化學(xué)品安全及安全技術(shù)說明書ChemicalSafety&MaterialSafetyDataSheet(MSDS)1法規(guī)要求Regulatoryrequirements化學(xué)品及其危害Introductionofchemicalsandthehazard安全標志Safetysign運輸標簽Transportlabel化學(xué)品安全技術(shù)說明書MaterialSafetyDataSheet(MSDS)化學(xué)品的安全使用、處置和運輸Thesafetyofusage,disposalandtransportofchemicals培訓(xùn)內(nèi)容

Trainingschedule2通過此次培訓(xùn)，對一些法規(guī)要求及化學(xué)品的基本知識有所了解，并能夠閱讀化學(xué)品安全技術(shù)說明書。Toincreasetheknowledgeoftheregulationrequirementsandthechemicals,becapabletoreadMSDSbythistraining.培訓(xùn)目的

Trainingobjective3我國的主要化學(xué)品管理法規(guī)及標準

MainregulationsandstandardsofchemicalsmanagementinChina中華人民共和國安全生產(chǎn)法SafeProductionLawofthePeople’sRepublicofChina危險化學(xué)品安全管理條例RegulationoncontroloverDGchemicals工作場所安全使用化學(xué)品規(guī)定（170公約）Regulationonsafelyusingchemicalsinworkingarea（170pact）《常用危險化學(xué)品的分類及標志》（GB13690-1992）Theclassificationandsignofdangerouschemicalsincommonuse《危險貨物分類和品名編號》（GB6944-2005）Theclassificationandnumberofdangerousgoods《危險貨物品名表》（GB12268-1990）Thenamelistofdangerousgoods《化學(xué)品安全標簽編寫規(guī)定》（GB15258-1999）

Regulationonsafetylabel《化學(xué)品安全技術(shù)說明書編寫規(guī)定》（GB16483-2000）

RegulationonmakingMSDS國內(nèi)相關(guān)法規(guī)及標準

Relatedregulation4指各種化學(xué)元素、由元素組成的化合物及其混合物，無論是天然的或是人造的。Meansallkindsofchemicalelement,compoundswhichconstitutedwithelementandcompoundsmixture,whethernaturalormanmade.什么是化學(xué)品？Whatarechemicals?5固體：在室溫下以固態(tài)形式存在的物質(zhì)。如金屬，塑料Solids–thematerialsexistasasolidformunderthenormalroomtemperature.e.g.metals,plastics液體：在室溫下以液態(tài)形式存在的物質(zhì)。如稀釋劑Liquids–thematerialsexistasaliquidformunderthenormalroomtemperature.e.g.thinners氣體：在室溫下以氣態(tài)形式存在的物質(zhì)。如一氧化碳Gases–thematerialsexistasagasformunderthenormalroomtemperature.e.g.carbonmonoxide蒸氣：液體由于溫度、壓力的改變形成空氣中的微小液滴，正常狀態(tài)下為液體。Vapours–theliquidformstinyliquiddropsintheairbecauseofthechangeoftemperatureandpressure,itwillbeliquidinnormalcondition.e.g.solvents煙：固體由于溫度、壓力的改變形成空氣中的細小的固體顆粒。Smoke–thesolidformstinysolidparticleintheairbecauseofthechangeoftemperatureandpressure.塵：室溫下空氣中的細小固體顆粒。Dust–thetinysolidparticleintheairunderthenormalroomtemperature.存在形式

Existenceforms6化學(xué)品中具有易燃、易爆、有毒、有害及有腐蝕特性，會對人員、設(shè)施、環(huán)境造成傷害或損害的化學(xué)品屬危險化學(xué)品。Thechemicalswhichhavethecharactersofflammability,explosive,toxic,harmfulandcorrosive,andwillcausehurtordamagetoperson,equipmentsandenvironmentaredangerouschemicals.危險化學(xué)品(一)Hazardouschemicals7《常用危險化學(xué)品的分類及標志》（GB13690-1992）

“Theclassificationandsignofdangerousgoodsincommonuse”第1類：爆炸品

class1:explosive第2類：壓縮氣體和液化氣體

class2:compressedgasandliquefiedgas第3類：易燃液體

class3:flammableliquid第4類：易燃固體、自燃物品和遇濕易燃物品

class4:flammablesolid,substanceliabletospontaneouscombustionandsubstancesflammablewhenwet第5類：氧化劑和過氧化物

class5:oxidizingsubstancesandperoxide第6類：有毒品

class6:toxic第7類：放射性物品

class7:radioactivesubstance第8類：腐蝕品

class8:corrosive危險化學(xué)品(二)Hazardouschemicals8BYC所用到的危險化學(xué)品

ExamplesinBYC產(chǎn)品：finishedproducts苯benzene甲苯toluene甲酸formicacid丙酸propionicacid一甲胺monomethylamine二甲胺dimethylamine三甲胺trimethylamine丙烯酸acrylicacid丙烯酸甲酯methylacrylate丙烯酸乙酯ethylacrylate丙烯酸丁酯butylacrylate……原料：rawmaterials硫酸sulfuricacid氫氧化鈉causticsoda氨（氨水、液氨）ammonia(ammoniawatersolution,ammonialiquid)……危險化學(xué)品(三)Hazardouschemicals9一些化學(xué)品單獨儲存可能是安全的,但是如果和其他化學(xué)品接觸時會變成危險品。Severalchemicalsareprobablysafewhenstorageseparately,howevertheywillbehazardouswhencontactwithotherchemicals.化學(xué)品的危害有：Thehazardofchemicalsare可燃flammable有毒toxic可爆explosive腐蝕caustic環(huán)境environmental……化學(xué)品的危害Thehazardofchemicals10你的肺部：如果你吸入煙,霧,灰塵

Yourlung:ifyouinhalesmoke,fuganddust你的皮膚：液體或粉料接觸或濺到皮膚上或眼睛里

Yourskin:contactliquidsorpowder,spilltoskinandeyes你的口：如果你接觸化學(xué)品后吃東西

Yourmouth:ifyoueatsomethingaftercontactingchemicals意外吞入：化學(xué)品

Swallowaccidentally:chemicals化學(xué)品進入人體的途徑

Routesofentryintobody11使用化學(xué)品必須遵守的第一條規(guī)則是…“知道你在和什么化學(xué)品打交道,并且知道如何保護自己和別人”Thefirstruleofusingchemicalsmustbeobservedis:Youmustknowwhichchemicalsyouareworkingon,andhowtoprotectyourselfandothers?安全使用化學(xué)品？Howtousechemicalssafety?12安全標志safetysign運輸標簽transportlabel化學(xué)品安全技術(shù)說明書materialsafetydatasheet（MSDS)……如何得到相關(guān)信息？Wheretogetinformation?13《安全標志》“safetysign”(GB2894-1996）《安全標志使用導(dǎo)則》“theusageguidelineofsafetysigns”(GB16179-1996）

BYCPortal:01-010-00-0-0-00-021Safetysigns安全標志在哪里？Wherearesafetysigns?公司/裝置的入口處theentranceofcompany/plant工作區(qū)域workingarea裝有化學(xué)品的管道、容器上thepipelineandcontainerwithchemicals……安全標志

Safetysign14禁止標志Prohibitionsign禁止堆放

Donotobstruct警告標志W(wǎng)arningsign當心腐蝕Caution,corrosion必須戴防護手套Mustwearprotectiveprotectiongloves強制性標志Mandatorysign應(yīng)急信息標志Emergencyinformationsign可動火區(qū)Flareupregion安全標志舉例

Examplesofsafetysign(1)15危險化學(xué)品標志Dangerouschemicalssign極其易燃性EXTREMELYFLAMMABLE極其易燃性Extremelyflammable擊碎板面

Breaktoobtainaccess消防安全標志Firesafetysigns環(huán)保標志Environmentprotectsigns廢氣排放口

Outletofwastegas當心危險固體廢物

Cautionhazardouswastesolid安全標志舉例

Examplesofsafetysign(2)16禁止用水滅火Nowatertoputoutthefire禁止飲用Donotdrink禁止通行Authorizedpersonalonly禁止放易燃物Nolayinginflammablething禁止標志

Prohibitionsign17當心中毒Caution,toxichazard當心火災(zāi)－易燃物質(zhì)Dangeroffire-Highlyflammablematerials

當心爆炸－爆炸性物質(zhì)Dangerofexplosion-Explosivematerials當心火災(zāi)－氧化物Dangeroffire-oxidizingmaterials警告標志

Warningsign18必須戴安全帽和防護眼鏡Mustwearsafetyhelmetandprotectivegoggles必須戴護耳器Mustwearearprotector必須戴眼部和臉部防護用品Mustweareyeandfaceprotection必須加鎖Mustbelocked必須戴防毒面具Mustweargasdefencemask強制性標志

Mandatorysign19避險處Haven可動火區(qū)Flareupregion眼部清洗處Eyewashstation噴淋安全裝置Safetyshowerstation應(yīng)急信息標志

Emergencyinformationsign20生物影響B(tài)IOHAZARDOUS對環(huán)境造成危險DANGEROUSFORTHEENVIRONMENT有害HARMFUL刺激性IRRITANT腐蝕性CORROSIVE毒性TOXIC毒性很強VERYTOXIC放射性RADIOACHIC高度易燃性HIGHLYFLAMMABLE極其易燃性EXTREMELYFLAMMABLE氧化性O(shè)XIDIZING爆炸性EXPLOSIVES危險化學(xué)品標志

Dangerouschemicalssign21舉例Example22《化學(xué)品安全標簽編寫規(guī)定》(GB15258-1999）“Theregulationofmakingchemicalssafetylabel”(GB15258-1999）化學(xué)品安全標簽包括物質(zhì)名稱、危險性標志、編號、警示詞、危險性概述、安全措施、滅火方法、生產(chǎn)廠家、地址、電話、應(yīng)急咨詢電話、提示參閱MSDS等內(nèi)容Thechemicalssafetylabelcontains:thenameofsubstance,hazardsign,number,alarmwords,hazardidentification,safetymeasures,fire-fightingmethod,productcompanyinformation(address,phonenumber,emergencyconsultationnumber),remindingofseeingMSDS……運輸標簽

Transportlabel23

揚子巴斯夫化工有限責任公司BASF-YPCCompanyLimited

純度/

pure：

凈重/

weight：

批號/

batchNo.：N-butanol正丁醇C4H10O注

意Notice易燃、有毒、具刺激性Flammable,Harmful,Irritating

安全措施/SafetyMeasures防止與堿類及堿化物料接近/Protectagainstalkaliesandalkalizingsubstances.防止靜電–遠離火源-近處應(yīng)準備滅火器/Preventelectrostaticcharge-sourcesofignitionshouldbekeptwellclear–fireextinguishersshouldbekepthandy.密閉包裝，并存于陰涼及干燥處/Keepcontainertightlyclosedinacool，dry.自燃濕度>300℃/Autoignitiontemperature>300℃.

滅火/FireFightingMeasure水噴霧,干滅火介質(zhì),耐醇性泡沫,二氧化碳/waterspray,dryextinguishingmedia,alcohol-resistantfoam,carbondioxide請向生產(chǎn)銷售企業(yè)索取安全技術(shù)說明書PleaseaskforMSDSfrommanufactureordistributors揚子巴斯夫化工有限責任公司CC出品ProductbyCCPLANT,BYCCo.Ltd郵編Zip-code：210048南京市六合區(qū)大廠鎮(zhèn)/DaChang,LuHe,Nanjingmunicipal電話Tel：025－×××××××UNNo.1120CNNo.33552應(yīng)急電話：Emergencycall24常用危險化學(xué)品標志-主標志Mainsign25常用危險化學(xué)品標志-副標志Subsidiarysign26《化學(xué)品安全技術(shù)說明書編寫規(guī)定》（GB16483-2000）“RegulationonmakingMSDS”

化學(xué)品使用者獲取有關(guān)化學(xué)品危害訊息和安全措施的來源Thesourceofhazardinformationandsafetyprecautionsofachemicalproductforusers化學(xué)品供應(yīng)商向用戶傳達必要的化學(xué)品危害信息的工具Thetoolforthechemicalsuppliertotransferessentialhazardinformationofachemicalproducttotherecipient提供緊急響應(yīng)的信息Provideemergencyresponseinformation管理工作場所中化學(xué)品的參考資料Thereferenceformanagementofhazardouschemicalsinworkplace操作工的安全培訓(xùn)Trainingprogramofworkerprotection安全措施Safetymeasures安全操作規(guī)程化學(xué)品安全技術(shù)說明書（MSDS）27MSDS1.化學(xué)品及企業(yè)標識Substance/preparationandcompanyidentification2.成份組成信息Composition/informationoningredients3.危險性概述Hazardidentification4.急救措施Firstaidmeasures5.消防措施Fire-fightingmeasures6.泄漏應(yīng)急處理Accidentalreleasemeasures7.操作處置與儲存Handlingandstorage8.控制接觸/個體防護Exposecontrolandpersonalprotection9.理化特性Physicalandchemicalproperties10.穩(wěn)定性和反應(yīng)活性Stabilityandreactivity11..毒理學(xué)資料Toxicologicalinformation12.生態(tài)學(xué)資料Ecologicalinformation13.廢棄處置Disposalconsiderations14.運輸信息Transportinformation15.法規(guī)信息Regulatoryinformation16.其他信息Otherinformation化學(xué)品安全技術(shù)說明書（MSDS）28以一份Documentum中公布的MSDS為例，詳細說明。TakeoneMSDSwhichhaspublishedinBYCDocumentumforexample,introduceeverypart.BYCPortal/EHS/MSDSC00-7.5.1-00PSH-200MSDSManagement舉例Example:29C00-6.3.0-00GSH-201

GuidelineInformationCard信息卡Informationcard30R22誤吞對人體有害HarmfulbyacuteingestionR24沾及皮膚后會中毒

ToxicbyacuteskinabsorptionR26吸入會中劇毒VeryToxicbyacuteinhalationR34引致灼傷Corrosivebyacuteeye/skinabsorptionR41對眼睛造成嚴重損害IrritantbyacuteeyeabsorptionR42吸入可引起過敏SensitisingbyacuteinhalationR45(1)引致癌癥

CarcinogenbychronicexposureR46(1)可造成遺傳性的基因損害MutagenbychronicexposureR47(1)可引致先天性缺陷Teratogenicbychronicexposure風險短語-舉例

Riskphrase-example31S1必須上鎖

KeeplockedupS2不要讓兒童接觸KeepoutofreachofchildrenS3置于陰涼處

Keepincoolplace

S4切勿放近住所

KeepawayfromlivingquartersS1/2上鎖保管并避免兒童接觸Keeplockedup&outofreachofchildrenS3/7保持容器密閉并在陰涼處保存

Keepcontainertightlyclosed,inacoolwellventilatedplaceS3/9/14置于陰涼、通風處，并遠離存放…(由生產(chǎn)廠指明的不相容物質(zhì))Keepinacool,wellventilatedplaceawayfrom…(incompatiblematerialtobeindicatedbymanufacturer)安全短語-舉例

Safetyphrase-example32你知道危害和如何保護自己knowthehazardandhowtoprotectyourself僅用于批準的用途onlyusechemicalsintheapprovedpurpose儲存適當suitablestoragethechemicals使用正確的個人防護用品usecorrectpersonalprotectiveequipments(PPE)不在使用化學(xué)品的區(qū)域飲食notdrinkandeatintheareaofusingchemicals接觸化學(xué)品后立即清洗cleanoutimmediatelyaftercontactingchemicals安全地使用化學(xué)品

Safetyusechemicals33可以用個人防護用品來防護化學(xué)品危害canusePPEtoprotectthechemicalshazard針對不同的化學(xué)品使用公司規(guī)定的個人防護用品usePPEwhichareprescriptivebycompanyaccordingtodifferentchemicals在使用前檢查個人防護用品,確保無損壞checkPPEandmakesurenodisrepairbeforeusing如果有飛濺危險,則使用面罩或防護鏡useshieldorgogglesifthereisthedangerofsplash使用適當?shù)暮粑鞣雷o灰塵,煙霧usesuitableairsupplyingtoprotectdustandfug在操作化學(xué)品時使用正確的手套usecorrectgloveswhenworkingonchemicals使用后正確地清潔和儲存?zhèn)€人防護用品cleanandstoragePPEcorrectlyafterusing不要把個人防護用品帶回家–為什么要把危險帶回家呢?nottakePPEhome–whytakedangerhome?保護自己-個人防護用品

Protectyourself-PPE34每種化學(xué)品和容器都必須合適地處置everychemicalandcontainermustbesuitabledisposed在徹底洗干凈前,容器并不是真的“空”了whetherthecontainerisemptyasfaraspossiblebeforebeingthoroughlycleaned根據(jù)環(huán)保法規(guī)要求處理使用過的容器disposetheusedcontaineraccordingtotherequestofenvironmentprotectionregulation依照BYC管理程序處理未使用的化學(xué)品disposetheuntappedchemicalsaccordingtotheBYCmanagementprocedure不要把未處理的化學(xué)品倒入水池、地表、雨水溝don’tpourthechemicalswithoutdisposalintopool,theearth’ssurfaceandthechannelofrainwater安全地處置化學(xué)品Safelydisposalwithchemicals35將不兼容的化學(xué)品分開儲存storageseparatelywithunincompatiblechemicals將易燃物的數(shù)量減少到最低reducet