TraditionalMethod2Layer-by-LayerMethod3Microwave-assistedMethodSecondgrowthMethod41AqueoussolutionofmetalorganicsolventsolutionofligandmixedsolventofwaterandorganicTEXT

TraditionalMethodLayeringMethodJ.Choi,G.GillanEdward.Inorg.Chem.2023,44,7385.SolvothermalMethodMicrowaveassistedmethod(1)Dipolerotation(2)Collisiontakesplace(2)LocalheatingenergyefficiencyMOF-5Fig.1SEMimagesofMOF-5preparedunder(a)conventionalsolvothermalsynthesisand(b)microwaveheating.MicrowaveassistedmethodJ.S.Choi,W.J.Son,J.KimandW.S.Ahn,MicroporousMesoporousMater.2023,116,727–731crystallinityandmorphologyofMOF-5Conventionalheatingwasusedforcomparison.Layer-by-Layer

MethodFig.2Layer-by-layergrowthofHKUST-1thinfilmsonCOOH-terminatedsupport.

ThesubstrateisrepeatedlyimmersedinsolutionsofCu(OAc)2andH3BTC,withanintermediatewashingbetweensuccessivesteps.C.Munuera,O.Shekhah.,H.Wang,C.Woll.,C.Ocal.Phys.Chem.Chem.Phys.2023,10,7257.TEXTseedspre-coatedN.Stock,S.Biswas.ChemRev.2023;112(2):933-69.Seedspre-coated:(1)spin-ordip-coating(3)rubbing(2)directgrowth(4)Layer-by-layer(LBL)growth.Fig.4ComparisonbetweendirectandsecondarygrowthmethodsforthepreparationofMOFthinfilmsundersolvothermalconditions.SecondaryGrowth16TEXTTEXTFig.5

DRMsassistedgrowthofMOF-5onaflatsurface.Fig.6

DRMsusedforpositioningMOF-5onpatternedsupportsSecondaryGrowthFunctionalization(DRMs)2-Dimension3-DimensionSelectivecatalyticReductionAdvantagesP.Falcaro.etal.Nat.Commun.,2023,2,237-244.CrystalSecondaryGrowthApplication3ApplicationofMOFsMolecularTransportY.Ikezoe,G.Washino,T.Uemura,S.KitagawaandH.Matsui,Nat.Mater.,2023,11,1081–1085B.D.Gates,Q.Xu,M.Stewart,D.Ryan,C.G.WillsonandG.M.Whitesides,Chem.Rev.,2023,105,1171–1196LargesurfacetensionBigporousDevicesactuators;Sensors;targeteddruginjectionosmoticpumpingOpticsG.LuandJ.T.Hupp,J.Am.Chem.Soc.,2023,132,7832–7833C.-Y.Sun,X.-L.Wang,X.Zhang,C.Qin,P.Li,Z.-M.Su,D.-X.Zhu,G.-G.Shan,K.-Z.Shao,H.WuandJ.Li,Nat.Commun.,2023,4,2717C.-W.Kung,T.C.Wang,J.E.Mondloch,D.Fairen-Jimenez,D.M.Gardner,W.Bury,J.M.Klingsporn,J.C.Barnes,R.