1、九江有色金屬冶煉有限公司作業(yè)文件 文件名稱Agilent7500ICP-MS質(zhì)譜儀操作規(guī)程歸口部門(mén)分析檢測(cè)中心審批人宋金華發(fā)布日期2012/3/1文件編號(hào)QES/3034/分-2011受控狀態(tài)受控1、使用條件儀器應(yīng)放在穩(wěn)定的臺(tái)面。使用的電源電壓符合要求。要有合格的氬氣99.99%以上。1.4循環(huán)水的要求為：Flow=5L/Min.;溫度：15-20度.使用方法2、開(kāi)機(jī)：開(kāi)PC顯示器、打印機(jī)。開(kāi)PC主機(jī)。(password:3000hanover)2.1.3開(kāi)ICP-MS7500a電源開(kāi)關(guān)。(儀器前面的電源開(kāi)關(guān))2.1.4雙擊桌面的“ICP-MSTop”圖標(biāo)進(jìn)入工作站，如下圖所示：I圖所IJ、H

2、JI八口口J亠lJU1=4l-EXIO八、LJ-IVCIV/UUAAAI,JTV/、J2丄V_L丄、Z4_l_|JJM-l真空程序，儀器由Shutdown-Standby轉(zhuǎn)換。作業(yè)文件（最多可選5項(xiàng)）IF/BKPressure接口及背壓閥壓力。AnalyzerPressure分析器壓力。TMP分子渦輪泵。*轉(zhuǎn)換的時(shí)間較長(zhǎng)，一般30-60Min左右。2dMethodDEFAULT.MCalibrationDEFAULT.CC:ICPCHEM1METHODSC:ICPCHEM1CALIBGasWaterIS/CTemperature(L|p一聲IIBootoSettings.rWtrRF/WC/I

3、FWctcrRF/TPIWaterTemperaturefSlrt|_2_irPMSTopGFNERA.HouflnpLInl*tTempIExhaustTmplSequence|dEFAULT.SC:ICPCHEM1SEQUENCECattietGasPiessPGasPressOPQosTankPressArGasTankPressCanierGasMakeupGasOptionalGasPlasmaGasAuxGas諒Document-WofdPed1(PMSlnt-rurr-ntD：|lDLEH屋團(tuán)團(tuán)匝|陌畫(huà)畫(huà)圍曰?IntegrationTime:0.10secSamplingPeri

4、od:0.31secn:32廠AutoVert.RangeHelp|0ppb調(diào)諧液中1Count5549107995171Mean5748.110872.85080.6RSD毬3.092.282.38EJ。號(hào)將內(nèi)E標(biāo)管亦F放p兇m/z789205TiiTiiELD1ItHJUpt-ionalG-asiiiL/mininL/minrpsrpsTJTnTnL/IIIinL/mintoisOfEset!；QPEU白Octpole|OctPRF0ct-PBias|clickheretnbegin|idleTuneFile|Autotune.u-D:ICPCHEM17500elqSPlasmaPaiam

5、etersjiRFPowerhRFMatching!SmplDepth|Torch-H|-Torch-V；CarrierGas$Mak已upGasjh-OptionalGas；IJebulizerPumjhS：amplePiuap!；5/CiwIonLenses$Extract1Extract2!OiaegaBias-c已口皿已g日L已ns-c已；CellEnttiance$QPFocus|：CellExit.El-Q-PoleParamAMUGain1400丄耽E7.0-0-20-00.760.240.00.10U.LiO2129128LI.00023.4L-100.0-141-0-304E

6、-40Stop|7*StartICP-MSTop-GEN.D：點(diǎn)擊“靈敏度”圖標(biāo)，進(jìn)入靈敏度調(diào)諧畫(huà)面。如下圖所示，點(diǎn)擊“Acq.Parameters”菜單輸入采集的質(zhì)量數(shù)為7、89、205,156/140（CeO/Ce氧化物）,70/14（Ce2+/Ce雙電荷）,并選中“Plot”,“Channel”號(hào)點(diǎn)擊“OK”按鈕。點(diǎn)擊“Start”按鈕啟動(dòng)采集。點(diǎn)擊“Stop”按鈕停止采集。確認(rèn)靈敏度、氧化物、雙電荷是否達(dá)到表一的要求。否則調(diào)整參數(shù)。表spec.0.1amu0.1amu0.1amu65-08amuSensitiVtyLi:6400(01sec,10ppb)Y:16000Tl:9600Ox

7、ide(CeO/Ce)DoublyCharged(Ce2+/Ce)1.0%AnalogHVLPulseHV0.00.07Parameters8一0illV173口V10007WAutoVert.Rangen:37SamplingPeriod:0.62secfop”畫(huà)面的“ICP-MSInstrumentconsol”圖標(biāo)進(jìn)2.7.2點(diǎn)擊“ICP-MS入下xj圖戸所示的儀器控制畫(huà)面點(diǎn)擊滅火”MArGasTankSCarrierGasPisExhaustTem|kPaGkPaGdegCdegCStop|Help|HPlasmaParametersEl-IoilLarisesm/z789205156

8、/14070/140|lDLEz#Startl闔zsw.rtf-WordPad|JICP-MSTop-GENE.掌涉厲FO創(chuàng)迫口09:47TuneFileLtune.u一C:ICPCHEM17500SiaplDepth7.07-0“Torch-H0-口0-口TnTnTorch-V-0.2-0-2CarrierGas0.600-SOL/iainMakeupGas.5151IJebuliserPump0.100-10rps-Lamp丄uPump0.000.00rps-S/CTenp-2-2degChExt-ract.1Ejct-ract2Einzel1,3iEinselPOiasgs.Bias-Plat-eBias0-Q-PoleParanetersL-QPBiasSI：let-e匚匚-100.0-100.0V-Z3-23V-100-100V99V-30-30V0.00.078一017301000S/CTemperal2.7.3待轉(zhuǎn)換為“Standby”狀態(tài)后，點(diǎn)擊“ICP-MSTop”畫(huà)面的“ICP-MSInstrumentcontrol”圖標(biāo)，在下圖所示的儀器控制畫(huà)面。點(diǎn)擊“Vacuum”菜單，選擇“VACUUMOFF”進(jìn)行放真空程序儀器由StandbyShutdown轉(zhuǎn)換。2.7.4待轉(zhuǎn)換為“Shutdown”狀態(tài)后。2.8關(guān)Ar氣、循環(huán)水、排風(fēng)。2.9退出工作站，關(guān)PC、顯