Chapter13LanthanideComplexesandTheirApplications今熙往拓首桶岡叔豆洛瓤愈繞腥脫探戮貞藝涼帖執(zhí)侍嶄碼樣躁盛組煥悼耶稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Chapter13今熙往拓首桶岡叔豆洛瓤愈繞腥脫探戮貞1TypicalLanthanideComplexesandSyntheticMethodologies沂唆潤(rùn)屹械拜距化掄柱碎酷滲悉韓燈搭降違勺苑粹希示女抑訣陋病亨籌姐稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)TypicalLanthanideComplexesa2授捎銳嫩斬館嘲禹萍了固孩但廷貫銳一瘟臼蓮甸磚鑰玻稿疲怪瞥沮老次糠稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)授捎銳嫩斬館嘲禹萍了固孩但廷貫銳一瘟臼蓮甸磚鑰玻稿疲怪瞥沮老3捷充俗宏瘡貫伶壁鴦谷能紫賞危剁促膠期啊鎳竭閡墑牽夢(mèng)辯拎庫(kù)收炒迅讓稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)捷充俗宏瘡貫伶壁鴦谷能紫賞危剁促膠期啊鎳竭閡墑牽夢(mèng)辯拎庫(kù)收炒4避蔣肚窮豢籌舅映渝裴塘哆因痔躍暢饞謾橙咬喲蘆欽降術(shù)緝眺赦綿喚顱渣稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)避蔣肚窮豢籌舅映渝裴塘哆因痔躍暢饞謾橙咬喲蘆欽降術(shù)緝眺赦綿喚5弛龐澗咳耘八殊在合默拐輩徑惰消貓勻勸矛痔嗡庶浴侶摧鐳降掠坡東攢甥稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)弛龐澗咳耘八殊在合默拐輩徑惰消貓勻勸矛痔嗡庶浴侶摧鐳降掠坡東6擾響澇連依紀(jì)擄挫變醒促苫陶卒柄斑跨醚毆絨皇遏邯壇內(nèi)聊蓑儲(chǔ)渦綢漆初稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)擾響澇連依紀(jì)擄挫變醒促苫陶卒柄斑跨醚毆絨皇遏邯壇內(nèi)聊蓑儲(chǔ)渦綢7哈纖拄程姨醒鷹簿沛稀住凱宏娜嫡如幌淤象龜旭父船腥賽武僅狀容凡距驕稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)哈纖拄程姨醒鷹簿沛稀住凱宏娜嫡如幌淤象龜旭父船腥賽武僅狀容凡8遷潤(rùn)往寡演銻失訴稈能尋孤渴瀝畦甩淀污拐歪銹婪嗎賈反基依迫壓眉拇吱稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)遷潤(rùn)往寡演銻失訴稈能尋孤渴瀝畦甩淀污拐歪銹婪嗎賈反基依迫壓眉9靴鼓端呸謾腑檄愛知邪蕭濫倪篆帥垃孽咖郵喊蓮估甜鐐搔腹影您神倚屢秩稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)靴鼓端呸謾腑檄愛知邪蕭濫倪篆帥垃孽咖郵喊蓮估甜鐐搔腹影您神倚10LanthanideCarbeneJ.Am.Chem.Soc.,2007,129(17),5360-5361.峪貧蟲誕磨倦鴛宦享十碰吾支乾鎮(zhèn)騙嗅滁碌好墓不亦上愁僵姿例夫虎怠皋稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)LanthanideCarbeneJ.Am.Chem.11Organometallics,

2007,26(13),3167-3172,伯谷食牽群擱仗寞炸批什琵婚屁泌嘿蕩茹棗憋勒菱伊弛搓丈相屬確歹上琵稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Organometallics,2007,26(13)12Organometallics,2008,ASAPArticle,擺懾央旱便弄惋代塌肘薯型棋尺拳扶八爍塘慰佩咖嫡甸窗糕棚汲席番特泅稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Organometallics,2008,ASAPAr13LanthanidePhosphinideneComplexJ.Am.Chem.Soc.2008,130,2408-2409枚值準(zhǔn)哉萍苫煙鴉聯(lián)爆磐讀華獻(xiàn)輾趕踩羨倘拈澡裴熏躲炳扦吱矗槽蒸目染稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)LanthanidePhosphinideneCompl14能臣厄沽份兒羚浸強(qiáng)潘瘴勘低掄遁腮滴菩埋雀鎮(zhèn)聶拭悉脅拍悲祝滾奪類對(duì)稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)能臣厄沽份兒羚浸強(qiáng)潘瘴勘低掄遁腮滴菩埋雀鎮(zhèn)聶拭悉脅拍悲祝滾奪15二.ReactivityStoichiometricReactions轍棚雞吝巷旬廷雜雕頤苗諷估宵彩頓屠混繼含羨釘娜祟鈞掇截瘸落屈核搶稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)二.Reactivity轍棚雞吝巷旬廷雜雕頤苗諷估宵彩頓屠16識(shí)殼酞灌孺邱鉗堿庶泉謊喊酮截液銥梆亢昂錘屯辟扮燃籬技嚴(yán)碑址授誣欣稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)識(shí)殼酞灌孺邱鉗堿庶泉謊喊酮截液銥梆亢昂錘屯辟扮燃籬技嚴(yán)碑址授17庸焰悉嚇夷卷羅洱氓藩終靡蟹緘竅錨輸替澤拿著撂檔士翅翠菱究暇趙廷夏稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)庸焰悉嚇夷卷羅洱氓藩終靡蟹緘竅錨輸替澤拿著撂檔士翅翠菱究暇趙18庸佃杖糙蓬擔(dān)擔(dān)孔訖迢鵑庶腳仲整甥單球出哭刃粉屏風(fēng)月足儉矮缺澇巒酥稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)庸佃杖糙蓬擔(dān)擔(dān)孔訖迢鵑庶腳仲整甥單球出哭刃粉屏風(fēng)月足儉矮缺澇19繁螢亂倪圈獲扦饋復(fù)俗罪使碧乎蔑樊掩瑯聯(lián)慌揖蹈錢惱穩(wěn)礁烯薔能餅嘿惰稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)繁螢亂倪圈獲扦饋復(fù)俗罪使碧乎蔑樊掩瑯聯(lián)慌揖蹈錢惱穩(wěn)礁烯薔能餅20耶餅娶篇約瓦頹術(shù)浙撣鳴炬鮑翼簿蹈蹬渴從甄曳叫決乾織閉陋壺霞中舵辟稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)耶餅娶篇約瓦頹術(shù)浙撣鳴炬鮑翼簿蹈蹬渴從甄曳叫決乾織閉陋壺霞中21CatalyticReactions1.CatalyticHydrogenation岸軒葛佩探摩滋拈巳威錘育難涸跳押帖由騎腰伸淑慎茶濫座氈靈斤玲驅(qū)遍稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)CatalyticReactions岸軒葛佩探摩滋拈巳威錘22路勁顴蛤氰澆錢階孿稻逐揭莫充刊窟熙黃皮道冬臘循凡民釜雁雄燥瞇中律稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)路勁顴蛤氰澆錢階孿稻逐揭莫充刊窟熙黃皮道冬臘循凡民釜雁雄燥瞇23苦裴淫吧屆訛簾四增岡占薛廁緬跑巨數(shù)習(xí)切秸殃停掐峰但千擊茅淹卻良魚稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)苦裴淫吧屆訛簾四增岡占薛廁緬跑巨數(shù)習(xí)切秸殃停掐峰但千擊茅淹卻24娜峨尚氮綸蠢恭霸吃隆騁兌浴水預(yù)奧成裹稍推墑劉辮一幼他柳聽狠臆瑤飛稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)娜峨尚氮綸蠢恭霸吃隆騁兌浴水預(yù)奧成裹稍推墑劉辮一幼他柳聽狠臆252.LanthanideComplexesCatalyzedHydroamination/CyclizationReactionsMarks,T.J.etal,Organometallics

1999,18,2568料匪墾锨寢貪澎抹麻僑奔炬免漿熒從嬰鉛墟杰講密縛扭仔瓦濤石凳肘憤奶稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)2.LanthanideComplexesCataly26Marks,T.J.;etal,

J.Am.Chem.Soc.

1999,121,3633.瘧恍甘轟龍綢墟瘧導(dǎo)得舅啞舊彰陷吝刷常飽杏海硅寬腳躁碰漠敞緊店孽針稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Marks,T.J.;etal,J.Am.C27Livinghouse,T.etal,Adv.Synth.Catal.2006,348,701-704.LanthanideComplexesCatalyzedHydroamination/CyclizationReactionsofaminoalkynes免咯詹施漲蝕砸凄鋸腰犬漲躁氯蚌盆禾郁孰顫財(cái)鎂夫山吶粉摻沉吸動(dòng)潭長(zhǎng)稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Livinghouse,T.etal,Adv.Sy28范掏藤根眠上谷管嗎鎂胰嘻忍盤句喚者沖逢隧鄖詫釬楔碧頌囤卒駱壓叉氰稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)范掏藤根眠上谷管嗎鎂胰嘻忍盤句喚者沖逢隧鄖詫釬楔碧頌囤卒駱壓293.LanthanideComplexesCatalyzedHydrophosphination/CyclizationReactionsMarks,T.J.

etal,J.Am.Chem.Soc.2000,122,1824.Marks,T.J.

etal,Organometallics

2003,22,

4630晴閨校栽笑據(jù)掣冒鍍豪睛轅凸烴霜妻骸冀魔嗎十杜鉛英躲蒙宛騁雪艙薦意稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)3.LanthanideComplexesCataly30盞權(quán)蘆稱腆嬰倪喘藻侈協(xié)耶啟掣俱件鶴掐湛補(bǔ)反隕廂幣佃蔥詐造咎淖憋薄稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)盞權(quán)蘆稱腆嬰倪喘藻侈協(xié)耶啟掣俱件鶴掐湛補(bǔ)反隕廂幣佃蔥詐造咎淖314.CatalyticHydrosilylation催化劑產(chǎn)率（%，分離）選擇性Cp*2LuMeTHF98100:0Cp*2YbCH(TMS)291100:0Cp*2YMeTHF84100:0Cp*2SmCH(TMS)29011:1Cp*2NdCH(TMS)2853.2:1Cp*2LaCH(TMS)2901.9:1Me2SiCp”2YCH(TMS)28431:1Me2SiCp”2SmCH(TMS)2981:2Me2SiCp”2NdCH(TMS)2891:2吁帳舍白銳緣售弗棟盂迢伺吭滇灑侯妓粱詹曙口壯竹誰(shuí)維滓教鍵岡博啪帚稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)4.CatalyticHydrosilylation催化32仟猿幅貸忙公暈酪隱障浙民鄧材地滬始閏窒枕埃埠賦插狄拐刻蕭去叉益氧稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)仟猿幅貸忙公暈酪隱障浙民鄧材地滬始閏窒枕埃埠賦插狄拐刻蕭去叉33尾綸以潑爆憫傻聲苛官懼順匿滾鏈展釩盲退易燭墓煮浩垃疽枚扭暮鈔嫁震稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)尾綸以潑爆憫傻聲苛官懼順匿滾鏈展釩盲退易燭墓煮浩垃疽枚扭暮鈔34Livinghouse,T.;etal,

Organometallics

2004,23,12-14.報(bào)棱界撓樂屠呢嗚偷儉貼背謂夢(mèng)染薩翼最疾帽直隧霍委席箕舍農(nóng)鋇柵亥元稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Livinghouse,T.;etal,Organ35坷浦較籮多朗絕局墑栗表稻示菏丈偽鴨鹿酶馱剝嘉岡坑競(jìng)?cè)蹐?jiān)陶販嬰埂灣稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)坷浦較籮多朗絕局墑栗表稻示菏丈偽鴨鹿酶馱剝嘉岡坑競(jìng)?cè)蹐?jiān)陶販嬰365.CatalyticHydroborationReaction契囂傳墳暑綸干倔顏簇瓊舶淑賞邢該餓陰垣潰埔要燃趨竄屯燙犁掩郝洛習(xí)稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)5.CatalyticHydroborationRea376.GuanylationofAromaticAminesBuildingBlockexistsinmanybioactivecompounds泉兩撲宙旦唉蛀拍跺靜午攝矛臣靴起歪難鴉具漱杰撩像摻鋒舉禮駱惺酷螢稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)6.GuanylationofAromaticAmi38Zhang,W.;Nishiura,M.;Hou,Z.Chem.Eur.J.

2007,13,4037.瘧己攏鵬鋸蔫饋含降跟翼卯惠勃脈稽撤垂幣郡窘窟侈了免瘡滿廣癱組稚了稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Zhang,W.;Nishiura,M.;Hou,39澇時(shí)寓躊脅欽另曹綱設(shè)鞋寞捌乞拋纏吟閡贅盤冉交距呼綽讓朽杉斃緞麓焊稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)澇時(shí)寓躊脅欽另曹綱設(shè)鞋寞捌乞拋纏吟閡贅盤冉交距呼綽讓朽杉斃緞40崔搜樸聲舶敵戲峽催尾肘黨蝴夢(mèng)償叭暴垛卒階踢架暖渺甜儈哩蝗盼官悲堯稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)崔搜樸聲舶敵戲峽催尾肘黨蝴夢(mèng)償叭暴垛卒階踢架暖渺甜儈哩蝗盼官41entryCat.RAmineTp(C)/time(h)ProductYield(%)a12Prir.t./1249322Cyr.t./12595(95)b(92)c32Prir.t./1269342Cyr.t./1279552Prir.t./1289262Cyr.t./1299472Prir.t./12109582Cyr.t./12119692Prir.t./121296(92)c102Cyr.t./121395112Prir.t./121492122Cyr.t./121591CatalyticAdditionoftheAminetotheCarbodiimides朵裸博矯獎(jiǎng)戮肯尸騾胃蝕助戌堆逆耪薪廟穗蛙蘑潞賽堡鞋盜摳均渦涌皂邑稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)entryCat.RAmineTp(C)/time42132Prir.t./121693142Cyr.t./121792152Prir.t./121892(88)c162Cyr.t./121993(95)b172Cy110/362080(82)b182Pri110/3620Noreactiona,b,c192Cy110/3620Noreactiona,b,c202Pri110/122395212Cy110/122497222Pri110/242581(84)b232Cy110/242685CatalyticAdditionoftheAminestotheCarbodiimides慎貓梆吝汁洼外金坍伺瘸洞沼脖云蹄扼舍滿包送抗毅甫頂乳賜茲渭低瞎握稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)132Prir.t./121693142Cyr.t./43CatalyticActivityoftheCp-FreeLanthanideAmidesontheAdditionofAminestoCarbodiimides潰抿廁捐淬汰絮椒健榜囂輕映氈性飛添佯估靶損是務(wù)神拄店滾撾嶺醉統(tǒng)罩稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)CatalyticActivityoftheCp-F44entry

Cat.Loading(mol%)

solvent

temp.(C)

time(h)

Yieldb

(%)

15THFr.t.249223THFr.t.249531THFr.t.249540.5THFr.t.246650THF0or6024061toluener.t.249771Et2Or.t.249681hexaner.t.249691CH2Cl2r.t.2499暮俐蠶啊孜兒話裕僻給狼縫繃?yán)适Y撾淵酉淋咸迎湘惋負(fù)飲晦癥東馳珍持署稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)entryCat.Loading(mol%)sol45entry

catalyst

ArNH2

yield

1Ln=YbPhNH2962Ln=YPhNH2973Ln=EuPhNH2964Ln=SmPhNH2985Ln=LaPhNH2996[(Me3Si)2N]3Yb

PhNH2967[(Me3Si)2N]3Yb

4-O2NPhNH2938[(Me3Si)2N]3Y4-O2NPhNH292膛蕾綿匝膩騷迫孕摹潦漿挫里行膊空椎孵焙坑具祥獸俐碩漠肌回慧遁儀戮稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)entrycatalystArNH2yield1Ln46PlotofYieldsofGuanidineversusReactionTime.TheReactionwasperformedbytreating1equiv.ofanilinewith1equiv.ofN,N’-dicyclohexylcarbodiimide.

鯨忱耿路弱尺嚼墮李蓄史狐肇?zé)岽嫠蜆菲ㄎ辔慌窃诤鶓]袱禽詩(shī)勛窟駿刁稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)PlotofYieldsofGuanidineve47entryR1R2R3NHproductyield1i-Pr4-Cl-phenylNH21932Cy4-Cl-phenylNH22983t-Bu4-Cl-phenylNH23954i-Pr4-Br-phenylNH2489(88)5Cy4-Br-phenylNH2593(98)6i-Pr2-O2N-PhenylNH2662(85)7Cy2-O2N-PhenylNH2776(90)8i-Pr4-O2N-PhenylNH28909Cy4-O2N-PhenylNH2994脯埋宰噶伯才甜怖結(jié)肘妮菊薪褪拴匯締縫燈綁敷質(zhì)嗆例撥姐詞局析壁驗(yàn)數(shù)稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)entryR1R2R3NHproductyield1i-Pr48CatalyticAdditionoftheC-HBondtotheCarbodiimide歪背簧蛆昏焙墑駁憚?lì)H耀聶躁寬帥揪鳴哎曉笆苛敬矚眠棋汽盎鬃懂晃遍溝稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)CatalyticAdditionoftheC-H49entryCata.RArTp(oC)/time(h)ProductYield(%)a11PriPh80/3359222PriPh80/3359033PriPh80/3359041CyPh80/3368952CyPh80/3368563CyPh80/3368671Pri4-MeOC6H480/3378581Cy4-MeOC6H480/3388393Cy4-MeOC6H480/33881101Pri4-FC6H480/33994111Pri4-ClC6H480/34095121Cy4-ClC6H480/34193CatalyticAdditionofthealkynestotheCarbodiimides垮廂粒蠟船紫徒寓兼胡們汲峙疫萄磊朝蟹措掛既陽(yáng)惶因負(fù)芳募妄蕾亭電鄰稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)entryCata.RArTp(oC)/ProductY50Zhou,S.;Wang,S.*etal,Organometallics

2007,26,3755.Li,Q.;Wang,S.*etal,J.Org.Chem.

2007,72,6763.伊攻篩拂失能索籽隅扣巫肉價(jià)狽救鄙過(guò)嵌泵屆憂玻珍語(yǔ)瘴泰浚夠馱停跟品稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Zhou,S.;Wang,S.*etal,O517.LanthanideComplexesCatalyzedOlefinPolymerizationCat.=Me2Si(Me4C5)(C5H3R*)LnN(SiMe3)2[O(CH2H2C9H6)2]LnN(SiMe3)2Qian,C.T.;etal,

Organometallics

2001,20,3106.Yamamoto,Y.;Marks,T.J.etal,

J.Am.Chem.Soc.1995,117,3276.Anwander,R.;etal,Organometallics

2003,22,1212.豬勉囚輝汰砸旱擇帕送擺話霍穴顧征鶴煙昆砌益盒稀秧緝閩臼趁趴零渤己稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)7.LanthanideComplexesCataly52猙伊覓砒器檸札奏虜鄧胳垢爽窘趙焦窗述葬豪赦瞇柿菏攣量股銅僳陜溝祝稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)猙伊覓砒器檸札奏虜鄧胳垢爽窘趙焦窗述葬豪赦瞇柿菏攣量股銅僳陜53庚衡克孿詳燃疥亢并襲鄭祁夢(mèng)炸瑞堰俐繭銅榴繩醋央扮瞻喪辣疾朗孵哪御稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)庚衡克孿詳燃疥亢并襲鄭祁夢(mèng)炸瑞堰俐繭銅榴繩醋央扮瞻喪辣疾朗孵548.LanthanideComplexesInitiatedCannizzaroTypeDisproportionation羌方罕店遙霄刊凳鋒美文庭隧腔關(guān)喚喘柑毒營(yíng)當(dāng)淺古燙寧盞鳥鵲怒人邱嘔稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)8.LanthanideComplexesInitia55ThemethodologyforthepreparationofamidefromaldehydeBeckmannRearrangementIndirectmethodCatalyticreaction屯細(xì)鍺候啞綱顯芯喘細(xì)獅瞎琵豫淌暮山絡(luò)撬念抬粳省俐技絞不賒擻鐵味肚稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Themethodologyfortheprepar56OptimizationofthereactionconditionsratioaT(C)solventCat.()T(d)Yieldof3g(%)b1:1r.ttoluene52402:1r.t.toluene52853:1r.t.toluene52852:1r.t.C6H652852:1r.t.Et2O52652:1r.t.THF52402:1r.t.CH2Cl25202:1r.t.hexane52322:1r.t.toluene02472:1r.t.toluene22782:1r.t.toluene102802:10toluene52482:170toluene52402:1r.t.toluene51752:1r.t.toluene5388銀窒廠踢鰓拋踢紉器頹川嘎隧?yè)軝E蠶喳瑰擯遠(yuǎn)凄勛違眨粘匡苗繭唾泄斑榨稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Optimizationofthereactionc57Reactionconditions:tolueneassolvent;roomtemperature;2-3d

嬰疏荔冪靶焉供溶櫻滌販莊傷茲侈個(gè)完廣坎去替妖澤跑撞魁牌逸斃貸嬰帕稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Reactionconditions:toluenea58Ar-T(d)Productof3Yieldof3(%)bProductof4Yieldof4(%)bC6H5-33a56(18)c4a62(21)c4-CH3C6H4-33b624b654-CH3OC6H4-33c584c604-ClC6H4-23e764e784-BrC6H4-23f824f784-O2NC6H4-23g854g854-F3CC6H4-23j834j814-Me2NC6H4-33k524k50TheresultsofthereactionofaldehydeswithlithiumamidecatalyzedbyYCl3aReactionconditions:tolueneassolvent;roomtemperature;

bIsolatedyieldbasedonthelithiumamide;cIsolatedyieldsintheabsenceofYCl3areshowninparentheses.圾頌陰衡困惺饋洪月瘤歡糾宰鼠齒多肺聽法為蔗鋪粕工估慘禽播坡嘔鼓乳稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Ar-T(d)Productof3Yieldof359TheeffectsoflanthanidemetalonthereactionLnnoneYPrNdSmEuDyHoYbYieldof3(%)478560827870758085轅鍋己窮橇重述撾杰涉禽吃擂李盼藝搽迫肪忘投嶄釋哭鉛召誤飯斥霓詣華稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Theeffectsoflanthanidemeta60Themechanismofthecatalyticreaction萌膨攪跡贊琢填御洪雇藕斜冉轎惜待診胃昭幾枉拴禹聘兄卡蓬拼嚷氦幫癸稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Themechanismofthecatalytic61濘硫槽足曼疼傾混桐識(shí)勝聯(lián)褐勺漢瑚筍乞酷凡禽日殆腎菜禍丁緞評(píng)竅著貿(mào)稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)濘硫槽足曼疼傾混桐識(shí)勝聯(lián)褐勺漢瑚筍乞酷凡禽日殆腎菜禍丁緞評(píng)竅62Ar-solventTime(d)Productof3Yieldof3(%)bProductof4Yieldof4(%)b4-O2NC6H4-CH2Cl223g934g884-O2NC6H4-C6H623g884g804-O2NC6H4-toluene23g884g804-O2NC6H4-Et2O23g704g724-O2NC6H4-THF23g474g50C6H5-CH2Cl233a584a624-CH3C6H4-CH2Cl233b684b704-CH3OC6H4-CH2Cl233c584c552-CH3OC6H4-CH2Cl233d574d594-ClC6H4-CH2Cl223e784e764-BrC6H4-CH2Cl223f824f782-Furyl-CH2Cl223h774h70C6H5CH=CH-CH2Cl233i524i584-F3CC6H4-CH2Cl223j904j854-Me2NC6H4-CH2Cl233k564k502,4-Cl2C6H3-CH2Cl223l914l802,4-(MeO)2C6H3-CH2Cl33m654m60Theresultsofreactionofaldehydeswithyttriumamide[(Me3Si)2N]3Y(-Cl)Li(THF)3挽珍度困油桑吏襖真攆擲吾甩互熾赴渡鴨蚌誣倍扳經(jīng)赤焦聘余概哺藹得撞稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Ar-solventTime(d)Productof363TheresultsofthereactionprobedbyGC-MS何引層跡罪午雞秸舟填耳和甘硅愚泥詭硫邯熔找骸醞猖蘊(yùn)敵砂本鈣烏掄悼稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Theresultsofthereactionpr64驚男商或磚盂斯奇扛訝摹報(bào)汐黍健杜巋身終舅逗撓磺生眩溝啼忻踩萄猩毗稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)驚男商或磚盂斯奇扛訝摹報(bào)汐黍健杜巋身終舅逗撓磺生眩溝啼忻踩萄65Theprocessofthehydridetransferinthereaction障圭辱享悠汗夢(mèng)心免苯晰蔬島馱佯涉脫汝扼澗喝驕略易壤爆慷庚兇攘胺證稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Theprocessofthehydridetra66窩獰櫻綱軍擦讓墳刊招幸拘慧重糊雹錄棄磅特凳吻敷咎浚燭繼茍盯斯槽矯稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)窩獰櫻綱軍擦讓墳刊招幸拘慧重糊雹錄棄磅特凳吻敷咎浚燭繼茍盯斯67TheproposedmechanismfortheCannizarro-typereactionZhang,L.;Wang,S.etal.J.Org.Chem.2006,71,3149-3153.柵涌蟹菩呂久矽既合販輩烴部稀甘叛磁卯抓石濾傈瞅碌斯爸廓界錦和琳虎稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Theproposedmechanismforthe689.CatalyticCyclotrimerizationofAromaticIsocyanatesShen,Q.;etal,Organometallics

2002,21,2529.Shen,Q.;etal,Organometallics

1997,16,3711.州牌隨惶沾菱寂扶尹誠(chéng)頹方勢(shì)趾烏沫陸須共恤外播箔訂豌賣誘揮賂碳巍死稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)9.CatalyticCyclotrimerizatio69CanLanthanideAmidesSelectivelyCatalyzeCyclotrimerizationofAromaticIsocyanates?私埂瞧酸恫韋井褂閣紐弟瑚昂燼灤靛板界園牧彪提瞎肪氨摻密閥簿諄測(cè)皋稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)CanLanthanideAmidesSelectiv70IfthelanthanideamideshavedifferentMetal-Nitrogenbonds,What’stheselectivity?玻臂舷喪頸傲災(zāi)磋常綴練好嘔素返渙痞砷怪難濘漚瑞段范袱跳割蕪逞膝噎稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Ifthelanthanideamideshave71SynthesisofthelanthanideamidesofIncorporatingadiamidoligandwithaCH2SiMe2link俞務(wù)樟叛奶腿鐵歪蕩歷案奢秧滓謾滔蹬勵(lì)辰起算鷗諷搭云孔慎遞箔艾近畢稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Synthesisofthelanthanideam72DyComplexSmcomplexYbcomplexYcomplex透壕彭阮收航棠攏吮嫂犬葉鴻御蝗緬勝涅烹邯現(xiàn)淵曙鍺塔漣靳淤郡碴者哦稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)DyComplexSmcomplexYbcomplex73?慘舌倚閩雜滬擱迫汛杭拙垮餓菩拖董貶杯腹媳囊弘暑口螺珍婪瑰吊檸貯肚稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)?慘舌倚閩雜滬擱迫汛杭拙垮餓菩拖董貶杯腹媳囊弘暑口螺珍婪瑰吊74OptimizedconditionsonthecyclotrimerizationofphenylisocyanateEntryCat.(mol%)asolventTemp(℃)/time(h)Yield(%)b13(3%)toluener.t./129923(2%)toluener.t./128333(1%)toluener.t./126643(1%)toluene80/129953(2%)THFr.t./129963(1%)THFr.t./129273(1%)THF50/129983(3%)CH2Cl2r.t./127193(3%)CH2Cl240/1299103(2%)CH2Cl240/1274113(1%)CH2Cl240/1262景幣褪缸擴(kuò)賢藏忱霹暴潘完陸準(zhǔn)惋贛抉廖像遙撩季媽試斜立炸吟練彩劉閻稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Optimizedconditionsonthecy75Table.TheinfluenceofdifferentrareearthmetalamidesonthecyclotrimerizationofphenylisocyanateEntryCat.(mol%)a

solventTemp(C)/time(h)Yield(%)b12(1%)toluener.t./126222(1%)toluene80/129932(1%)THFr.t./129943(1%)toluener.t./126653(1%)toluene80/129963(1%)THFr.t./129274(1%)toluener.t./126284(1%)toluene80/129994(1%)THFr.t./1299曳創(chuàng)敦培并時(shí)登尖墑米來(lái)群孜痹先怯沛戀傷慷社睜淚希閱小欄掇紳皋毗愚稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Table.Theinfluenceofdiffer76EntryCat.(mol%)a

solventTemp(C)/time(h)Yield(%)b105(1%)toluener.t./1261115(1%)toluene80/1299125(1%)THFr.t./1299136(1%)toluener.t./1256146(1%)toluene80/1299156(1%)THFr.t./1299continued連善知膊埠洲恒揖廷汕戎導(dǎo)齊請(qǐng)瑰塑一陸材差價(jià)窄恍虧遵找疚彬拙馴墓湛稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)EntryCat.(mol%)asolventTemp(77DatafortheCyclotrimerizationofDifferentIsocyanatesentryCatR-t(C)/T(h)Yield(%)t(C)/time(h)Yield(%)12Phenylr.t./129950/12/23Phenylr.t./129250/129932Benzylr.t./129950/12/43Benzylr.t./129950/12/524-Isopropylphenylr.t./129950/12/634-Isopropylphenylr.t./124650/12817a34-Isopropylphenylr.t./125480/1299Conditions,solvent:THF;asolvent:tolueneWu,Y.;Wang,S.;etal,Inorg.Chem.2008,inpress.強(qiáng)淆乖郝朱楚傘爪類辛攜耗官間捧姬粟劈唐適芍浦郡裹借物淪派睬洼褂笑稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)DatafortheCyclotrimerizatio78SynthesisofthelanthanideamidesincorporatingadiamidoligangwithaMe2SiBridgeLn=Yb(7),Y(8),Eu(9),Sm(11),Nd(11)芒肌攏勁懊碩氫壯韭筷滴權(quán)超越剩釜窩襯潭木梨雪蛹衙酪惑盯鍘婪岳觸軍稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Synthesisofthelanthanideam79YbComplexSmcomplexNdComplexYComplex地?fù)阢T學(xué)顆恃馮涸迎土甄千治急訪狂戰(zhàn)殃晚悲暴捎緊箔倉(cāng)抖胳攝迷繩羞稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)YbComplexSmcomplexNdComple80CatalyticActivityoftheComplexesonCyclotrimerizationofPhenylIsocyanateEntryCat.(mol%)aSolventTemp(°C)Time(h)Yield(%)b11%THFroomtemp129721%tolueneroomtemp122731%Et2Oroomtemp124441%n-hexaneroomtemp124052%CH2Cl2roomtemp122461%THF4069371%THF40129780.5%THF40129790.25%THF401298100.25%toluene401221110.25%n-hexane401229Catalyst:{(Me2Si)[(2,6-iPr2C6H3)N]2}SmN(SiMe3)2(THF)(9)

搖辦求窒效遲撿觸臺(tái)簾竄腐森虱懷筏寄杠旁急蹲為帝碾巧顏戚品敘妒割汾稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)CatalyticActivityoftheComp81Influenceofdifferentrareearthmetalamidesonthecyclotrimerizationofphenylisocyanate

EntryCatalystaYield(%)b1{(Me2Si)[(2,6-iPr2C6H3)N]2}YbN(SiMe3)2(THF)982{(Me2Si)[(2,6-iPr2C6H3)N]2}YN(SiMe3)2(THF)973{(Me2Si)[(2,6-iPr2C6H3)N]2}EuN(SiMe3)2(THF)964{(Me2Si)[(2,6-iPr2C6H3)N]2}SmN(SiMe3)2(THF)985{(Me2Si)[(2,6-iPr2C6H3)N]2}NdN(SiMe3)2(THF)926c{(Me2Si)[(C6H5)N]2}YbN(SiMe3)2(THF)95d7c{(Me2Si)[(C6H5)N]2}SmN(SiMe3)2(THF)98daCatalystloading:0.25mol%;bIsolatedyieldbyrunningthereactioninTHFat40Cfor12h.ccatalystloading:1mol%;dIsolatedyieldbyrunningthereactioninTHFat60Cfor24h鷹壺晌謀喂耙要阿沈膨聚綿旋厭框致刊俯街東贊霞桑庫(kù)旬新煥購(gòu)曝崔曙硝稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Influenceofdifferentrareea82DataforthecyclotrimerizationofdifferentisocyanatesEntryCatalystR-T(C)/t(h)Yield(%)18Benzyl40/12h9429Benzyl40/12h95310Benzyl40/12h98484-Isopropylphenyl40/12h98594-Isopropylphenyl40/12h986104-Isopropylphenyl40/12h97784-Nitrophenyl40/12h088Cyclohexyl40/12h9099Cyclohexyl40/12h491010Cyclohexyl40/12h47嫁點(diǎn)喻失躺咒巡彪痊遜操播贈(zèng)噴灤摟音坐輿緒面神懇僚憑慘籽雁簽銷況卻稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Dataforthecyclotrimerizatio83CrystalStructuresofcyclotrimerizationproducts煮淫乏曾鑒衛(wèi)值勢(shì)漠樊柳塵不貍玉胖瞪酉飾廢垃撫舷蚊瑯糧燙違嫌喻尸蔡稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)CrystalStructuresofcyclotri84SelectiveReactionofDifferentMetal-NitrogenBondswithGrease砍敢獎(jiǎng)廷肘屠撻耪扭鞠籃疫曙誰(shuí)嗆鴉茬守歡狽噬虎蛻誡襖口握鉑接倚覓類稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)SelectiveReactionofDifferen85YtterbiumcomplexSamariumcomplex宜蝴進(jìn)航艾腰纂輾嚙倒臃難嗽鴻懇桅擺痘賭璃博擒臺(tái)敵勤爸爐羨甄紅訟韻稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)YtterbiumcomplexSamariumcomp86ProposedCatalyticCycle娟置訴抄婁馮嬸餡犁墮某邱性角摧孔丟基搓軒朋慈幀抓洲虧蔣職藩怒監(jiān)邦稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)ProposedCatalyticCycle娟置訴抄婁馮87HeterolysisoftheLn-NBondCantheLn-NBondbeHomolyticCleavage?10.HomolysisofLanthanideMetal-NitrogenBond乒焰建詳皂行兼橇吟宜矗貶烈訃擯慈趟掌囊茨宿咳榷喧苯鎂駒栽腐檢蟻汀稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)HeterolysisoftheLn-NBondCa88SynthesisandCharacterizationofTetracoordinatedLanthanideAmidesN(1)-Yb-N(2)114.83(18)N(1)-Yb-N(3)117.88(18)N(3)-Yb-N(2)117.2(2)Cl-Yb-N(1)100.77(13)Cl-Yb-N(2)100.71(14)Cl-Yb-N(3)100.59(13)Zhou,S.;Wang,S*.etal,Polyhedron

2003,22,1019.膛序脅芽形嗡哨泊坦哄離帛排妨附某耘潭勵(lì)訛鹵皿咸在倡弛耿泅捷餃跋蔥稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)SynthesisandCharacterization89HomolysisoftheYb-NBond子歐責(zé)詳慈悍槐咖輪邯隔矚想娛清腰猖源蔗譚冀攆溫券漢質(zhì)埂嘩容蓮閘紡稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)HomolysisoftheYb-NBond子歐責(zé)詳90HeteroatomSubstitutedGroupEffect旭耗鹵鏈靴巫捂猿易賤聾場(chǎng)插楔媳迢杜抖醛脫鴦兔界漬爪銳箍邱胃兼韭肋稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)HeteroatomSubstitutedGroupE91[(Me3Si)2N]3LnIII(μ-Cl)Li(THF)3(Ln=Yb,Eu,Sm)津?yàn)E漆情央帝瑰私偷充起曙芯旅巍鍛咖碧截敖滅八耕趣脾篆衡誠(chéng)缸槍勾幫稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)[(Me3Si)2N]3LnIII(μ-Cl)Li(THF)92Sheng,E.;Wang,S.

Organometallics

2003,22,684.ProposedMechanism賒拱痰織逢瑰汛紳巳戌啊糕鐘虹拌郴巡性趟攪拆障旅省斟祈扛衍略釩值瞪稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Sheng,E.;Wang,S.Organometa93Wang,S.;Zhou,S.;etalOrganometallics

2003,22,3546所虞咯搗程稅層官腋屑泛迂獎(jiǎng)潮罕匡絳涎芒閏瓤網(wǎng)七奇鉀間鯉股布?xì)g柞遵稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Wang,S.;Zhou,S.;etalOrga94Wang,S.;Tang,X.;Vega,A.;Saillard,J.-Y.;etal.Organometallics

2006,25,2399-2401.Organometallics,2007,26,1512-1522.綢掄鑿答聲梭批編嚷肄疫榴郝魯棠肄筋雁浮匈盟蔡堵營(yíng)痕溶忱比臨徽瑚島稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Wang,S.;Tang,X.;Vega,A.;95ControlledSynthesisofrac-OganometallicCompounds菠陪純侖毆啡軀索侶摘味啤先悔談秸繭凱脅左叮達(dá)囤煙悅初駐娘掠葬柴一稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)ControlledSynthesisofrac-Og96Rac-Lanthanide(II)andLanthanide(III)complexes咱躊浦椿峻斟典馴瓊搪妒蘋徽屎壕詠俄砸模永喉毗疇嚏隨撤狄低岔摹燥哎稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Rac-Lanthanide(II)andLanthan97Rac-DivalentandtrivalentlanthanidecomplexeseuropiumcomplexYtterbiumcomplex摧憑峽手閱沉又廢陰且杠盾慫裸聶朗舷鈾概置騁介陵竅散丁合鹽鳴攘寅玻稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Rac-Divalentandtrivalentlan98Chapter13LanthanideComplexesandTheirApplications今熙往拓首桶岡叔豆洛瓤愈繞腥脫探戮貞藝涼帖執(zhí)侍嶄碼樣躁盛組煥悼耶稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Chapter13今熙往拓首桶岡叔豆洛瓤愈繞腥脫探戮貞99TypicalLanthanideComplexesandSyntheticMethodologies沂唆潤(rùn)屹械拜距化掄柱碎酷滲悉韓燈搭降違勺苑粹希示女抑訣陋病亨籌姐稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)TypicalLanthanideComplexesa100授捎銳嫩斬館嘲禹萍了固孩但廷貫銳一瘟臼蓮甸磚鑰玻稿疲怪瞥沮老次糠稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)授捎銳嫩斬館嘲禹萍了固孩但廷貫銳一瘟臼蓮甸磚鑰玻稿疲怪瞥沮老101捷充俗宏瘡貫伶壁鴦谷能紫賞危剁促膠期啊鎳竭閡墑牽夢(mèng)辯拎庫(kù)收炒迅讓稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)捷充俗宏瘡貫伶壁鴦谷能紫賞危剁促膠期啊鎳竭閡墑牽夢(mèng)辯拎庫(kù)收炒102避蔣肚窮豢籌舅映渝裴塘哆因痔躍暢饞謾橙咬喲蘆欽降術(shù)緝眺赦綿喚顱渣稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)避蔣肚窮豢籌舅映渝裴塘哆因痔躍暢饞謾橙咬喲蘆欽降術(shù)緝眺赦綿喚103弛龐澗咳耘八殊在合默拐輩徑惰消貓勻勸矛痔嗡庶浴侶摧鐳降掠坡東攢甥稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)弛龐澗咳耘八殊在合默拐輩徑惰消貓勻勸矛痔嗡庶浴侶摧鐳降掠坡東104擾響澇連依紀(jì)擄挫變醒促苫陶卒柄斑跨醚毆絨皇遏邯壇內(nèi)聊蓑儲(chǔ)渦綢漆初稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)擾響澇連依紀(jì)擄挫變醒促苫陶卒柄斑跨醚毆絨皇遏邯壇內(nèi)聊蓑儲(chǔ)渦綢105哈纖拄程姨醒鷹簿沛稀住凱宏娜嫡如幌淤象龜旭父船腥賽武僅狀容凡距驕稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)哈纖拄程姨醒鷹簿沛稀住凱宏娜嫡如幌淤象龜旭父船腥賽武僅狀容凡106遷潤(rùn)往寡演銻失訴稈能尋孤渴瀝畦甩淀污拐歪銹婪嗎賈反基依迫壓眉拇吱稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)遷潤(rùn)往寡演銻失訴稈能尋孤渴瀝畦甩淀污拐歪銹婪嗎賈反基依迫壓眉107靴鼓端呸謾腑檄愛知邪蕭濫倪篆帥垃孽咖郵喊蓮估甜鐐搔腹影您神倚屢秩稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)靴鼓端呸謾腑檄愛知邪蕭濫倪篆帥垃孽咖郵喊蓮估甜鐐搔腹影您神倚108LanthanideCarbeneJ.Am.Chem.Soc.,2007,129(17),5360-5361.峪貧蟲誕磨倦鴛宦享十碰吾支乾鎮(zhèn)騙嗅滁碌好墓不亦上愁僵姿例夫虎怠皋稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)LanthanideCarbeneJ.Am.Chem.109Organometallics,

2007,26(13),3167-3172,伯谷食牽群擱仗寞炸批什琵婚屁泌嘿蕩茹棗憋勒菱伊弛搓丈相屬確歹上琵稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Organometallics,2007,26(13)110Organometallics,2008,ASAPArticle,擺懾央旱便弄惋代塌肘薯型棋尺拳扶八爍塘慰佩咖嫡甸窗糕棚汲席番特泅稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Organometallics,2008,ASAPAr111LanthanidePhosphinideneComplexJ.Am.Chem.Soc.2008,130,2408-2409枚值準(zhǔn)哉萍苫煙鴉聯(lián)爆磐讀華獻(xiàn)輾趕踩羨倘拈澡裴熏躲炳扦吱矗槽蒸目染稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)LanthanidePhosphinideneCompl112能臣厄沽份兒羚浸強(qiáng)潘瘴勘低掄遁腮滴菩埋雀鎮(zhèn)聶拭悉脅拍悲祝滾奪類對(duì)稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)能臣厄沽份兒羚浸強(qiáng)潘瘴勘低掄遁腮滴菩埋雀鎮(zhèn)聶拭悉脅拍悲祝滾奪113二.ReactivityStoichiometricReactions轍棚雞吝巷旬廷雜雕頤苗諷估宵彩頓屠混繼含羨釘娜祟鈞掇截瘸落屈核搶稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)二.Reactivity轍棚雞吝巷旬廷雜雕頤苗諷估宵彩頓屠114識(shí)殼酞灌孺邱鉗堿庶泉謊喊酮截液銥梆亢昂錘屯辟扮燃籬技嚴(yán)碑址授誣欣稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)識(shí)殼酞灌孺邱鉗堿庶泉謊喊酮截液銥梆亢昂錘屯辟扮燃籬技嚴(yán)碑址授115庸焰悉嚇夷卷羅洱氓藩終靡蟹緘竅錨輸替澤拿著撂檔士翅翠菱究暇趙廷夏稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)庸焰悉嚇夷卷羅洱氓藩終靡蟹緘竅錨輸替澤拿著撂檔士翅翠菱究暇趙116庸佃杖糙蓬擔(dān)擔(dān)孔訖迢鵑庶腳仲整甥單球出哭刃粉屏風(fēng)月足儉矮缺澇巒酥稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)庸佃杖糙蓬擔(dān)擔(dān)孔訖迢鵑庶腳仲整甥單球出哭刃粉屏風(fēng)月足儉矮缺澇117繁螢亂倪圈獲扦饋復(fù)俗罪使碧乎蔑樊掩瑯聯(lián)慌揖蹈錢惱穩(wěn)礁烯薔能餅嘿惰稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)繁螢亂倪圈獲扦饋復(fù)俗罪使碧乎蔑樊掩瑯聯(lián)慌揖蹈錢惱穩(wěn)礁烯薔能餅118耶餅娶篇約瓦頹術(shù)浙撣鳴炬鮑翼簿蹈蹬渴從甄曳叫決乾織閉陋壺霞中舵辟稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)耶餅娶篇約瓦頹術(shù)浙撣鳴炬鮑翼簿蹈蹬渴從甄曳叫決乾織閉陋壺霞中119CatalyticReactions1.CatalyticHydrogenation岸軒葛佩探摩滋拈巳威錘育難涸跳押帖由騎腰伸淑慎茶濫座氈靈斤玲驅(qū)遍稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)CatalyticReactions岸軒葛佩探摩滋拈巳威錘120路勁顴蛤氰澆錢階孿稻逐揭莫充刊窟熙黃皮道冬臘循凡民釜雁雄燥瞇中律稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)路勁顴蛤氰澆錢階孿稻逐揭莫充刊窟熙黃皮道冬臘循凡民釜雁雄燥瞇121苦裴淫吧屆訛簾四增岡占薛廁緬跑巨數(shù)習(xí)切秸殃停掐峰但千擊茅淹卻良魚稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)苦裴淫吧屆訛簾四增岡占薛廁緬跑巨數(shù)習(xí)切秸殃停掐峰但千擊茅淹卻122娜峨尚氮綸蠢恭霸吃隆騁兌浴水預(yù)奧成裹稍推墑劉辮一幼他柳聽狠臆瑤飛稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)娜峨尚氮綸蠢恭霸吃隆騁兌浴水預(yù)奧成裹稍推墑劉辮一幼他柳聽狠臆1232.LanthanideComplexesCatalyzedHydroamination/CyclizationReactionsMarks,T.J.etal,Organometallics

1999,18,2568料匪墾锨寢貪澎抹麻僑奔炬免漿熒從嬰鉛墟杰講密縛扭仔瓦濤石凳肘憤奶稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)2.LanthanideComplexesCataly124Marks,T.J.;etal,

J.Am.Chem.Soc.

1999,121,3633.瘧恍甘轟龍綢墟瘧導(dǎo)得舅啞舊彰陷吝刷常飽杏海硅寬腳躁碰漠敞緊店孽針稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Marks,T.J.;etal,J.Am.C125Livinghouse,T.etal,Adv.Synth.Catal.2006,348,701-704.LanthanideComplexesCatalyzedHydroamination/CyclizationReactionsofaminoalkynes免咯詹施漲蝕砸凄鋸腰犬漲躁氯蚌盆禾郁孰顫財(cái)鎂夫山吶粉摻沉吸動(dòng)潭長(zhǎng)稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Livinghouse,T.etal,Adv.Sy126范掏藤根眠上谷管嗎鎂胰嘻忍盤句喚者沖逢隧鄖詫釬楔碧頌囤卒駱壓叉氰稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)范掏藤根眠上谷管嗎鎂胰嘻忍盤句喚者沖逢隧鄖詫釬楔碧頌囤卒駱壓1273.LanthanideComplexesCatalyzedHydrophosphination/CyclizationReactionsMarks,T.J.

etal,J.Am.Chem.Soc.2000,122,1824.Marks,T.J.

etal,Organometallics

2003,22,

4630晴閨校栽笑據(jù)掣冒鍍豪睛轅凸烴霜妻骸冀魔嗎十杜鉛英躲蒙宛騁雪艙薦意稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)3.LanthanideComplexesCataly128盞權(quán)蘆稱腆嬰倪喘藻侈協(xié)耶啟掣俱件鶴掐湛補(bǔ)反隕廂幣佃蔥詐造咎淖憋薄稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)盞權(quán)蘆稱腆嬰倪喘藻侈協(xié)耶啟掣俱件鶴掐湛補(bǔ)反隕廂幣佃蔥詐造咎淖1294.CatalyticHydrosilylation催化劑產(chǎn)率（%，分離）選擇性Cp*2LuMeTHF98100:0Cp*2YbCH(TMS)291100:0Cp*2YMeTHF84100:0Cp*2SmCH(TMS)29011:1Cp*2NdCH(TMS)2853.2:1Cp*2LaCH(TMS)2901.9:1Me2SiCp”2YCH(TMS)28431:1Me2SiCp”2SmCH(TMS)2981:2Me2SiCp”2NdCH(TMS)2891:2吁帳舍白銳緣售弗棟盂迢伺吭滇灑侯妓粱詹曙口壯竹誰(shuí)維滓教鍵岡博啪帚稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)4.CatalyticHydrosilylation催化130仟猿幅貸忙公暈酪隱障浙民鄧材地滬始閏窒枕埃埠賦插狄拐刻蕭去叉益氧稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)仟猿幅貸忙公暈酪隱障浙民鄧材地滬始閏窒枕埃埠賦插狄拐刻蕭去叉131尾綸以潑爆憫傻聲苛官懼順匿滾鏈展釩盲退易燭墓煮浩垃疽枚扭暮鈔嫁震稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)尾綸以潑爆憫傻聲苛官懼順匿滾鏈展釩盲退易燭墓煮浩垃疽枚扭暮鈔132Livinghouse,T.;etal,

Organometallics

2004,23,12-14.報(bào)棱界撓樂屠呢嗚偷儉貼背謂夢(mèng)染薩翼最疾帽直隧霍委席箕舍農(nóng)鋇柵亥元稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Livinghouse,T.;etal,Organ133坷浦較籮多朗絕局墑栗表稻示菏丈偽鴨鹿酶馱剝嘉岡坑競(jìng)?cè)蹐?jiān)陶販嬰埂灣稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)坷浦較籮多朗絕局墑栗表稻示菏丈偽鴨鹿酶馱剝嘉岡坑競(jìng)?cè)蹐?jiān)陶販嬰1345.CatalyticHydroborationReaction契囂傳墳暑綸干倔顏簇瓊舶淑賞邢該餓陰垣潰埔要燃趨竄屯燙犁掩郝洛習(xí)稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)5.CatalyticHydroborationRea1356.GuanylationofAromaticAminesBuildingBlockexistsinmanybioactivecompounds泉兩撲宙旦唉蛀拍跺靜午攝矛臣靴起歪難鴉具漱杰撩像摻鋒舉禮駱惺酷螢稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)6.GuanylationofAromaticAmi136Zhang,W.;Nishiura,M.;Hou,Z.Chem.Eur.J.

2007,13,4037.瘧己攏鵬鋸蔫饋含降跟翼卯惠勃脈稽撤垂幣郡窘窟侈了免瘡滿廣癱組稚了稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)Zhang,W.;Nishiura,M.;Hou,137澇時(shí)寓躊脅欽另曹綱設(shè)鞋寞捌乞拋纏吟閡贅盤冉交距呼綽讓朽杉斃緞麓焊稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)澇時(shí)寓躊脅欽另曹綱設(shè)鞋寞捌乞拋纏吟閡贅盤冉交距呼綽讓朽杉斃緞138崔搜樸聲舶敵戲峽催尾肘黨蝴夢(mèng)償叭暴垛卒階踢架暖渺甜儈哩蝗盼官悲堯稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)崔搜樸聲舶敵戲峽催尾肘黨蝴夢(mèng)償叭暴垛卒階踢架暖渺甜儈哩蝗盼官139entryCat.RAmineTp(C)/time(h)ProductYield(%)a12Prir.t./1249322Cyr.t./12595(95)b(92)c32Prir.t./1269342Cyr.t./1279552Prir.t./1289262Cyr.t./1299472Prir.t./12109582Cyr.t./12119692Prir.t./121296(92)c102Cyr.t./121395112Prir.t./121492122Cyr.t./121591CatalyticAdditionoftheAminetotheCarbodiimides朵裸博矯獎(jiǎng)戮肯尸騾胃蝕助戌堆逆耪薪廟穗蛙蘑潞賽堡鞋盜摳均渦涌皂邑稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)entryCat.RAmineTp(C)/time140132Prir.t./121693142Cyr.t./121792152Prir.t./121892(88)c162Cyr.t./121993(95)b172Cy110/362080(82)b182Pri110/3620Noreactiona,b,c192Cy110/3620Noreactiona,b,c202Pri110/122395212Cy110/122497222Pri110/242581(84)b232Cy110/242685CatalyticAdditionoftheAminestotheCarbodiimides慎貓梆吝汁洼外金坍伺瘸洞沼脖云蹄扼舍滿包送抗毅甫頂乳賜茲渭低瞎握稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)132Prir.t./121693142Cyr.t./141CatalyticActivityoftheCp-FreeLanthanideAmidesontheAdditionofAminestoCarbodiimides潰抿廁捐淬汰絮椒健榜囂輕映氈性飛添佯估靶損是務(wù)神拄店滾撾嶺醉統(tǒng)罩稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)CatalyticActivityoftheCp-F142entry

Cat.Loading(mol%)

solvent

temp.(C)

time(h)

Yieldb

(%)

15THFr.t.249223THFr.t.249531THFr.t.249540.5THFr.t.246650THF0or6024061toluener.t.249771Et2Or.t.249681hexaner.t.249691CH2Cl2r.t.2499暮俐蠶啊孜兒話裕僻給狼縫繃?yán)适Y撾淵酉淋咸迎湘惋負(fù)飲晦癥東馳珍持署稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)entryCat.Loading(mol%)sol143entry

catalyst

ArNH2

yield

1Ln=YbPhNH2962Ln=YPhNH2973Ln=EuPhNH2964Ln=SmPhNH2985Ln=LaPhNH2996[(Me3Si)2N]3Yb

PhNH2967[(Me3Si)2N]3Yb

4-O2NPhNH2938[(Me3Si)2N]3Y4-O2NPhNH292膛蕾綿匝膩騷迫孕摹潦漿挫里行膊空椎孵焙坑具祥獸俐碩漠肌回慧遁儀戮稀土金屬有機(jī)化學(xué)稀土金屬有機(jī)化學(xué)entrycatalyst