電力設(shè)備金屬材料原子發(fā)射光譜分析技術(shù)導(dǎo)則II目 次前言 II1規(guī)性用1術(shù)和1儀2光分5光5分結(jié)及8分8附錄A（X9附錄B（資性火電廠用屬料學(xué)15附錄C（資性電用金材化3211電力設(shè)備金屬材料原子發(fā)射光譜分析技術(shù)導(dǎo)則范圍（GB/T4336 素鋼低合鋼多素量測定火放原發(fā)譜法(規(guī)法)GB/T7999 及鋁光電讀射譜析GB/T11170 GB11533 GB/T14203 GB/T38939 （）GB/T31364 XGB/T4793.1-2007測量控制和實(shí)驗(yàn)室用電氣設(shè)備的安全要求第1部分：通用要求GB/T18871-2002DL/T715 DL/T931 JJG768 YS/T482 JB/T12962.1能量色散X射線熒光光譜儀EJ/T684便攜式能量色散X射線熒光分析儀下列術(shù)語和定義適用于本文件。3.1電力設(shè)備electricalpowerequipment電力生產(chǎn)過程所需發(fā)電、輸電、配電設(shè)備的總稱，如鍋爐、汽機(jī)、管道、發(fā)電機(jī)、變壓器、線路、鐵塔、金具、風(fēng)力發(fā)電廠高強(qiáng)度螺栓等。3.2原子發(fā)射光譜分析atomicemissionspectrometry（AES）(以下簡稱光譜分析)22（3.3看譜鏡spectroscope3.4SparkOpticalEmissionSpectrometer(OES)（儀）CMOS/CCD3.5手持式能量色散X射線熒光光譜儀HandholdEDXRFspectrometer(以下簡稱：手持式光譜儀)采用小功率X射線管作為激發(fā)光源，用檢測器測量被激元素發(fā)射的特征X射線能量大小與相應(yīng)強(qiáng)度，進(jìn)行元素的定性、半定量分析的儀器。具有體積小、重量輕，人可手持測量的特點(diǎn)。3.6看譜定性分析qualitativespectralanalysisofspectroscope根據(jù)譜線識(shí)別被檢材料中事先指定的元素是否存在，但不確定其含量的分析方法。3.7看譜半定量分析semiquantitativespectralanalysisofspectroscope利用譜線亮度（強(qiáng)度）與元素含量的函數(shù)關(guān)系，粗略地確定被檢材料中某種成分大致含量的分析方法，其誤差一般在70%～130%之間。3.8手持式光譜儀半定量分析semiquantitativespectralanalysisofHandholdEDXRFspectrometerX1%～10%Mg10%～303.9定量分析quantitativespectralanalysis火花直讀光譜儀，根據(jù)譜線強(qiáng)度，準(zhǔn)確地測定被檢材料中某種成分含量?；娟P(guān)系式為：I=aCb，式中I為譜線強(qiáng)度，C為元素含量，a、b為常數(shù)。3.10標(biāo)準(zhǔn)樣品standardsample20100V1n，33XGB4793.1-200712.250mm的任何5μSv/h量不超過GB18871-2002B1.1.1.150mSv/年。XX(5cm)2s看譜鏡400nm～700nm3A～5A（GBW01328～GBW01333）4/5——Mn476.59476.64、487.13nm487.21、613.66613.77；——Mn476.59476.64、498.26nm498.33、507.92507.98。b)目視可見0.04%釩V(波長437.92nm)和0.25%硅Si(波長634.70nm)譜線。GB/T14203GB/T4336JJG768200nm～670nm（160nm～670nm）區(qū)域。2400條/mm～3600條JJG768X2W180eV。XJB/T12962.1EJ/T684中X射線熒光光譜儀的規(guī)定。44（/看譜鏡220VGB/T31364在XXX55光譜分析人員應(yīng)按DL/T931相關(guān)條款的規(guī)定，經(jīng)過培訓(xùn)及考試合格，方可從事與等級相應(yīng)的分析工作，并承擔(dān)相應(yīng)的技術(shù)責(zé)任?？醋V分析人員應(yīng)無色盲，無色弱，矯正視力在4.8以上（視力測定依據(jù)GB11533），采用5分記錄值）。從事光譜分析工作的人員，應(yīng)掌握相關(guān)安全防護(hù)知識(shí)。（Ⅲ）見附錄BC）（Ⅱ）ⅡAⅡB500kV666.26.3（0.25~0.124mm（60~120目）。16mm2mm。77（）（）（T91/P91、T92/P92））（）1/23GB/T14203GB/T4336GB/T11170GB/T7999YS/T482GB/T3893988（。手持式光譜儀分析方法詳見規(guī)范性附錄A?！?；”光譜分析報(bào)告應(yīng)包括以下內(nèi)容：ⅡAⅡBⅢ）99附錄A（規(guī)范性）電力設(shè)備常用金屬材料多元素含量的測定手持式能量色散X射線熒光光譜分析法范圍本方法規(guī)定了手持式能量色散X射線熒光光譜儀，測定電力設(shè)備常用鋼鐵材料中的鉻、鉬、釩、鎳、鎢、鈦、鈮、錳元素，鋁合金中的硅、鎂、銅、鋅、錳元素成分的原理、檢測方法和結(jié)果判定。本方法適用于手持式能量色散X射線熒光光譜儀，對電力設(shè)備常用鋼鐵材料中的鉻、鉬、釩、鎳、A.1A.2表A.1鋼鐵中各元素分析范圍元素名稱分析范圍a(質(zhì)量分?jǐn)?shù))%鉻(Cr)0.170~25.95鉬(Mo)0.176~8.37釩(V)0.127~1.87鎳(Ni)0.603~52.28鎢(W）0.489~17.45鈦(Ti)0.074~1.03鈮(Nb）0.048~5.14錳(Mn)0.800~18.70a規(guī)定的含量范圍表示已做過精密度試驗(yàn)，超范圍的分析可參照本方法。表A.2鋁合金中各元素分析范圍元素名稱分析范圍b(質(zhì)量分?jǐn)?shù))%硅(Si)0.160~7.82鎂(Mg)1.040~10.32銅(Cu)0.028~4.21鋅(Zn)0.087~6.00猛(Mn)0.066~0.60b規(guī)定的含量范圍表示已做過精密度試驗(yàn)，超范圍的分析可參照本方法。（GB/T6379.1 ）GB/T6379.2 （GB/T31364 X1010原理XXX被檢樣品的有效待測區(qū)域直徑應(yīng)大于儀器測量區(qū)域直徑，推薦待測區(qū)域直徑不小于10mm，樣。0.25mm5min。檢測cA6.1.2A6.1.23330s10-20s。必要時(shí)，如超分析范圍等，可選擇組成成分相近的標(biāo)準(zhǔn)樣品/標(biāo)準(zhǔn)物質(zhì)對待測樣品的測量結(jié)果進(jìn)行修正(見表A.3)。表A.3修正示例元素名稱標(biāo)準(zhǔn)樣品差值%樣品測量值%樣品修正值%認(rèn)證值%測量值%鎂2.082.22-0.142.32.161111/（≧1％）b)（<1％）50精密度25121017710r和再現(xiàn)性R的A.4。表A.4鋼鐵中元素分析重復(fù)性與再現(xiàn)性序號元素含量范圍m%重復(fù)性r/%再現(xiàn)性R/%1鉻(Cr)0.170~25.95lgr=0.4833lgm-1.4223lgR=0.7266gm-1.19392鉬(Mo)0.176~8.37r=0.0114m+0.0155R=0.0295m+0.03203釩(V)0.127~1.87lgr=0.4054lgm-1.3378R=0.0474m+0.04534鎳(Ni)0.603~52.28lgr=0.3751lgm-1.1925lgR=0.4949lgm-0.90145鎢(W）0.489~17.45lgr=0.3907lgm-1.1688R=0.0545m+0.02306鈦(Ti)0.074~1.03lgr=0.4366lgm-1.2231lgR=0.3861m-0.72177鈮(Nb）0.048~5.14lgr=0.4960lgm-1.4434lgR=0.6573gm-1.13018錳(Mn)0.800~18.70r=0.0099m+0.0535R=0.0391m+0.0802在重復(fù)性條件下，獲得的兩次測試結(jié)果的絕對差值不大于重復(fù)性限（，大于重復(fù)性限（）95%（（95%66810平的銅、6個(gè)水平的MnGB/T6379.1GB/T6379.2rRA.5。表A.5鋁合金中元素分析重復(fù)性與再現(xiàn)性序號元素含量范圍m%重復(fù)性限r(nóng)/%再現(xiàn)性限R/%1硅(Si)0.160~7.82r=0.138m+0.0308R=0.35m+0.0682鎂(Mg)1.040~10.32r=0.072m+0.52R=0.163m+0.6213銅(Cu)0.028~4.21r=0.0716m+0.00618R=0.158m+0.009674鋅(Zn)0.087~6.00r=0.0552m+0.0102R=0.141m+0.01015猛(Mn)0.066~0.60r=0.156m+0.0187R=0.0914m+0.0115在重復(fù)性條件下，獲得的兩次測試結(jié)果的絕對差值不大于重復(fù)性限（，大于重復(fù)性限（）95%（（1212況以95%的置信水平為前提。（%）1%13A.4或A.51.2r取31.2r1.3r個(gè)總和范圍內(nèi)（例如GB5310-2017中牌號為10Cr9Mo1VNbN材料的鋼管，Cr元素標(biāo)準(zhǔn)含量的要求為7.60-9.91%C表A.6精密度試驗(yàn)傳遞的鋼鐵標(biāo)準(zhǔn)樣品序號樣品名稱元素含量（質(zhì)量分?jǐn)?shù)）%鉻(Cr)鉬(Mo)釩(V)鎳(Ni)鎢(W)鈦(Ti)鈮(Nb)錳(Mn)1YSBS11253-2012(12CrMoV合金結(jié)構(gòu)鋼)0.560.3110.2230.018———0.6042YSBS11245-2012(25Cr2Mo1VA)2.331.030.4280.068———0.6413ZBGS013(35Cr2NiWMoV)1.910.4460.3771.291.20.081—0.7014YSBS11358-2017(22Cr12NiWMoV)11.550.980.2630.7251.01——0.885YSBS11381b-2012(TP310)24.50.1330.06119.330.1660.0631.066YSBS37387-16(ZG25Cr25Ni14Si2)19.780.9550.09414.19—0.0250.030.4257HLBS11028-2011(GCr1)25.950.5160.2810.777—0.0290.0110.6258HLBS11027-2011(GMn3)3.690.5260.0130.062———16.989HighChromiumCastIRON(GCr-2)13.570.3460.1750.559—0.020.0251.1810BPS3114Cr5MoSiV1(H130)5.31.181.040.15———0.411YSBS11484-2009W18Cr4V4.090.0761.120.07417.450.003—0.22712GSB03-2671-2011S17400(17-4PH)15.850.1950.0673.530.058—0.2020.69113GBW(E)0102191Cr13Ni2Mn16Cu212.240.0340.052.07———16.4814BPS3084Cr10Si2Mo10.530.7980.0510.346———0.42515BPS301W6Mo5Cr4V2Al4.315.11.870.186.18——0.316ZBG044合金鋼15CrMo0.9270.439—0.027———0.57117YSBS41306-2012不銹鋼304L(材字906）18.350.2090.0668.220.0240.00590.00950.8618YSBS11471-2010T80.318——0.301———0.42519YSBS41307a-2011不銹鋼321（1Cr18Ni9Ti)(材字907a)17.260.1930.0299.250.2230.2391.4720YSBS11472-2010T120.17——0.108———0.2221YSBS37265-1620Cr2Ni41.5—0.013.42———0.51122YSBS281034a-201731616.662.070.07510.160.0290.00240.0151.03131323YSBS11388-20061Cr21Ni5Ti20.970.0380.0455.330.3350.5440.61724YSBS281145-202020Cr1Mo1VNbTiB1.160.8260.5330.046—0.0740.140.46425YSBS41330a-2017（943a）P928.740.360.20.21.55——0.4426YSBS11274b-2010(35CrMo)20250.9510.176—0.011———0.55727YSBS352017-2020（15CrMo耐熱鋼）1.20.490.00460.037—0.0039—0.47628YSBS11356b-2019(10Cr9Mo1VNb)8.750.950.2120.133——0.0690.45729GSB03-1321-6-2021Cr18Ni13Mn2Mo3Ti17.032.730.02912.140.0130.35—1.330GSB03-2676-2011S32750(2507)(材字912）25.053.450.0496.380.018—0.0110.65931YSBS41502-2012Inconel625(材字916）20.698.37—63.72—0.0123.180.12432YSBS37284-18(35Mn2V)0.1270.0860.1270.145———1.5833HLBS11016-2010(QT500)0.650.340.260.89—0.11—0.5340.950.830.4970.176—0.175—0.43935GSB03-1063-2010B34.381.260.80.1480.496——0.84236YSBS2810266-201620CrNiMo0.4980.2420.0140.603—0.0029—0.74537YSBS35281-2019合金鋼（22Cr12NiMoWV）11.650.9460.2440.831——0.62538YSBS11391a-2012(05Cr17Ni4Cu4Nb)16.040.1070.0483.660.024—0.220.82439YSBS35306-2015(07Cr17Ni7Al)16.460.1910.0526.79———0.6940GSB03-1321-7-20100Cr18Ni9Ti17.80.0930.0238.710.00940.631—1.2541YSBS11370-2011(TP347H)17.930.2450.0999.66——0.4661.1242GSB03-1321-1-2021Cr5Ni234.040.00190.02622.430.00220.0016—0.57843YSBS41504-2012耐蝕合金Incoloy800(材字918）20.720.297—32.22—0.49—0.80744YSBS41503-2012鎳基高溫合金Inconel718(材字917）18.563.29—52.28—1.035.140.05745YSBS11586-2018(D)(P92)8.810.3820.1840.1611.670.00040.0480.33746YSBS41321-201020CrMnTi(材字931）1.190.0030.0060.032—0.046—1.0147YSBS20120A-5-201220MnVB0.0440.1010.0411.3648YSBS41116-2014Q3450.020.00110.0690.0180.0012—1.549GSB03-2672-2011S20100(201)(材字913）16.010.0520.0494.120.0055——7.9850BPS304214N21.140.0570.0663.92———9.3451HLBS11026-2011高錳鋼0.2580.1770.00420.057———13.4652BPS3024Cr4Mn184.03——0.06———17.153機(jī)字K18-358ZGMn18Cr220.2490.2010.5930.0770.0060.07718.71414表A.7精密度試驗(yàn)傳遞的鋁合金標(biāo)準(zhǔn)樣品序號樣品名稱元素含量（質(zhì)量分?jǐn)?shù)）%硅(Si)鐵(Fe)銅(Cu)錳(Mn)鎂(Mg)鉻(Cr)鎳(Ni)鋅(Zn)15A12（編號：YSS091-2016）(新)0.1610.1690.0410.69.30.0380.0760.14725083(編號：YSS086-2016)(新)0.2330.2370.1150.694.450.1740.0350.1573k6063d(新)0.4260.180.0790.0980.6420.0820.040.08746932(新)0.7270.4330.3970.1830.5220.1980.0210.055GSB04-2091-2208ZBY5015.560.0260.010.0850.1960.00510.00530.00646GSB04-2091-2208ZBY5067.820.4830.2750.3070.5780.1080.0910.3387N6061(新)0.6710.5790.2890.1141.040.3—0.0582933(新)0.3990.2963.960.3741.250.0790.0380.17492A12(E123b)(新)0.1290.3854.210.5441.55—0.0360.14310E323c0.260.3861.330.3162.080.1330.0354.9911E225b0.0990.0990.0120.0565.210.0490.00720.0212E235b0.040.110.0280.06610.320.00930.1340.03113E3151.531.870.9270.2872.26—0.1530.36714E41160.0280.1472.320.022.280.00730.0396155A12（編號：YSS091-2016）(新)0.1610.1690.0410.69.30.0380.0760.147C：標(biāo)準(zhǔn)值為個(gè)單位定值平均值的平均值，擴(kuò)展不確定度為：????=????????2 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√????ubb好，ults（）usts（）Snuchark95%k=2.1515附錄B（資料性）火力發(fā)電廠常用金屬材料化學(xué)成分表B.1汽水管道、聯(lián)箱和鍋爐受熱面管子常用金屬材料化學(xué)成分鋼 號化學(xué)成分（%）CMnSiCrMoVTiBWNiAlNb其它元素PS20GGB5310—20170.17～0.230.35～0.650.17～0.370.0250.01520MnGGB5310—20170.17～0.230.70～1.000.17～0.370.0250.01525MnGGB5310—20170.22～0.270.70～1.000.17～0.370.0250.01515MoGGB5310—20170.12～0.200.40～0.800.17～0.370.25～0.350.0250.01520MoGGB5310—20170.15～0.250.40～0.800.17～0.370.44～0.650.0250.01512CrMoGGB5310—20170.08～0.150.40～0.700.17～0.370.40～0.700.40～0.550.0250.01515CrMoGGB5310—20170.12～0.180.40～0.700.17～0.370.80～1.100.40～0.550.0250.01512Cr2MoGGB5310—20170.08～0.150.40～0.60≤0.502.00～2.500.90～1.130.0250.01512CrMoVGB3077—20150.08～0.150.40～0.700.17～0.370.30～0.600.25～0.350.15～0.30161612Cr1MoVGGB5310—20170.08～0.150.40～0.700.17～0.370.90～1.200.25～0.350.15～0.300.0250.01012Cr2MoGGB5310—20170.08~0.150.40~0.60≤0.502.00~2.500.90~1.130.0250.01512Cr2MoWVTiB(102)GB5310—20170.08～0.150.45～0.650.45～0.751.60～2.100.50～0.650.28～0.420.08～0.180.0020～0.00800.30～0.550.0250.01512Cr3MoVSiTiBGB5310—20170.09～0.150.50～0.800.60～0.902.50～3.001.00～1.200.25～0.350.22～0.380.0050～0.01100.0250.01510Cr9Mo1VNbN(T91/P91)GB5310—20170.08～0.120.30～0.600.20～0.508.00～9.500.85～1.050.18～0.25≤0.40≤0.0200.06～0.10N0.030～0.0700.0200.01007Cr2MoW2VNbBGB5310-20170.04～0.100.10～0.60≤0.501.90～2.600.05～0.300.20～0.300.0005～0.00601.45～1.75≤0.0300.02～0.08N≤0.0300.0250.01015Ni1MnMoNbCuGB5310-20170.10～0.170.80～1.200.25～0.50--0.25～0.50--------1.00～1.30≤0.0500.015～0.045N≤0.020Cu:0.50～0.800.0250.01510Cr9MoW2VNbBNGB5310-20170.07~0.130.30～0.60≤0.508.50~9.500.30~0.600.15~0.250.0010~0.00601.50~2.00≤0.40≤0.0200.04~0.09N:0.030~0.0700.0200.01010Cr11MoW2VNbCu1BNGB5310-20170.07~0.14≤0.70≤0.5010.00~11.500.25~0.600.15~0.300.0005~0.00501.50~2.50≤0.50≤0.0200.04~0.10N：0.040~0.100 ；Cu:0.30-1.700.0200.01011Cr9Mo1W1VNbBNGB5310-20170.09~0.130.30~0.600.10~0.508.50~9.500.90~1.100.18~0.250.0003~0.00600.90~1.10≤0.40≤0.0200.06~0.100.040~0.0900.0200.01010Cr18Ni9NbCu3BNGB5310-20170.07~0.13≤1.00≤0.3017.00~19.000.0010~0.01007.50~10.500.003~0.0300.30~0.60N：0.050~0.12;Cu:2.50~3.500.0300.01007Cr25Ni21GB5310-20170.04~0.10≤2.00≤0.7524.00~26.0019.00~22.000.0300.01507Cr25Ni21NbNGB5310-20170.04~0.10≤2.00≤0.7524.00~26.0019.00~22.000.20~0.600.150~0.3500.0300.015171707Cr19Ni11TiGB5310-20170.04~0.10≤2.00≤0.7517.00~20.004C~0.609.00~13.000.0300.01507Cr18Ni11NbGB5310-20170.04~0.10≤2.00≤0.7517.00~19.009.00~13.008C~1.100.0300.01508Cr18Ni11NbFGGB5310-20170.06~0.10≤2.00≤0.7517.00~19.0010.00~12.008C~1.100.0300.01515Cr1Mo1V15X1M1(OCT4543)0.08～0.150.40～0.700.17～0.370.90～1.201.00～1.200.15～0.25≤0.035≤0.03510CrMo910DIN17155-19830.06～0.150.40～0.70≤0.502.00～2.500.90～1.10≤0.035≤0.030X20GrMoV121(F12)DIN17155-19830.17～0.23≤1.00≤0.5010.00～12.500.80～1.200.25～0.350.30～0.80≤0.030≤0.030A106BASTMA335≤0.300.29～1.06≤0.10≤0.058≤0.048A106CASTMA335≤0.350.29～1.06≤0.10≤0.058≤0.048A335P11ASTMA335≤0.150.30～0.600.50～1.001.00～1.500.44～0.65≤0.030≤0.030A335P12ASTMA335≤0.300.30～0.61≤0.500.80～1.250.44～0.65≤0.045≤0.045A335P22ASTMA335≤0.150.30～0.60≤0.501.90～2.600.87～1.13≤0.030≤0.03015NiCuMoNb5(WB36)B-No.61119880.10～0.170.80～1.200.25～0.50≤0.0300.25～0.50------Cu0.50～0.801.00～1.30≤0.0500.015～0.045N≤0.020≤0.025≤0.03010Cr5MoWVTiB(G106)首鋼技術(shù)條件0.07～0.120.45～0.750.40～0.704.50～6.000.48～0.650.20～0.330.16～0.240.008～0.0140.20～0.40≤0.030≤0.03018181Cr9Mo1(X12CrMo91)德國曼內(nèi)斯曼鋼廠材料規(guī)范≤0.150.30～0.600.25～1.008.00～10.000.90～1.10≤0.030≤0.0301Cr9Mo2(HCM9M)≤0.080.30～0.70≤0.508.00～10.001.80～2.20≤0.030≤0.0301Mn17Cr7MoVNbBZr(17-7MoV)0.05～0.1217.00～19.000.50～0.807.00～9.000.80～1.100.25～0.450.005～0.012Zr0.080.30～0.50≤0.030≤0.03512Cr18Ni9(舊1Cr18Ni9）GB/T1220—20070.152.001.0017.00～19.008.00～10.00N:0.100.0450.03007Cr19Ni10GB5310—20170.04~0.10≤2.00≤0.7518.00~20.008.00~11.00≤0.030≤0.0151Cr18Ni9TiGB1220—1992≤0.12≤2.00≤1.0017.00～19.005×(C-0.02)～0.88.00～11.00≤0.030≤0.035TP316ASMESA-213≤0.08≤2.00≤0.7516.0～18.02.00～3.0011.0～14.0≤0.030≤0.040TP321ASMESA-213≤0.08≤2.00≤0.7517.0～20.0≥5×C%～0.69.00～13.0≤0.030≤0.040T23(HCM2S)ASMESA-2130.04～0.100.10～0.60≤0.501.90～2.600.05～0.300.20～0.300.0005～0.0061.45～1.75≤0.0300.02～0.08N≤0.40≤0.010≤0.03T92(NF616)ASMESA-2130.07～0.130.30～0.60≤0.508.50～9.500.30～0.600.15～0.250.001～0.0061.5 ～2.00≤0.40≤0.040.04～0.09N0.03～0.07≤0.010≤0.020T122(HCM12A)ASMESA-2130.07～0.14≤0.07≤0.5010.00～12.500.25～0.600.15～0.300.0005～0.0061.50～2.50≤0.50≤0.0400.04～0.10N0.040～0.100Cu0.30～1.70≤0.010≤0.020TP304HASMESA-2130.04～0.10≤2.00≤0.7518.00～20.008.00～11.00≤0.030≤0.040TP347HASMESA-2130.04～0.10≤2.00≤0.7517.0～20.09.00～13.00Nb＋Ta≥8×C%～1.00≤0.030≤0.0401919TP347HFGASMESA-2130.06～0.10≤2.00≤0.7517.0～20.09.00～13.00Nb＋Ta≥8×C%～1.00≤0.030≤0.040TP310HNbN(HR3C)ASMESA-2130.04～0.10≤2.00≤0.7524.00～26.0017.00～23.00Nb＋Ta0.20～0.60N0.15～0.35≤0.030≤0.030表B.2鍋爐鍋筒、分離器常用金屬材料化學(xué)成分鋼號化學(xué)成分（%）CMnSiCrMoVTiNiCuAlWNbSPSB49JISG3103板厚＜25mm＜0.31＜0.900.15～0.30≤0.040≤0.035板厚25～50mm＜0.33板厚50～＜0.35200mm11474CSN411474≤0.22≥0.70≤0.35≥0.03≤0.30≤0.30≤0.70≤0.04≤0.0419Mn6寶鋼技術(shù)條件0.15～0.221.00～1.600.30～0.60≤0.15≤0.10≤0.03≤0.03≤0.15≤0.150.02≤0.03≤0.035板厚≤25.4mm≤0.280.84～0.13～≤0.040≤0.035A2991.520.45板厚≥25.4mm≤0.30≤0.040≤0.035ASTMA299-19860.84～0.13～1.620.4515NiMnMoNbCuGB5310-20170.10~0.170.80~1.200.25~0.500.25~0.501.00~1.300.50~0.80≤0.050N≤0.0200.015~0.0450.0150.02515CrMoGGB5310-20170.12~0.180.40~0.700.17~0.370.80~1.100.40~0.550.0150.02510Cr9Mo1VNbNGB5310-20170.08~0.120.30~0.600.20~0.508.00~9.500.85~1.050.18~0.25≤0.40≤0.020N0.0700.06~0.100.0100.020BHW35(德國梯森鋼鐵公司規(guī)范）≤0.151.00～1.600.10～0.500.20～0.400.20～0.400.60～1.00～0.01≤0.025≤0.02516ΓHM0.12～0.200.7～0.90.17～0.37≤0.300.4～0.551.0～1.5≤0.040≤0.0352020OCT108030118-7818MnMoNbRGB713—2014≤0.211.20～1.600.15～0.50≤0.300.45～0.65≤0.30≤0.300.025～0.050≤0.010≤0.02018MnMoNbJB1270—20140.16～0.221.20～1.500.20～0.400.45～0.600.020～0.045≤0.010≤0.012Q245RGB713—2014≤0.200.50~1.10≤0.35≤0.30≤0.08≤0.050≤0.030≤0.30≤0.30≥0.020≤0.050≤0.010≤0.025Q345RGB713—2014≤0.201.20~1.70≤0.55≤0.30≤0.08≤0.050≤0.030≤0.30≤0.30≥0.020≤0.050≤0.010≤0.025表B.3鍋爐受熱面固定件和吹灰器常用金屬材料化學(xué)成分鋼 號化學(xué)成分（%）CMnSiAlTiNiCrMoNSP12Cr5MoGB1221—20070.150.600.500.604.00～6.000.40～0.600.0300.04042Cr9Si2GB1221—20070.35～0.500.702.00～3.000.608.00～10.000.0300.03516Cr20Ni14Si2GB1221—20070.201.501.50～2.5012.00～15.0019.00～22.000.0300.04016Cr25Ni20Si2GB1221—20070.201.501.50～2.5018.00～21.0024.00～27.000.0300.04026Cr18Mn12Si2NGB1221—20070.22～0.3010.50～12.501.40～2.2017.00～19.000.22～0.330.0300.05022Cr20Mn10Ni2Si2NGB1221—20070.17～0.268.50～11.001.80～2.702.00～3.0018.00～21.000.20～0.300.0300.0502121表B.4 鍋爐架用屬料學(xué)成分鋼 號化學(xué)成分（%）CMnSiSPNiCrAlNbCuVQ235GB700—2006Q235A級(A3)≤0.22≤1.40≤0.35≤0.050≤0.045Q235B級≤0.20≤1.40≤0.35≤0.045≤0.045Q235C級≤0.17≤1.40≤0.35≤0.040≤0.040Q235D級≤0.17≤1.40≤0.35≤0.035≤0.035Q355(代替Q345）GB/T1591—2018B0.241.600.55≤0.035≤0.0350.300.300.40C（公稱壁厚或直徑/mm≤40）0.20≤0.030≤0.030C（公稱壁厚或直徑/mm＞40）0.22≤0.030≤0.030D（公稱壁厚或直徑/mm≤40）0.20≤0.025≤0.025D（公稱壁厚或直徑/mm＞40）0.22≤0.025≤0.02511523CSN411523+a≤0.20≤1.60≤0.55≤0.045≤0.050≤0.60≥0.0015SM50BJISG3106板厚＜50mm0.18＜1.50＜0.55＜0.040＜0.040板厚50～100mm0.2015MnVBGB3077—20150.12～0.181.20～1.600.17～0.370.07～0.12SM41B板厚＜50mm＜0.200.60～1.20＜0.35＜0.040＜0.040板厚50～100mm＜0.220.60～1.20＜0.35＜0.040＜0.0402222SM53C板厚＜50mm＜0.20＜1.50＜0.55＜0.040＜0.040ASTM—A36型鋼0.26＜0.05＜0.04板厚≤19mm0.25＜0.05＜0.04板厚19～38mm0.250.80～1.20＜0.05＜0.04板厚38～64mm0.260.80～1.200.15～0.40＜0.05＜0.04板厚64～102mm0.270.80～1.200.15～0.40＜0.05＜0.04板厚＞102mm0.290.80～1.200.15～0.40＜0.05＜0.04表B.5汽輪機(jī)主軸、轉(zhuǎn)子體、輪盤與葉輪及汽輪發(fā)電機(jī)轉(zhuǎn)子和無磁性護(hù)環(huán)常用金屬材料化學(xué)成分鋼 號化學(xué)成分（%）CSiMnSPNiCrMoVCuAlWB備注35GB/T699-20150.32~0.390.17~0.370.50~0.80≤0.035≤0.035≤0.30≤0.25≤0.2540GB/T699-20150.37~0.440.17~0.370.50~0.80≤0.035≤0.035≤0.30≤0.25≤0.2545GB/T699-20150.42～0.500.17～0.370.50～0.80≤0.035≤0.035≤0.30≤0.25≤0.2540CrGB/T3077-20150.37～0.440.17～0.370.50～0.800.80～1.1035SiMnGB/T3077-20150.32～0.401.10～1.401.10～1.4035CrMo0.32～0.17～0.40～0.80～0.15～2323GB/T3077-20150.400.370.701.100.2535CrMoVGB/T3077-20150.30～0.380.17～0.370.40～0.701.00～1.300.20～0.300.10～0.2034CrMo1JB/T1265-20140.30~0.38Sia0.17~0.370.40~0.70≤0.020≤0.020≤0.400.70~1.200.40~0.55≤0.2030Cr1Mo1VJB/T1265-20140.27～0.340.20～0.350.70～1.00≤0.012≤0.012≤0.501.05～1.351.00～1.300.21～0.29≤0.15≤0.01028CrMoNiVJB/T1265-20140.25～0.30≤0.300.30～0.80≤0.012≤0.0120.50～0.751.10～1.400.80～1.000.25～0.35≤0.20≤0.01034CrNi3MoJB/T1265-2014≤0.400.17～0.370.50～0.80≤0.018≤0.0152.75～3.250.70～1.100.25～0.40≤0.2025CrNi1MoVJB/T1267-20140.22～0.28≤0.30≤0.70≤0.018≤0.0151.00～1.501.00～1.500.25～0.400.05～0.15≤0.2025Cr2Ni1Mo1VJB/T11030-20100.21～0.29≤0.100.10～0.37≤0.010≤0.0101.10～1.502.00～2.501.00～1.300.20～0.30≤0.10≤0.008As≤0.010Sn≤0.010Sba≤0.001530Cr2Ni4MoVJB/T1265-2014≤0.35≤0.100.20~0.40≤0.010≤0.0103.25~3.751.50~2.000.30~0.600.07~0.15≤0.15≤0.01025Cr2NiMoVSQB40.320.22～0.280.15～0.350.70～0.90≤0.018≤0.0151.00～1.501.00～1.500.25～0.400.05～0.15≤0.2012Cr10NiMoWVNbNJB/T11019-20100.11~0.13≤0.120.40~0.50≤0.008≤0.0120.70~0.8010.20~10.601.00~1.100.15~0.25≤0.0100.95~1.050N0.060Nb0.04~0.0713Cr10NiMoVNbNJB/T11019-20100.10~0.16≤0.10≤1.00≤0.015≤0.015≤1.0010.00~11.001.30~1.600.12~0.22≤0.010N0.03~0.07Nb0.03~0.0814Cr10NiMoWVNbNJB/T11019-20100.12~0.16≤0.100.40~0.70≤0.010≤0.0150.60~1.009.50~11.500.90~1.200.15~0.25≤0.0100.80~1.20N0.04~0.08Nb0.03~0.1215Cr10NiMoWVNbNJB/T11019-20100.13~0.16≤0.070.40~0.70≤0.010≤0.0150.40~0.7010.00~11.001.15~1.350.15~0.20≤0.0100.25~0.40N0.03~Nb0.04~24240.070.0750Mn18Cr4WNJB/T1268-20140.40～0.600.30～0.8017.00～19.00≤0.025≤0.0600.083.00～5.000.70～1.20N≥0.081Mn18Cr18NJB/T1268-2014≤0.12≤0.8017.50～20.00≤0.015≤0.05017.50～20.00≤0.0301Mn18Cr18NJB/T7030-2014≤0.12≤0.8017.50～20.00≤0.015≤0.05017.50～20.00≤0.030≤0.001N≥0.47表B.6汽輪機(jī)與燃?xì)廨啓C(jī)葉片常用金屬材料化學(xué)成分鋼 號化學(xué)成分（%）CSiMnPSNiCrMoVWCuNNbBAlTiCeZr20CrMoGB3077-20150.17～0.240.17～0.370.40～0.700.80～1.100.15～0.251Cr12GB1220-20070.150.501.000.0400.030(0.60)11.50～13.0012Cr12MoGB1221-20070.10～0.150.500.30～0.500.0350.0300.30～0.6011.50～13.000.30～0.600.3006Cr13GB1220-20070.081.001.000.0400.030(0.60)11.50～13.5012Cr13GB1221-20070.08～0.151.001.000.0400.030(0.60)11.50～13.5013Cr13MoGB1221-20070.08～0.180.601.000.0400.030(0.60)11.50～14.000.30～0.6020Cr13GB1221-20070.16～0.251.001.000.0400.030(0.60)12.00～14.0014Cr11MoVGB1221-20070.11～0.180.500.600.0350.0300.6010.00～11.500.50～0.700.25～0.40252515Cr12WMoV(ЭИ802)GB1221-20070.12～0.180.500.50～0.900.0350.0300.40～0.8011.00～13.000.50～0.700.15～0.300.70～1.1018Cr11NiMoNbVNGB1221-20070.15～0.200.500.50～0.800.0300.0250.30～0.6010.00～12.000.60～0.900.20～0.300.04～0.090.20～0.600.302Cr12MoVGB8732-20140.18～0.240.10～0.500.30～0.80≤0.030≤0.0200.30～0.8011.00～12.500.80～1.200.25～0.35≤0.3014Cr17Ni2GB1221-20070.11～0.170.800.800.0400.0301.50～2.5016.00～18.0018Cr12MoVNbNGB1221-20070.15～0.200.500.50～1.000.0350.030(0.60)10.00～13.000.30～0.900.10～0.400.05～0.100.20～0.6022Cr12NiMoWV(C-422)GB1221-20070.20～0.250.500.50～1.000.0400.0300.50～1.0011.00～13.000.75～1.250.20～0.400.75～1.252Cr12WMoVNbB(ЭИ993)YB/Z8-19750.15～0.22≤0.50≤0.50≤0.030≤0.0250.6011.00～13.000.40～0.600.15～0.300.40～0.700.20～0.40≤0.0030Cr14Ni40W4Mo2Ti3A12BZr(302合金)≤0.08≤0.60≤0.60≤0.020≤0.01038.00～42.0012.00～16.001.50～2.503.50～4.500.0101.80～2.302.30～3.000.0200.0500Cr15Ni35W3Ti3AlB(ЭИ787)≤0.08≤0.60≤0.60≤0.020≤0.01033.00～37.0014.00～16.002.00～4.000.0300.70～1.702.40～3.2005Cr17Ni4Cu4Nb(17-4PH)GB1221-20070.071.001.000.0400.0303.00～5.0015.50～17.503.00～5.000.15～0.45Refractaloy-26≤0.08≤1.50≤1.00≤0.030≤0.03035.00～39.0016.00～20.002.50～3.502.50～3.0018.00～22.00≤0.250.001～0.011Cr14Ni8W2NbBCe(ЭИ726)0.08～0.12≤0.601.00～2.00≤0.020≤0.02018.00～20.0013.00～15.002.00～2.750.90～1.30≤0.025≤0.021Cr15Ni36W3Ti(ЭИ612)GB1221-1992≤0.12≤0.801.00～2.00≤0.030≤0.03034.00～38.0014.00～16.002.80～3.201.00～1.401Mn18Cr10MoVB(K9)0.12～0.170.30～0.7017.00～19.00≤0.035≤0.0359.50～11.500.40～0.600.70～0.900.032626表B.7緊固件常用金屬材料化學(xué)成分鋼 號化學(xué)成分（%）CSiMnSPNiCrMoVCuTiCoWAlNbBFeMgZr35GB699—20150.32～0.390.17～0.370.50～0.80≤0.035≤0.035≤0.30≤0.25≤0.2545GB699—20150.42～0.500.17～0.370.50～0.80≤0.035≤0.035≤0.30≤0.25≤0.2535SiMnGB3077—20150.32～0.401.10～1.401.10～1.4035CrMoGB3077—20150.32～0.400.17～0.370.40～0.700.80～1.100.15～0.2525Cr2MoVAGB3077—20150.22～0.290.17～0.370.40～0.701.50～1.800.25～0.350.15～0.3025Cr2Mo1VAGB3077—20150.22～0.290.17～0.370.50～0.802.10～2.500.90～1.100.30～0.5035CrMoAGB/T20410-20060.32～0.400.17～0.370.40～0.70≤0.025≤0.025≤0.300.80～1.100.15～0.25≤0.2542CrMoAGB/T20410-20060.38～0.450.17～0.370.50～0.80≤0.025≤0.025≤0.300.90～1.200.15～0.25≤0.2525Cr2MoVAGB/T20410-20060.22～0.290.17～0.370.40～0.70≤0.025≤0.025≤0.301.50～1.800.25～0.350.15～0.30≤0.2525Cr2Mo1VAGB/T20410-20060.22～0.290.17～0.370.50～0.80≤0.025≤0.025≤0.302.10～2.500.90～1.100.30～0.50≤0.2545Cr1MoVAGB/T20410-20060.42～0.500.20～0.350.45～0.70≤0.025≤0.025≤0.300.80～1.150.45～0.650.25～0.35≤0.25≤0.01520Cr1Mo1V1A0.18≤0.35≤0.50≤≤≤0.601.000.800.70≤0.252727GB/T20410-2006～0.250.0250.025～1.30～1.10～1.1020Cr1Mo1VTiBGB/T20410-20060.17～0.230.40～0.600.40～0.65≤0.025≤0.025≤0.300.90～1.300.75～1.000.45～0.65≤0.250.16～0.280.001~0.00520Cr1Mo1VNbTiBGB/T20410-20060.17～0.230.40～0.600.40～0.65≤0.025≤0.025≤0.300.90～1.300.75～1.000.50～0.70≤0.250.05～0.140.11～0.220.001~0.0042Cr12WMoVNbBYB/Z8—19750.15～0.22≤0.50≤0.50≤0.025≤0.030≤0.6011.00～13.000.40～0.600.15～0.300.40～0.700.20～0.40≤0.0032Cr12NiMo1W1VGB/T20410-20060.20～0.25≤0.500.50～1.10≤0.025≤0.0300.50～1.0011.00～12.500.90～1.250.20～0.30≤0.250.90～1.25Refractaloy-26≤0.08≤1.50≤1.00≤0.030≤0.03035.00～39.0016.00～20.002.50～3.502.50～3.0018.00～22.00≤0.250.001～0.01GH145≤0.08≤0.35≤0.35≤0.015≤0.010≥7014.0～17.0≤0.502.25～2.75≤1.000.40～1.000.70～1.20≤0.0105.00～9.00≤0.010≤0.050表B.8汽輪機(jī)、鍋爐常用鑄鋼化學(xué)成分鋼 號化學(xué)成分（%）CSiMnPSCrNiMoVWNbNAlZG12Cr9Mo1VNbNJB/T11018-20100.11～0.140.20～0.500.40～0.80≤0.020≤0.0108.00～9.50≤0.400.90～1.050.18～0.250.05～0.080.040～0.060≤0.020ZG11Cr10MoVNbNJB/T11018-20100.09～0.13≤0.70≤0.80≤0.030≤0.0109.10～10.00.40～0.700.65～1.000.13～0.200.03～0.070.030～0.070≤0.025ZG13Cr11MoVNbNJB/T11018-20100.11～0.150.20～0.600.30～0.60≤0.025≤0.0259.50～11.500.40～0.700.70～1.000.20～0.300.05～0.200.030～0.060ZG14Cr10MoVNbNJB/T11018-20100.12～0.160.20～0.350.50～0.70≤0.020≤0.0209.60～10.600.30～0.600.70～1.000.20～0.25Sn≤0.05(目標(biāo)）0.07～0.130.030～0.060≤0.010ZG11Cr10Mo1NiVNbNJB/T11018-20100.09～0.14≤0.300.40～0.70≤0.020≤0.02010.00～11.000.40～0.701.00～1.300.15～0.250.20～0.300.04～0.080.030～0.070≤0.010Sn≤0.052828ZG12Cr10Mo1W1VNbN-1JB/T11018-20100.11～0.140.20～0.400.80～1.20≤0.020≤0.0109.20～10.200.60～0.800.90～1.050.18～0.250.95～1.050.05～0.080.040～0.060≤0.020ZG12Cr10Mo1W1VNbN-2JB/T11018-20100.11～0.140.20～0.400.80～1.00≤0.020≤0.0109.10～10.000.50～0.750.90～1.050.18～0.250.95～1.050.04～0.080.040～0.070≤0.020Cu≤0.10Sn≤0.015As≤0.025Sb≤0.001ZG12Cr10Mo1W1VNbN-3JB/T11018-20100.11～0.140.20～0.500.40～1.20≤0.020≤0.0109.20～10.200.60～0.800.90～1.050.17～0.250.95～1.050.05～0.100.030～0.060ZG230-450JB/T10087-2016≤0.30≤0.50≤0.90≤0.030≤0.030WCBJB/T12229-20050.300.601.000.040.0450.500.500.250.03WC1JB/T5263-2005≤0.25≤0.600.50-0.80≤0.035≤0.040≤0.35≤0.500.45-0.65ZG15Cr1MoJB/T10087-2016≤0.20≤0.600.50～0.80≤0.030≤0.0301.00～1.500.45～0.65ZG20CrMoJB/T10087-20160.15～0.250.20～0.600.50～0.80≤0.030≤0.0300.50～0.800.40～0.60ZG15Cr1Mo1VJB/T10087-20160.12~0.200.20~0.600.40~0.70≤0.030≤0.0301.20~1.700.90~1.200.20~0.40ZG15Cr2Mo1JB/T10087-2016≤0.18≤0.600.40～0.70≤0.030≤0.0302.00～2.750.90～1.20≤0.025ZG20CrMoVJB/T10087-20160.18～0.250.20～0.600.40～0.70≤0.030≤0.0300.90～1.200.50～0.700.20～0.30ZG10Cr9Mo1VNbNJB/T11018-20100.08～0.120.20～0.500.30～0.60≤0.020≤0.0108.00～9.50≤0.400.80～1.050.18～0.250.06~0.100.030~0.070≤0.040C?N422712捷克鋼號0.17～0.250.20～0.500.80～1.40≤0.050≤0.050≤0.30≤0.40C?N4227430.11～0.20～0.45～≤0.045≤0.0450.50～≤0.300.20～0.20～2929捷克鋼號0.190.500.700.700.350.35C?N422744捷克鋼號0.11～0.180.20～0.500.45～0.70≤0.045≤0.0450.50～0.70≤0.400.40～0.600.20～0.35C?N422745捷克鋼號0.11～0.190.20～0.500.45～0.70≤0.035≤0.0350.40～0.60≤0.400.85～1.050.20～0.35表B.9常用彈簧鋼化學(xué)成分鋼 號化學(xué)成分（%）CSiMnPSCrNiMoWVCub65GB1222—20160.62～0.700.17～0.370.50～0.80≤0.030≤0.030≤0.25≤0.35≤0.2570GB1222—20160.67～0.750.17～0.370.50～0.80≤0.030≤0.030≤0.25≤0.35≤0.2585GB1222—20160.82～0.900.17～0.370.50～0.80≤0.030≤0.030≤0.25≤0.35≤0.2565MnGB1222—20160.62～0.700.17～0.370.90～1.20≤0.030≤0.030≤0.25≤0.35≤0.2560Si2MnGB1222—20160.56～0.641.50～2.000.70～1.00≤0.025≤0.020≤0.35≤0.35≤0.2560Si2CrGB1222—20160.56～0.641.40～1.800.40～0.70≤0.025≤0.0200.70～1.00≤0.35≤0.2555SiMnVBGB1222—20160.52～0.600.70～1.001.00～1.30≤0.025≤0.020≤0.35≤0.35B0.0008～0.00350.08～0.16≤0.2550CrVGB1222—20160.46～0.540.17～0.370.50～0.80≤0.025≤0.0200.80～1.10≤0.350.10～0.20≤0.25303030W4Cr2VGB1222—20160.26～0.340.17～0.37≤0.40≤0.025≤0.0202.00～2.50≤0.354.00～4.500.50～0.80≤0.253Cr13GB1220—20070.26～0.351.001.000.0400.03012.00～14.00(0.60)4Cr13GB1220—20070.36～0.450.600.800.0400.03012.00～14.00(0.60)0Cr17Ni7AlGB1221—20070.091.001.000.0400.03016.00～18.006.50～7.75Al0.75～1.50Inconel≤0.08≤0.50≤1.00Fe5.00～9.0014.00～17.00≥70.00Nb0.70～1.20Ti2.25～2.75Al0.40～1.00≤0.50表B.10凝汽器常用金屬材料化學(xué)成分鋼 號化學(xué)成分（%）CSiMnPSCrNiMoWVCu06Cr19Ni10GB/T20878-20070.081.002.000.0450.03018.00~20.008.00~10.00022Cr19Ni10GB/T20878-20070.0301.002.000.0450.03018.00~20.008.00~12.0006Cr18Ni11TiGB/T20878-20070.081.002.000.0450.03017.00~19.009.00~12.00Ti5C~0.7006Cr17Ni12Mo2GB/T20878-20070.081.002.000.0450.03016.00~18.0010.00~14.002.00~3.00022Cr17Ni12Mo2GB/T20878-20070.0301.002.000.0450.03016.00~18.0010.00~14.002.00~3.0006Cr19Ni13Mo3GB/T20878-20070.081.002.000.0450.03018.00~20.0011.00~15.003.00~4.00022Cr19Ni13Mo3GB/T20878-20070.0301.002.000.0450.03018.00~20.0011.00~15.003.00~4.003131表B.11壓力容器常用金屬材料化學(xué)成分鋼 號化學(xué)成分（%）CSiMnCuNiCrMoNbVTiAltbPS其它Q245RGB713-2014≤0.20≤0.350.50～1.10≤0.30≤0.30≤0.30≤0.08≤0.050≤0.050≤0.030≥0.020≤0.025≤0.010Cu+Ni+Cr+Mo≤0.70Q345RGB713-2014≤0.20≤0.551.20～1.70≤0.30≤0.30≤0.30≤0.08≤0.050≤0.050≤0.030≥0.020≤0.025≤0.010Cu+Ni+Cr+Mo≤0.7015CrMoRGB713-20140.08~0.180.15~0.400.40～0.70≤0.30≤0.300.80~1.200.45~0.60≤0.025≤0.01013MnNiMoRGB713-2014≤0.150.15~0.501.20～1.60≤0.300.60～1.000.20～0.400.20～0.400.005～0.020≤0.020≤0.0103232附錄C（資料性）電網(wǎng)常用金屬材料化學(xué)成分表C.1電網(wǎng)常用變形鋁及鋁合金化學(xué)成分牌號化學(xué)成分（%）SiFeCuMnMgCrNiZnVTiAl1035GB/T3190-20200.350.60.100.050.050.100.050.0399.351040GB/T319