頁(yè)摘要針對(duì)全球工業(yè)化進(jìn)程中CO2排放引發(fā)的溫室效應(yīng)問(wèn)題，本研究以剛性三蝶烯為構(gòu)筑基元，通過(guò)外交聯(lián)策略合成超交聯(lián)微孔聚合物(HCPs)，分別采用二甲醇縮甲醛（Dimethoxymethane，DMM）和1,4-對(duì)二氯芐（1,4-Bis（chloromethy）-benzene，DCBZ）構(gòu)建超交聯(lián)聚合物前驅(qū)體（HCP-DMM與HCP-DCBZ)，經(jīng)乙二胺（Ethylenediamine，EDA）氨基功能化改性，成功制備HCP-DMM-EDA與HCP-DMM-DCBZ兩種新型吸附材料。利用FT-IR來(lái)對(duì)HCP-DMM-EDA和HCP-DCBZ-EDA結(jié)構(gòu)進(jìn)行表征，二者的紅外光譜在1590cm-1左右區(qū)域都出現(xiàn)C-N鍵的特征吸收峰以及在3420cm-1區(qū)域都存在寬化的N-H鍵特征峰。表明氨基基團(tuán)在共聚物的骨架中HCP-DMM-EDA與HCP-DCBZ-EDA保存良好。對(duì)合成產(chǎn)物進(jìn)行XRD測(cè)試，得出所有樣品在5°–50°范圍內(nèi)僅呈現(xiàn)寬化的彌散峰（2θ=15.12°），未出現(xiàn)明顯尖銳特征峰，表明材料具有非晶態(tài)特征。氮?dú)馕?附測(cè)試結(jié)果表明，DCBZ交聯(lián)前驅(qū)體比表面積達(dá)1332.41m2/g，較DMM體系（409.94m2/g）提升225%，氨基化后仍保持959.57m2/g；DMM體系胺化后比表面積增至427.62m2/g，體現(xiàn)柔性交聯(lián)骨架的動(dòng)態(tài)結(jié)構(gòu)重組特性。在273K、1bar條件下，HCP-DCBZ-EDA的CO2吸附容量為2.22mmol/g，較DMM體系（1.94mmol/g）提升14.4%，驗(yàn)證了剛性交聯(lián)骨架與氨基修飾協(xié)同強(qiáng)化的物理-化學(xué)吸附機(jī)制。本研究闡明交聯(lián)劑剛性與孔結(jié)構(gòu)穩(wěn)定性的構(gòu)效關(guān)系，為高性能碳捕集材料的定向設(shè)計(jì)提供了新思路。關(guān)鍵詞：DMM；DCBZ；三蝶烯；氨基化修飾；N2/CO2吸附

ABSTRACTInordertosolvethegreenhouseeffectcausedbyCO2emissionsintheprocessofglobalindustrialization,thisstudysynthesizedsuper-cross-linkedmicroporouspolymers(HCPs)usingrigidtriptyceneasthebuildingblockandusingDimethoxymethane(DMM)and1,4-Bis(chloromethy)-benzene,respectively.DCBZ)toconstructsuper-crosslinkedpolymerprecursors(HCP-DMMandHCP-DCBZ),whichweremodifiedbyethylenediamine(EDA)aminofunctionalization,andtwonewadsorptionmaterials,HCP-DM-EDAandHCP-DMM-DCBZ,weresuccessfullyprepared.FT-IRwasusedtocharacterizethestructuresofHCP-DMM-EDAandHCP-DCBZ-EDA,andtheinfraredspectraofbothshowedcharacteristicabsorptionpeaksofC-Nbondsintheregionofabout1590cm-1andbroadenedcharacteristicpeaksofN-Hbondsintheregionof3420cm-1.Theresultsshowedthattheaminogroupswerewellpreservedinthebackboneofthecopolymers,HCP-DMM-EDAandHCP-DCBZ-EDA.XRDtestsofthesyntheticproductsshowedthatallsamplesshowedonlywideneddiffusionpeaks(2θ=15.12°)intherangeof5°–50°,andnoobvioussharpcharacteristicpeaksappeared,indicatingthatthematerialhadamorphouscharacteristics.Theresultsofnitrogenadsorption-detachmenttestshowedthatthespecificsurfaceareaofDCBZcross-linkedprecursorsreached1332.41m2/g,whichwas225%higherthanthatofDMMsystem(409.94m2/g),andremainedat959.57m2/gafteramination.ThespecificsurfaceareaoftheDMMsystemincreasedto427.62m2/gafteramination,reflectingthedynamicstructuralreorganizationcharacteristicsoftheflexiblecross-linkedframework.At273Kand1bar,theCO2adsorptioncapacityofHCP-DCBZ-EDAwas2.22mmol/g,whichwas14.4%higherthanthatofDMMsystem(1.94mmol/g),whichverifiedthephysico-chemicaladsorptionmechanismofrigidcross-linkedframeworkandaminomodification.Thisstudyclarifiesthestructure-activityrelationshipbetweentherigidityofthecrosslinkerandthestabilityoftheporestructure,andprovidesanewideaforthedirectionaldesignofhigh-performancecarboncapturematerials.Keywords:DMM;DCBZ;Triptycene;AminationModification;N2/CO2Adsorption

目錄前言 11.實(shí)驗(yàn)部分 21.1實(shí)驗(yàn)試劑與實(shí)驗(yàn)儀器 21.1.1實(shí)驗(yàn)試劑 21.1.2實(shí)驗(yàn)儀器 31.2三蝶烯的超交聯(lián)氨基化聚合物的制備 31.2.1交聯(lián)劑DMM型前驅(qū)體（HCP-DMM）合成 31.2.2交聯(lián)劑DCBZ型前驅(qū)體（HCP-DCBZ）合成 31.2.3氯甲基化反應(yīng) 31.2.3乙二胺氨基化修飾 41.3樣品的表征測(cè)試條件 41.3.1X射線衍射的測(cè)試條件 41.3.2傅里葉紅外光譜儀測(cè)試條件 41.3.3比表面積測(cè)試及對(duì)CO2/N2吸附測(cè)試條件 42結(jié)果 52.1材料X射線衍射的測(cè)試結(jié)果分析 52.2FT-IR測(cè)試結(jié)果分析 62.3材料的比表面積測(cè)試結(jié)果分析 72.4HCP-DMM-EDA與HCP-DCBZ-EDA對(duì)CO2/N2的吸附等溫線分析 83.總結(jié) 11參考文獻(xiàn) 12致謝 14前言隨著全球工業(yè)化進(jìn)程的迅猛發(fā)展，煤炭、石油等化石燃料的過(guò)度消耗導(dǎo)致大氣中二氧化碳濃度持續(xù)攀升，引發(fā)溫室效應(yīng)加劇、極端氣候頻發(fā)、冰川消融及海平面上升等一系列環(huán)境危機(jī)，嚴(yán)重威脅生態(tài)平衡與人類社會(huì)的可持續(xù)發(fā)展ADDINEN.CITE<EndNote><CiteExcludeYear="1"><Author>鄭貴濱</Author><RecNum>79</RecNum><DisplayText><styleface="superscript">[1]</style></DisplayText><record><rec-number>79</rec-number><foreign-keys><keyapp="EN"db-id="fawf9edt55z95zevsvjxa5sfrx9t9frsta25"timestamp="1746589810">79</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>鄭貴濱</author><author>李燕</author><author>吳卓</author></authors></contributors><auth-address>廣州大學(xué)地理科學(xué)與遙感學(xué)院;</auth-address><titles><title>面向碳中和目標(biāo)的廣州市土地利用優(yōu)化與碳儲(chǔ)量評(píng)估</title><secondary-title>環(huán)境科學(xué)</secondary-title></titles><periodical><full-title>環(huán)境科學(xué)</full-title></periodical><pages>1-15</pages><keywords><keyword>土地利用優(yōu)化</keyword><keyword>碳儲(chǔ)量</keyword><keyword>碳中和</keyword><keyword>FLUS-InVEST模型</keyword><keyword>廣州市</keyword></keywords><dates></dates><isbn>0250-3301</isbn><call-num>11-1895/X</call-num><urls><related-urls><url>/doi/10.13227/j.hjkx.202410257</url></related-urls></urls><electronic-resource-num>10.13227/j.hjkx.202410257</electronic-resource-num><remote-database-provider>Cnki</remote-database-provider></record></Cite></EndNote>[1]。國(guó)際能源署(IEA)的數(shù)據(jù)顯示，2023年，中國(guó)二氧化碳排放量達(dá)126億噸，同比增長(zhǎng)4.7%，其中能源燃燒排放增長(zhǎng)5.2%ADDINEN.CITE<EndNote><Cite><Author>劉帥</Author><Year>2025</Year><RecNum>27</RecNum><DisplayText><styleface="superscript">[2]</style></DisplayText><record><rec-number>27</rec-number><foreign-keys><keyapp="EN"db-id="fawf9edt55z95zevsvjxa5sfrx9t9frsta25"timestamp="1746179595">27</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>劉帥</author><author>楊丹輝</author></authors></contributors><auth-address>中國(guó)財(cái)政科學(xué)研究院宏觀經(jīng)濟(jì)研究中心;中國(guó)社會(huì)科學(xué)院工業(yè)經(jīng)濟(jì)研究所;</auth-address><titles><title>綠色稅制體系的改革方向與建構(gòu)路徑</title><secondary-title>齊魯學(xué)刊</secondary-title></titles><periodical><full-title>齊魯學(xué)刊</full-title></periodical><pages>108-122</pages><number>02</number><keywords><keyword>綠色稅制</keyword><keyword>全面深化改革</keyword><keyword>“雙碳目標(biāo)”</keyword><keyword>綠色發(fā)展</keyword></keywords><dates><year>2025</year></dates><isbn>1001-022X</isbn><call-num>37-1085/C</call-num><urls><related-urls><url>/kcms2/article/abstract?v=IP3-TJYmrEuoNHHuBdOav2OuMGe_VlCtNiYAyCkjR4PQS3QAw86ti9SF21_zxOgnf0AI3cnCEJnvmU_Zevs-tJ-t1XrE_7NTDNAinKwc9yDeyass-osdRhS3lHUjewh1GcidLIR6Z-oDjUmLIdwjskvCnLjl69fjdrtw1oOyQmWDG_uYGIPbloi5vk3bYrBpnvc3YF0H--4=&uniplatform=NZKPT&language=CHS</url></related-urls></urls><remote-database-provider>Cnki</remote-database-provider></record></Cite></EndNote>[2]，成為全球碳中和目標(biāo)實(shí)現(xiàn)的關(guān)鍵挑戰(zhàn)。為應(yīng)對(duì)這一嚴(yán)峻形勢(shì)，我國(guó)明確提出“雙碳”戰(zhàn)略目標(biāo)，即2030年前實(shí)現(xiàn)碳達(dá)峰、2060年前達(dá)成碳中和ADDINEN.CITE<EndNote><Cite><Author>李沛宣</Author><Year>2025</Year><RecNum>28</RecNum><DisplayText><styleface="superscript">[3]</style></DisplayText><record><rec-number>3</rec-number><foreign-keys><keyapp="EN"db-id="509eptteo2df2ke55575z25xtapx2xr9zra2"timestamp="1746198131">3</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>李沛宣</author></authors></contributors><auth-address>天津商業(yè)大學(xué);</auth-address><titles><title>碳邊際減排成本測(cè)算研究綜述</title><secondary-title>中國(guó)戰(zhàn)略新興產(chǎn)業(yè)</secondary-title></titles><periodical><full-title>中國(guó)戰(zhàn)略新興產(chǎn)業(yè)</full-title></periodical><pages>160-162</pages><number>08</number><keywords><keyword>碳邊際減排</keyword><keyword>成本測(cè)算</keyword><keyword>綜述</keyword></keywords><dates><year>2025</year></dates><isbn>2095-6657</isbn><call-num>10-1156/F</call-num><urls><related-urls><url>/kcms2/article/abstract?v=IP3-TJYmrEuW6kKWa5qDaa4TpjW7UORE3v7Sf0bYKqpnYOOB5Bdv6ruie5IUm9qWlgm6dhiSZXkXIDZNOw6_B_bKJkIkx0OO31Iqjd9OyNZM4lHz6Tw5_EqLIli22GhO7pxpZGYh6N8i8c9NJ2-Fe6Zw7AOUfcvOf_zFltt4fdJoYLVENtorsDJD1AVuxv1FVYzOIbZORk4=&uniplatform=NZKPT&language=CHS</url></related-urls></urls><remote-database-provider>Cnki</remote-database-provider></record></Cite></EndNote>[3]。在此背景下，碳捕集與封存（CarbonCaptureandStorage,CCS）技術(shù)作為減少工業(yè)源CO2排放的核心手段ADDINEN.CITE<EndNote><Cite><Author>宋倩倩</Author><Year>2015</Year><RecNum>30</RecNum><DisplayText><styleface="superscript">[4]</style></DisplayText><record><rec-number>30</rec-number><foreign-keys><keyapp="EN"db-id="fawf9edt55z95zevsvjxa5sfrx9t9frsta25"timestamp="1746179595">30</key></foreign-keys><ref-typename="Thesis">32</ref-type><contributors><authors><author><styleface="normal"font="default"charset="134"size="100%">宋倩倩</style></author></authors><tertiary-authors><author><styleface="normal"font="default"charset="134"size="100%">蔣慶哲</style><styleface="normal"font="default"size="100%">,</style></author></tertiary-authors></contributors><titles><title><styleface="normal"font="default"charset="134"size="100%">中國(guó)煉油廠碳產(chǎn)業(yè)鏈及低碳煉油廠的構(gòu)建</style></title></titles><keywords><keyword>CO2排放</keyword><keyword>CO2回收技術(shù)</keyword><keyword>CO2利用</keyword><keyword>碳產(chǎn)業(yè)鏈</keyword><keyword>低碳煉油廠</keyword></keywords><dates><year>2015</year></dates><pub-location><styleface="normal"font="default"charset="134"size="100%">北京</style></pub-location><publisher><styleface="normal"font="default"charset="134"size="100%">中國(guó)石油大學(xué)</style></publisher><work-type><styleface="normal"font="default"charset="134"size="100%">博士</style></work-type><urls><related-urls><url>/kcms2/article/abstract?v=IP3-TJYmrEsSc0Zwv-xS3yeMf8Mql4rPl6MKwZk7BqgXtGxOwVfBuXrCipaADht-KHCsnijiSvmRs4VGbsqIV77KUuN5_uMRSow132eGq9ao4TEORBo5iOfQoddF5IyRpkkSSMZQda-Yn6RhBsBTX5Hi0v6Yn3TH5DuY5YopNdc7TMVV570UbQWNgieA3lCY9W8v_FvMVA4=&uniplatform=NZKPT&language=CHS</url></related-urls></urls><remote-database-provider>Cnki</remote-database-provider></record></Cite></EndNote>[4]，其核心瓶頸在于開(kāi)發(fā)兼具高吸附容量、優(yōu)異選擇性、低成本及可再生性的新型吸附材料。然而，傳統(tǒng)物理吸附劑如活性炭雖具有低成本優(yōu)勢(shì)，但其微孔分布寬泛（1-3nm）與CO2分子動(dòng)力學(xué)直徑（0.33nm）匹配度低，導(dǎo)致0oC、1bar條件下吸附量?jī)H2-3mmol/gADDINEN.CITE<EndNote><Cite><Author>Okoniewska</Author><Year>2021</Year><RecNum>36</RecNum><DisplayText><styleface="superscript">[5]</style></DisplayText><record><rec-number>36</rec-number><foreign-keys><keyapp="EN"db-id="fawf9edt55z95zevsvjxa5sfrx9t9frsta25"timestamp="1746195087">36</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Okoniewska,Ewa</author></authors></contributors><titles><title>RemovalofSelectedDyesonActivatedCarbons</title><secondary-title>Sustainability</secondary-title></titles><periodical><full-title>Sustainability</full-title></periodical><pages>4300</pages><volume>13</volume><number>8</number><dates><year>2021</year><pub-dates><date>2021/04/13</date></pub-dates></dates><urls><related-urls><url>/10.3390/su13084300</url></related-urls></urls><electronic-resource-num>10.3390/su13084300</electronic-resource-num></record></Cite></EndNote>[5]；而沸石分子篩（如13X型）因孔徑剛性限制，CO2/N2選擇性普遍低于30ADDINEN.CITEADDINEN.CITE.DATA[6]，難以滿足工業(yè)煙氣中低濃度CO2ADDINEN.CITE<EndNote><Cite><Author>張克利</Author><Year>2025</Year><RecNum>74</RecNum><DisplayText><styleface="superscript">[7]</style></DisplayText><record><rec-number>74</rec-number><foreign-keys><keyapp="EN"db-id="fawf9edt55z95zevsvjxa5sfrx9t9frsta25"timestamp="1746589553">74</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>張克利</author><author>劉欣</author><author>張?zhí)鞁?lt;/author></authors></contributors><auth-address>大唐內(nèi)蒙古多倫煤化工有限責(zé)任公司;中國(guó)石油工程建設(shè)有限公司華北分公司;</auth-address><titles><title>低濃度二氧化碳捕集技術(shù)現(xiàn)狀</title><secondary-title>當(dāng)代化工</secondary-title></titles><periodical><full-title>當(dāng)代化工</full-title></periodical><pages>687-692</pages><volume>54</volume><number>03</number><keywords><keyword>低濃度碳源</keyword><keyword>碳捕集技術(shù)</keyword><keyword>吸收</keyword><keyword>吸附劑</keyword><keyword>膜</keyword><keyword>煙道氣</keyword></keywords><dates><year>2025</year></dates><isbn>1671-0460</isbn><call-num>21-1457/TQ</call-num><urls><related-urls><url>/doi/10.13840/21-1457/tq.20250327.001</url></related-urls></urls><electronic-resource-num>10.13840/21-1457/tq.20250327.001</electronic-resource-num><remote-database-provider>Cnki</remote-database-provider></record></Cite></EndNote>[7]的高效分離需求。此外，有機(jī)氨溶液雖可通過(guò)化學(xué)吸附實(shí)現(xiàn)高選擇性，但存在再生能耗高、設(shè)備腐蝕性強(qiáng)等問(wèn)題ADDINEN.CITE<EndNote><Cite><Author>楊慧</Author><Year>2021</Year><RecNum>81</RecNum><DisplayText><styleface="superscript">[8]</style></DisplayText><record><rec-number>81</rec-number><foreign-keys><keyapp="EN"db-id="fawf9edt55z95zevsvjxa5sfrx9t9frsta25"timestamp="1746589810">81</key></foreign-keys><ref-typename="Thesis">32</ref-type><contributors><authors><author><styleface="normal"font="default"charset="134"size="100%">楊慧</style></author></authors><tertiary-authors><author><styleface="normal"font="default"charset="134"size="100%">丁軼</style><styleface="normal"font="default"size="100%">,</style></author><author><styleface="normal"font="default"charset="134"size="100%">孟繁慧</style><styleface="normal"font="default"size="100%">,</style></author></tertiary-authors></contributors><titles><title><styleface="normal"font="default"charset="134"size="100%">電化學(xué)直接催化下羰基化合物及芳香族化合物的活化轉(zhuǎn)化</style></title></titles><keywords><keyword>羰基化合物</keyword><keyword>三氟甲基/氰基硅烷化</keyword><keyword>電化學(xué)</keyword><keyword>化學(xué)選擇性</keyword><keyword>還原</keyword></keywords><dates><year>2021</year></dates><pub-location><styleface="normal"font="default"charset="134"size="100%">天津</style></pub-location><publisher><styleface="normal"font="default"charset="134"size="100%">天津理工大學(xué)</style></publisher><work-type><styleface="normal"font="default"charset="134"size="100%">碩士</style></work-type><urls><related-urls><url>/doi/10.27360/ki.gtlgy.2021.000399</url></related-urls></urls><electronic-resource-num>10.27360/ki.gtlgy.2021.000399</electronic-resource-num><remote-database-provider>Cnki</remote-database-provider></record></Cite></EndNote>[8]。因此，亟需開(kāi)發(fā)新型多孔材料以突破現(xiàn)有技術(shù)局限。近年來(lái)，超交聯(lián)微孔聚合物（Hyper-crosslinkedPolymers,HCPs）因其獨(dú)特的物理化學(xué)性質(zhì)成為多孔材料領(lǐng)域的研究熱點(diǎn)ADDINEN.CITE<EndNote><Cite><Author>Tan</Author><Year>2015</Year><RecNum>50</RecNum><DisplayText><styleface="superscript">[9]</style></DisplayText><record><rec-number>50</rec-number><foreign-keys><keyapp="EN"db-id="fawf9edt55z95zevsvjxa5sfrx9t9frsta25"timestamp="1746345689">50</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Tan,Liangxiao</author><author>Tan,Bien</author></authors></contributors><titles><title>ResearchProgressinHypercrosslinkedMicroporousOrganicPolymers</title><secondary-title>ActaChimicaSinica</secondary-title></titles><periodical><full-title>ActaChimicaSinica</full-title></periodical><pages>530</pages><volume>73</volume><number>6</number><section>530</section><dates><year>2015</year></dates><isbn>0567-7351</isbn><urls></urls><electronic-resource-num>10.6023/a15020096</electronic-resource-num></record></Cite></EndNote>[9]。超交聯(lián)微孔聚合物（HCPs）通過(guò)剛性芳香單體的拓?fù)浣宦?lián)策略，構(gòu)建三維互穿網(wǎng)絡(luò)結(jié)構(gòu)，其比表面積可突破1000m2/gADDINEN.CITE<EndNote><Cite><Author>Tsyurupa</Author><Year>2006</Year><RecNum>38</RecNum><DisplayText><styleface="superscript">[10]</style></DisplayText><record><rec-number>38</rec-number><foreign-keys><keyapp="EN"db-id="fawf9edt55z95zevsvjxa5sfrx9t9frsta25"timestamp="1746195871">38</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Tsyurupa,M.P.</author><author>Davankov,V.A.</author></authors></contributors><titles><title>Porousstructureofhypercrosslinkedpolystyrene:State-of-the-artmini-review</title><secondary-title>Reactive&FunctionalPolymers</secondary-title></titles><periodical><full-title>Reactive&FunctionalPolymers</full-title></periodical><pages>768-779</pages><volume>66</volume><number>7</number><dates><year>2006</year><pub-dates><date>2006/07/01</date></pub-dates></dates><urls><related-urls><url>/10.1016/j.reactfunctpolym.2005.11.004</url></related-urls></urls><electronic-resource-num>10.1016/j.reactfunctpolym.2005.11.004</electronic-resource-num></record></Cite></EndNote>[10]，且微孔（<2nm）占比高達(dá)70%以上ADDINEN.CITE<EndNote><Cite><Author>Furukawa</Author><Year>2009</Year><RecNum>48</RecNum><DisplayText><styleface="superscript">[11]</style></DisplayText><record><rec-number>48</rec-number><foreign-keys><keyapp="EN"db-id="fawf9edt55z95zevsvjxa5sfrx9t9frsta25"timestamp="1746243683">48</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Furukawa,Hiroyasu</author><author>Yaghi,OmarM.</author></authors></contributors><titles><title>StorageofHydrogen,Methane,andCarbonDioxideinHighlyPorousCovalentOrganicFrameworksforCleanEnergyApplications</title><secondary-title>JournaloftheAmericanChemicalSociety</secondary-title></titles><periodical><full-title>JournaloftheAmericanChemicalSociety</full-title></periodical><pages>8875-8883</pages><volume>131</volume><number>25</number><dates><year>2009</year><pub-dates><date>2009/07/01</date></pub-dates></dates><urls><related-urls><url>/10.1021/ja9015765</url></related-urls></urls><electronic-resource-num>10.1021/ja9015765</electronic-resource-num></record></Cite></EndNote>[11]，與CO2分子尺寸的高度契合性使其成為物理吸附主導(dǎo)型材料的理想候選ADDINEN.CITE<EndNote><Cite><Author>Xu</Author><Year>2013</Year><RecNum>69</RecNum><DisplayText><styleface="superscript">[12]</style></DisplayText><record><rec-number>69</rec-number><foreign-keys><keyapp="EN"db-id="fawf9edt55z95zevsvjxa5sfrx9t9frsta25"timestamp="1746579592">69</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Xu,Shujun</author><author>Luo,Yali</author><author>Tan,Bien</author></authors></contributors><titles><title>RecentDevelopmentofHypercrosslinkedMicroporousOrganicPolymers</title><secondary-title>MacromolecularRapidCommunications</secondary-title></titles><periodical><full-title>MacromolecularRapidCommunications</full-title></periodical><pages>471-484</pages><volume>34</volume><number>6</number><dates><year>2013</year><pub-dates><date>2013/01/30</date></pub-dates></dates><urls><related-urls><url>/10.1002/marc.201200788</url></related-urls></urls><electronic-resource-num>10.1002/marc.201200788</electronic-resource-num></record></Cite></EndNote>[12]，并且其合成條件溫和，無(wú)需貴金屬催化劑，可通過(guò)廉價(jià)單體與交聯(lián)劑在常壓下一步反應(yīng)制備，成本可控ADDINEN.CITE<EndNote><Cite><Author>王楠</Author><Year>2025</Year><RecNum>25</RecNum><DisplayText><styleface="superscript">[13]</style></DisplayText><record><rec-number>10</rec-number><foreign-keys><keyapp="EN"db-id="509eptteo2df2ke55575z25xtapx2xr9zra2"timestamp="1746198131">10</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>王楠</author><author>王媛</author><author>宗帥</author><author>趙文杰</author></authors></contributors><auth-address>河南工業(yè)大學(xué)化學(xué)化工學(xué)院;寧夏計(jì)量質(zhì)量檢驗(yàn)檢測(cè)研究院;</auth-address><titles><title>環(huán)糊精聚合物在食品分析樣品前處理中的應(yīng)用</title><secondary-title>分析測(cè)試學(xué)報(bào)</secondary-title></titles><periodical><full-title>分析測(cè)試學(xué)報(bào)</full-title></periodical><pages>34-42</pages><volume>44</volume><number>01</number><keywords><keyword>環(huán)糊精</keyword><keyword>環(huán)糊精聚合物</keyword><keyword>樣品前處理</keyword><keyword>食品分析</keyword><keyword>選擇性吸附</keyword></keywords><dates><year>2025</year></dates><isbn>1004-4957</isbn><call-num>44-1318/TH</call-num><urls><related-urls><url>/kcms2/article/abstract?v=IP3-TJYmrEs-HbelBG4KlvXAb0fHSO_klXcndm_tlCgtHfgcqLQn0Y-75s4OK0YSXiGC1_r2gMa-MnOVX5xAIBeTenjPWrc9AN4amTVYjuaZ30XYBELqyZhtR7QA5jkVcv06s8t2zL7EVIf5olO9BEt0ZyzMImIgMx6lVeOAN64YyoRP7egBTiW7Zy4DwIEGgPHyVPMpZcs=&uniplatform=NZKPT&language=CHS</url></related-urls></urls><remote-database-provider>Cnki</remote-database-provider></record></Cite></EndNote>[13]；最后HCPs表面功能化靈活A(yù)DDINEN.CITE<EndNote><Cite><Author>梁森</Author><Year>2020</Year><RecNum>34</RecNum><DisplayText><styleface="superscript">[14]</style></DisplayText><record><rec-number>34</rec-number><foreign-keys><keyapp="EN"db-id="fawf9edt55z95zevsvjxa5sfrx9t9frsta25"timestamp="1746194586">34</key></foreign-keys><ref-typename="Thesis">32</ref-type><contributors><authors><author><styleface="normal"font="default"charset="134"size="100%">梁森</style></author></authors><tertiary-authors><author><styleface="normal"font="default"charset="134"size="100%">張曼霞</style><styleface="normal"font="default"size="100%">,</style></author></tertiary-authors></contributors><titles><title><styleface="normal"font="default"charset="134"size="100%">新型聚咔唑共軛聚合物的合成及在</style><styleface="normal"font="default"size="100%">CO2</style><styleface="normal"font="default"charset="134"size="100%">吸附和硝基芳烴檢測(cè)性能研究</style></title></titles><keywords><keyword>環(huán)境污染</keyword><keyword>微孔有機(jī)聚合物</keyword><keyword>氣體吸附</keyword><keyword>熒光檢測(cè)</keyword></keywords><dates><year>2020</year></dates><pub-location><styleface="normal"font="default"charset="134"size="100%">大連</style></pub-location><publisher><styleface="normal"font="default"charset="134"size="100%">大連海事大學(xué)</style></publisher><work-type><styleface="normal"font="default"charset="134"size="100%">碩士</style></work-type><urls><related-urls><url>/doi/10.26989/ki.gdlhu.2020.000653</url></related-urls></urls><electronic-resource-num>10.26989/ki.gdlhu.2020.000653</electronic-resource-num><remote-database-provider>Cnki</remote-database-provider></record></Cite></EndNote>[14]，通過(guò)氨基化修飾可引入堿性位點(diǎn)，增強(qiáng)對(duì)CO2的化學(xué)吸附能力，從而克服物理吸附劑選擇性不足的缺陷ADDINEN.CITE<EndNote><Cite><Author>龔兵麗</Author><Year>2009</Year><RecNum>43</RecNum><DisplayText><styleface="superscript">[15]</style></DisplayText><record><rec-number>43</rec-number><foreign-keys><keyapp="EN"db-id="fawf9edt55z95zevsvjxa5sfrx9t9frsta25"timestamp="1746242829">43</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>龔兵麗</author><author>邱宇平</author><author>趙雅萍</author><author>黃民生</author></authors></contributors><auth-address>華東師范大學(xué)環(huán)境科學(xué)與技術(shù)系;浙江工業(yè)大學(xué)生物與環(huán)境工程學(xué)院;</auth-address><titles><title>黑碳吸附亞甲基藍(lán)染料廢水的行為研究</title><secondary-title>環(huán)境科學(xué)與技術(shù)</secondary-title></titles><periodical><full-title>環(huán)境科學(xué)與技術(shù)</full-title></periodical><pages>18-23</pages><volume>32</volume><number>11</number><keywords><keyword>亞甲基藍(lán)</keyword><keyword>黑碳</keyword><keyword>吸附</keyword><keyword>動(dòng)力學(xué)</keyword><keyword>熱力學(xué)</keyword></keywords><dates><year>2009</year></dates><isbn>1003-6504</isbn><call-num>42-1245/X</call-num><urls><related-urls><url>/kcms2/article/abstract?v=Bo5Zm1RyAilQ0v1PAjirpGBbNnzxwMDd4r7MFfQAdtxRV2XTQUbpgIvALyz6ItPe4imYf2Dw_eZopikl1xuxlJ4A4EVgKN_rad2yfX24Z6m9WnbXgMYhhKjNZCx6vkWTuUVDkeWbVUNgr9MVO644lInoQgksKljPZ4bd3E-wXVYxqWXZgxxhr3X7U-BPLrWU&uniplatform=NZKPT&language=CHS</url></related-urls></urls><remote-database-provider>Cnki</remote-database-provider></record></Cite></EndNote>[15]。三蝶烯（Triptycene）憑借其獨(dú)特的蝶狀共軛結(jié)構(gòu)與C3對(duì)稱性，可有效抑制交聯(lián)過(guò)程中的π-π堆積效應(yīng)ADDINEN.CITE<EndNote><Cite><Author>何妍</Author><Year>2021</Year><RecNum>44</RecNum><DisplayText><styleface="superscript">[16]</style></DisplayText><record><rec-number>44</rec-number><foreign-keys><keyapp="EN"db-id="fawf9edt55z95zevsvjxa5sfrx9t9frsta25"timestamp="1746242917">44</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>何妍</author><author>鮑文利</author><author>那兵</author><author>郭柱雷</author><author>吳云軒</author><author>楊俊鑫</author><author>袁定重</author><author>羅太安</author></authors></contributors><auth-address>東華理工大學(xué)化學(xué)生物與材料科學(xué)學(xué)院;東華理工大學(xué)江西省聚合物微納制造與器件重點(diǎn)實(shí)驗(yàn)室;</auth-address><titles><title>新型的三蝶烯基超交聯(lián)多孔共聚物對(duì)孔雀石綠的吸附性能研究</title><secondary-title>東華理工大學(xué)學(xué)報(bào)(自然科學(xué)版)</secondary-title></titles><periodical><full-title>東華理工大學(xué)學(xué)報(bào)(自然科學(xué)版)</full-title></periodical><pages>287-293</pages><volume>44</volume><number>03</number><keywords><keyword>超交聯(lián)多孔共聚物</keyword><keyword>孔雀石綠</keyword><keyword>吸附性</keyword><keyword>廢水處理</keyword></keywords><dates><year>2021</year></dates><isbn>1674-3504</isbn><call-num>36-1300/N</call-num><urls><related-urls><url>/urlid/36.1300.n.20201227.1007.002</url></related-urls></urls><remote-database-provider>Cnki</remote-database-provider></record></Cite></EndNote>[16]，通過(guò)分子間位阻效應(yīng)維持孔道剛性ADDINEN.CITE<EndNote><Cite><Author>Li</Author><Year>2018</Year><RecNum>46</RecNum><DisplayText><styleface="superscript">[17]</style></DisplayText><record><rec-number>46</rec-number><foreign-keys><keyapp="EN"db-id="fawf9edt55z95zevsvjxa5sfrx9t9frsta25"timestamp="1746243031">46</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Li,Wenjie</author><author>Xiong,Chaochao</author><author>Wang,Lijun</author><author>Luo,Qianfu</author></authors></contributors><titles><title>Triptycene-basedporouspolymersregulatedbydiarylethenes</title><secondary-title>DyesandPigments</secondary-title></titles><periodical><full-title>DyesandPigments</full-title></periodical><pages>72-76</pages><volume>159</volume><number>0</number><dates><year>2018</year><pub-dates><date>2018/06/07</date></pub-dates></dates><urls><related-urls><url>/10.1016/j.dyepig.2018.06.007</url></related-urls></urls><electronic-resource-num>10.1016/j.dyepig.2018.06.007</electronic-resource-num></record></Cite></EndNote>[17]，為構(gòu)建高穩(wěn)定性微孔網(wǎng)絡(luò)提供了分子層面的設(shè)計(jì)基礎(chǔ)。然而，現(xiàn)有研究多集中于苯基單體的交聯(lián)體系，對(duì)三蝶烯基HCPs的孔結(jié)構(gòu)調(diào)控機(jī)制及交聯(lián)劑類型對(duì)氨基化修飾效率的影響缺乏系統(tǒng)性探索，尤其是交聯(lián)劑柔性與剛性DCBZ對(duì)材料微孔占比、表面活性位點(diǎn)分布及CO2吸附性能的量化關(guān)系尚未明確，制約了該類材料的工業(yè)化應(yīng)用。基于此，本研究以三蝶烯為構(gòu)筑單元，分別采用柔性交聯(lián)劑二甲醇縮甲醛（Dimethoxymethane,DMM）與剛性交聯(lián)劑1,4-對(duì)二氯芐（1,4-Bis（chloromethy）-benzene,DCBZ），通過(guò)傅克烷基化反應(yīng)（Friedel-CraftsAlkylation）合成超交聯(lián)聚合物前驅(qū)體（HCP-DMM與HCP-DCBZ）ADDINEN.CITE<EndNote><Cite><Author>石經(jīng)</Author><Year>2024</Year><RecNum>66</RecNum><DisplayText><styleface="superscript">[18]</style></DisplayText><record><rec-number>66</rec-number><foreign-keys><keyapp="EN"db-id="fawf9edt55z95zevsvjxa5sfrx9t9frsta25"timestamp="1746437991">66</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>石經(jīng)</author><author>張志豪</author><author>周瑾修</author><author>黃木華</author></authors></contributors><auth-address>北京理工大學(xué)材料學(xué)院;</auth-address><titles><title>偶氮苯骨架的多孔高分子：結(jié)構(gòu)創(chuàng)新及應(yīng)用研究進(jìn)展</title><secondary-title>高分子學(xué)報(bào)</secondary-title></titles><periodical><full-title>高分子學(xué)報(bào)</full-title></periodical><pages>936-953</pages><volume>55</volume><number>08</number><keywords><keyword>多孔高分子</keyword><keyword>偶氮苯</keyword><keyword>羥基偶氮苯</keyword><keyword>氨基偶氮苯</keyword><keyword>三酮三腙環(huán)己酮</keyword></keywords><dates><year>2024</year></dates><isbn>1000-3304</isbn><call-num>11-1857/O6</call-num><urls><related-urls><url>/urlid/11.1857.O6.20240710.1611.002</url></related-urls></urls><remote-database-provider>Cnki</remote-database-provider></record></Cite></EndNote>[18]，進(jìn)一步經(jīng)氯甲基化反應(yīng)引入活性位點(diǎn)，并利用乙二胺（Ethylenediamine,EDA）進(jìn)行氨基化修飾ADDINEN.CITE<EndNote><Cite><Author>王明媚</Author><Year>2024</Year><RecNum>61</RecNum><DisplayText><styleface="superscript">[19]</style></DisplayText><record><rec-number>61</rec-number><foreign-keys><keyapp="EN"db-id="fawf9edt55z95zevsvjxa5sfrx9t9frsta25"timestamp="1746347845">61</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>王明媚</author><author>董季玲</author><author>鐘晨晨</author><author>蔣偉</author><author>劉洋</author></authors></contributors><auth-address>重慶科技大學(xué)化學(xué)化工學(xué)院;重慶科技大學(xué)冶金與動(dòng)力工程學(xué)院;</auth-address><titles><title>氨基功能化雙金屬ZIF的合成及其CO2吸附性能研究</title><secondary-title>功能材料</secondary-title></titles><periodical><full-title>功能材料</full-title></periodical><pages>12104-12111</pages><volume>55</volume><number>12</number><keywords><keyword>氨基功能化</keyword><keyword>雙金屬</keyword><keyword>ZIFs</keyword><keyword>CO2吸附</keyword></keywords><dates><year>2024</year></dates><isbn>1001-9731</isbn><call-num>50-1099/TH</call-num><urls><related-urls><url>/urlid/50.1099.TH.20241204.1127.062</url></related-urls></urls><remote-database-provider>Cnki</remote-database-provider></record></Cite></EndNote>[19]，最終制備氨基功能化材料HCP-DMM-EDA與HCP-DCBZ-EDA。通過(guò)系統(tǒng)性表征（如氮?dú)馕?/p>