1、物化上-Exercise 1-考研試題資料系列物化上-Exercise 1-考研試題資料系列物化上-Exercise 1-考研試題資料系列物化上-Exercise 1-考研試題資料系列Exercise 1Tesecifi heacapay Cp forixures o silyi 1 + V K02 wermaued at tpratuTring from 28.15 to 370.15K bdifrentalcaningcalorimetr， C The p da ae isd intheTable Plea cnstrc the uve ops。 fr w1， te as ractin o

2、f component 1, rom to0.4 in one figu,resectvehe dendenc of p on tmpertur can be xpred b q1 in th rnge rom an initial temperatureTi a inal tempatue f。 1Wre， 2lesegive he coeffcent aiof Eq. b fittig expeientlda of C。 Ifaliner rationhieween aind w1 issupose lase ge te oeffients f Eq.3frve ai i Eq。 1， r

3、spcively. hanen terodnamic proeris fo the intl temperaure Ti to given tmperature T,freampleenthalpychnge=HT-HTi, a alcultedro he data of Cp。 Pleae gie the auesf tay hant temerture T， ad contruthe ursof Hagainst Tfor al the mixures withmassfraw1。 able. Th Cp /。K11formture of ilyin 1+PVP 0 2t massfrac

4、ions w1 0, o 。 at meateTby DSCmehod TKw10.0.230.429.151。261221.991。151.11129.1.1。2251.2021.1.1630。15121.231.2066213301.15。1.236121。671.1330215。211231.241.1721。3633151。1。251.2181.1771.13.113071。261。231。1821.4305.151.3131.61。2281.181.152306。151。321。268.2.192.5807151.31.231.231.191。1638。15.3112791.2121

5、.16830。151.3371。2841。24。0417310.5.41291.221.2091.7931.15。341。29612571.141。14312.551.31221.221。1931。153621。3081。2671.2261。1963.1.681。1231.232.20215.15741。311.791.39120316.151。3811.3261.28。241。21317.151。371331。2921251.2231151.391341。281。2591.2319。151。413491。3061。6233.151.41。371.3.231。4721。15.414。365.3

6、19281。255322。15.1.373。251.871263。151.423821.321。241。2734.5.4381。391。31.3011。7325.151.41.1。3513071.22611571。091511.31.2.151。461。418.35322。27328。151。41。21.3663291。30339。151。421。4361.3731.336.30933。151。491.45.38.3431。31631514981.451。381。3511.23332.155071465。39515.32933151。11。4751。4041。35.6415.526481.41

7、1371.34335。151.51。494141.71。33。151。551。50314。385.56.555。5114311392.33338。15.5631.191。438981。3693915571.526.4441.37434。151.581534151。47341.151。5891。541.48.141.384342。1557.551461。49138733.516051.5571.411.41。391.1631.561.477142819515627。4331。3836151.271.761489.436。0234。151.63415811.4439。4534.151.158614

8、981。414093.15.451.591501。4143350。156511。5515071。4414163151.651.51.511.448419352。1.61.601.51.4511.225。51.661。605。519。45。4535411。671。07。52142835.51.67.081.21.581。336。151。651.052614591。3235。151.71。6081.5281491.3358151。6781。608。531。461.435.51678160.531.461.43636011。676。601。314613761.151。6751。6041521.6.438365167。602。3。419363。517161.5321.611.6.151668.91.3.411.44365。151.6661.5961