一、常見(jiàn)重點(diǎn)問(wèn)題答疑I.AnswerstoFrequentlyAskedKeyQuestions1.請(qǐng)分別定義凈化的原料和產(chǎn)品，并列舉硫酸鋅溶液凈化中產(chǎn)品的兩種主要類型及其核心特點(diǎn)。1.Pleasedefinetherawmaterialsandproductsforpurificationrespectively,andlistthetwomaintypesofproductsinzincsulfatesolutionpurificationandtheircorecharacteristics.解答：（1）凈化的原料：指通過(guò)各種浸出過(guò)程得到的金屬化合物溶液，是凈化工序的處理對(duì)象（如硫酸鋅中性浸出液）。Answer:(1)Rawmaterialsforpurification:Refertothemetalcompoundsolutionobtainedthroughvariousleachingprocesses,whichisthetreatmentobjectofthepurificationprocess(suchaszincsulfateneutralleachingsolution).（2）凈化的產(chǎn)品：指經(jīng)凈化處理后得到的物質(zhì)，主要包括兩類：(2)Purifiedproducts:Refertothesubstancesobtainedafterpurificationtreatment,mainlyincludingtwocategories:①凈化液：滿足后續(xù)工序（如電積）要求的溶液，核心特點(diǎn)是主體金屬濃度穩(wěn)定（如硫酸鋅凈化液中Zn130-180g/L）、雜質(zhì)含量低于限值（如Cu≤0.5mg/L、Co≤3mg/L）。①Purificationsolution:Asolutionthatmeetstherequirementsofsubsequentprocesses(suchaselectrowinning).Thecorefeaturesarethattheconcentrationofthemainmetalisstable(suchasZn130-180g/Linthezincsulfatepurificationsolution)andtheimpuritycontentislowerthanthelimitvalue(suchasCu≤0.5mg/L,Co≤3mg/L).②凈化渣：含有被去除的雜質(zhì)或可回收有價(jià)金屬的固體殘?jiān)?，核心特點(diǎn)是富集特定雜質(zhì)（如Cu-Cd渣、鈷渣），具有回收利用價(jià)值。②Purificationslag:Referstosolidresiduecontainingremovedimpuritiesorrecoverablevaluablemetals.Itscorefeatureistoenrichspecificimpurities(suchasCu-Cdslagandcobaltslag),whichhasrecyclingvalue.2.某硫酸鋅中性浸出液的成分如下：Zn150g/L、Cu0.8g/L、Cd0.5g/L、Ca2.0g/L、Cl0.3g/L。請(qǐng)說(shuō)明該原料的成分特點(diǎn)，對(duì)比鋅電積對(duì)凈化后液的典型標(biāo)準(zhǔn)，并對(duì)其中的雜質(zhì)進(jìn)行分類。2.Thecomponentsofazincsulfateneutralleachingsolutionareasfollows:Zn150g/L,Cu0.8g/L,Cd0.5g/L,Ca2.0g/L,Cl0.3g/L.Pleaseexplainthecompositioncharacteristicsofthisrawmaterial,comparethetypicalstandardofzincelectrowinningforpurifiedliquid,andclassifytheimpuritiesinit.解答：（1）原料成分特點(diǎn)：主體金屬為Zn（150g/L），含有多種雜質(zhì)（Cu、Cd、Ca、Cl等），雜質(zhì)濃度遠(yuǎn)高于后續(xù)工序要求。Answer:(1)Characteristicsofrawmaterialcomposition:ThemainmetalisZn(150g/L),whichcontainsavarietyofimpurities(Cu,Cd,Ca,Cl,etc.),andtheimpurityconcentrationismuchhigherthantherequirementsofsubsequentprocesses.（2）鋅電積對(duì)凈化后液的典型標(biāo)準(zhǔn)：Zn130-180g/L、Cu≤0.5mg/L、Cd≤0.8mg/L、Ca≤1.5g/L、Cl≤0.05g/L。(2)Typicalstandardsforzincelectrowinningonpurifiedliquid:Zn130-180g/L,Cu≤0.5mg/L,Cd≤0.8mg/L,Ca≤1.5g/L,Cl≤0.05g/L.（3）雜質(zhì)分類：第一類（影響產(chǎn)品質(zhì)量）：Cu、Cd（會(huì)導(dǎo)致電積鋅純度下降）；第二類（阻塞管道）：Ca（易結(jié)晶沉積，堵塞管道和溜槽）；第三類（干擾電積）：Cl（腐蝕陽(yáng)極板，縮短其使用壽命）。(3)Impurityclassification:CategoryI(affectingproductquality):Cu,Cd(willleadtoadecreaseinthepurityofelectrowinnedzinc);CategoryII(blockingpipes):Ca(pronetocrystallinedeposition,blockingpipesandchutes);CategoryIII(interferingwithelectrowinning):Cl(corrodingtheanodeplate,shorteningitsservicelife).3.針對(duì)硫酸鋅溶液中的Cu、Co、Cl三種雜質(zhì)，分別說(shuō)明對(duì)應(yīng)的凈化方法及得到的凈化液和凈化渣的特點(diǎn)。3.PleaseexplainthecorrespondingpurificationmethodsandthecharacteristicsoftheobtainedpurificationliquidandpurificationresiduerespectivelyaccordingtothethreeimpuritiesofCu,CoandClinzincsulfatesolution.解答：Answer:（1）Cu雜質(zhì)：1)Cuimpurity:①凈化方法：鋅粉置換法（反應(yīng)：CuSO?+Zn=ZnSO?+Cu↓）；①Purificationmethod:Zincdustprecipitation(reaction:CuSO?+Zn=ZnSO?+Cu↓);②產(chǎn)品特點(diǎn)：凈化液中Cu≤0.5mg/L；凈化渣為Cu-Cd渣（含Cu、Cd等有價(jià)金屬，可回收）。②Productfeatures:Cuinpurificationliquid≤0.5mg/L;thepurificationslagisCu-Cdslag(containingvaluablemetalssuchasCuandCd,whichcanberecycled).（2）Co雜質(zhì)：(2)Coimpurity:①凈化方法：黃藥法（黃酸鉀與Co2?反應(yīng)生成黃酸鈷沉淀）；①Purificationmethod:Xanthatemethod(potassiumxanthatereactswithCo2?toformcobaltxanthateprecipitate);②產(chǎn)品特點(diǎn)：凈化液中Co≤3mg/L；凈化渣為鈷渣（富集Co，具有回收價(jià)值）。②Productfeatures:Coinpurificationsolution≤3mg/L;Thepurifiedslagiscobaltslag(enrichedinCo,whichhasrecoveryvalue).（3）Cl雜質(zhì)：(3)Climpurity:①凈化方法：硫酸銀沉淀法（反應(yīng)：Ag?SO?+2Cl?=2AgCl↓+SO?2?）；①Purificationmethod:Silversulfateprecipitationmethod(reaction:Ag?SO?+2Cl?=2AgCl↓+SO?2?);②產(chǎn)品特點(diǎn)：凈化液中Cl≤0.05g/L；凈化渣為氯化銀渣（可通過(guò)還原法回收Ag）。②Productfeatures:Clinpurificationsolution≤0.05g/L;thepurificationresidueissilverchlorideresidue(Agcanberecoveredbyreductionmethod).二、常見(jiàn)難點(diǎn)問(wèn)題答疑II.AnswerstoFrequentlyAskedDifficultQuestions1.硫酸鋅溶液中若Cl?濃度超標(biāo)（如0.5g/L），會(huì)對(duì)后續(xù)鋅電積工序造成哪些具體危害？請(qǐng)從設(shè)備和生產(chǎn)效率兩方面說(shuō)明。1.WhatspecifichazardswillitcausetothesubsequentzincelectrowinningprocessiftheCl?concentrationinthezincsulfatesolutionexceedsthestandard(suchas0.5g/L)?Pleaseexplainfromtwoaspectsofequipmentandproductionefficiency.解答：Cl?濃度超標(biāo)對(duì)鋅電積的危害如下：Answer:ThehazardsofexcessiveCl?concentrationtozincelectrowinningareasfollows:（1）設(shè)備方面：Cl?具有強(qiáng)腐蝕性，會(huì)加速鉛陽(yáng)極板的腐蝕（生成可溶性鉛氯化物），縮短陽(yáng)極板使用壽命，增加設(shè)備更換成本；同時(shí)可能腐蝕電解槽槽體，導(dǎo)致電解液泄漏。(1)Equipment:Cl?ishighlycorrosive,whichwillacceleratethecorrosionofleadanodeplates(generatesolubleleadchloride),shortentheservicelifeofanodeplates,andincreaseequipmentreplacementcosts;atthesametime,itmaycorrodetheelectrolyticcellbody,resultinginelectrolyteleakage.（2）生產(chǎn)效率方面：Cl?在陽(yáng)極放電生成Cl?氣體，污染車間環(huán)境并腐蝕電極接線；此外，Cl?會(huì)降低電解液的導(dǎo)電率，增加槽電壓，導(dǎo)致電能消耗上升，電流效率下降。(2)Intermsofproductionefficiency:Cl?dischargesattheanodetogenerateCl2gas,whichpollutestheworkshopenvironmentandcorrodeselectrodewiring;inaddition,Cl?reducestheelectrolyteconductivityandincreasesthecellvoltage,resultinginanincreaseinelectricenergyconsumptionandadecreaseincurrentefficiency.2.某硫酸鋅原料中Co2?濃度高達(dá)50mg/L（遠(yuǎn)高于電積要求的3mg/L），且含有少量Cu2?（0.3g/L）。應(yīng)優(yōu)先選擇哪種方法除Co？說(shuō)明選擇依據(jù)及與原料雜質(zhì)特點(diǎn)的匹配性。2.TheCo2?concentrationinazincsulfaterawmaterialisashighas50mg/L(muchhigherthantheelectrowinningrequirementof3mg/L),anditcontainsasmallamountofCu2?(0.3g/L).WhichmethodshouldbepreferredtoremoveCo?Explaintheselectionbasisandthematchingwiththeimpuritycharacteristicsofrawmaterials.解答：應(yīng)優(yōu)先選擇黃藥法除Co。Answer:ThexanthatemethodshouldbepreferredtoremoveCo.（1）選擇依據(jù)：黃藥（如丁基黃藥）與Co2?反應(yīng)生成難溶的黃酸鈷沉淀（Ksp極小），可將Co2?從50mg/L降至3mg/L以下，適用于高濃度Co?的深度去除。(1)Selectionbasis:Xanthate(suchasbutylxanthate)reactswithCo2?toformaninsolublecobaltxanthateprecipitate(Kspisextremelysmall),whichcanreduceCo2?from50mg/Ltolessthan3mg/L.ItissuitablefordeepremovalofhighconcentrationsofCo?.（2）與原料雜質(zhì)的匹配性：原料中含少量Cu2?，而黃藥對(duì)Cu2?也有沉淀作用（生成黃酸銅），可同步去除部分Cu2?，減少后續(xù)鋅粉置換除Cu的負(fù)荷，與原料雜質(zhì)特點(diǎn)匹配度高。(2)Matchingwithrawmaterialimpurities:TherawmaterialcontainsasmallamountofCu2?,andxanthatealsohasaprecipitationeffectonCu2?(generatingcopperxanthate),whichcansimultaneouslyremovepartofCu2?andreducetheloadofsubsequentzincdustprecipitationtoremoveCu.Ithasahighdegreeofmatchingwiththeimpuritycharacteristicsofrawmaterials.3.在硫酸鋅溶液凈化中，若采用鋅粉置換法除Cu時(shí)鋅粉過(guò)量（超過(guò)理論用量的50%），會(huì)對(duì)凈化液和后續(xù)電積工序產(chǎn)生哪些影響？請(qǐng)說(shuō)明影響路徑。3.WhatimpactwillithaveonthepurifiedsolutionandthesubsequentelectrowinningprocessinthepurificationofzincsulfatesolutionwhenthezincpowderreplacementmethodisusedtoremoveCuincaseofanexcessiveamountofzincpowder(morethan50%ofthetheoreticaldosage)?Pleasespecifytheimpactpath.解答：鋅粉過(guò)量的影響及路徑如下：Answer:Theeffectsandpathsofexcessivezincpowderareasfollows:（1）對(duì)凈化液的影響：過(guò)量鋅粉未完全反應(yīng)，會(huì)以金屬鋅顆粒形式殘留于凈化液中，導(dǎo)致凈化液中懸浮固體增多。(1)Effectonthepurificationliquid:Excesszincpowderisnotcompletelyreactedandwillremaininthepurificationsolutionintheformofmetalliczincpartic