2《錳礦石與錳精礦氧化鉀、氧化鈉含量的測定火焰原子發(fā)射光譜法》編制說明根據(jù)國家標準化管理委員會關(guān)于下達2024年劃編號為20240145-T-605）國家標準的編制工作，該項目計劃2024年完成。GB/T6397.1-2004《測量方義》、GB/T6397.2-2004《（2）充分考慮生產(chǎn)技術(shù)及應用領(lǐng)域的發(fā)展，本著檢測分析方法的技術(shù)性能指標適3在化學工業(yè)方面，錳礦石還是制取二氧化錳、硫酸錳、高錳酸不同產(chǎn)地、不同礦中錳礦石成分差異較大。隨著經(jīng)濟的發(fā)展，對產(chǎn)品的要求越來經(jīng)檢索，國內(nèi)現(xiàn)僅有一項錳礦石中鉀、鈉含量檢測的相關(guān)標準GB/T14949.7-1994《錳礦石化學分析方法鈉和鉀量的測定》，檢測方法為火焰原子吸收光譜法。未檢索到采用火焰原子發(fā)射光譜法測定錳礦石與錳精原子發(fā)射光譜法（AtomicEmissionSpectrometry，AES）是利用物質(zhì)在熱激發(fā)或電光譜法可對約70種元素（金屬元素及磷、硅、砷、碳、硼等非金屬元素）進行分析。concentrates—Determinationofpotassiumandsodiumcontents—Flameatomicemission4我們在修改采用ISO4571:1981標準的基礎(chǔ)上，修改了前言部分；增加了警告；修表達方式。主要技術(shù)內(nèi)容為通過國內(nèi)8家實驗室10個水平樣品的標準適用于錳礦石與錳精礦中氧化鉀、氧化鈉含量的測定。測定范圍：氧化鉀用單色配置消除鈣的干擾，用硝酸銫溶液消除堿元本標準修改采用ISO4571:1981《Manganeseoresandconcentrates—Determinationofpotassiumandsodiumcontents—Flameatomicemissionspectrometricmethod》，標準本文件與ISO4571:1981《錳礦石和錳精礦鉀和鈉含量的測定火焰原子發(fā)射光譜5——增加了警告；——增加了術(shù)語和定義；——增加了分析天平；——刪除了低鐵含量（易分解）的樣品的處理；——增加了最終結(jié)果表示；——增加了試驗報告；——增加了試驗結(jié)果驗收流程圖。經(jīng)過實驗室驗證，使用ISO4571:1981《錳礦石和錳精礦鉀和鈉含量的測定火焰采用5個錳礦石標準樣品進行驗證，根據(jù)本方法對試樣進行氧化鉀含量的測定。驗61234t采用5個錳礦石標準樣品進行驗證，根據(jù)本方法對試樣進行氧化鈉含量的測定。驗Na2O1234t致，根據(jù)標準物質(zhì)證書提供的均值和標準偏差做C值檢驗，小于C值，測量結(jié)果和標Sr—重復性標準偏差；n1—實驗室組數(shù)；n2—實驗室內(nèi)檢測次數(shù)。表3協(xié)同實驗中標準樣品的結(jié)果比對%水平編號協(xié)同實驗總平均值標稱值標準不確定度差值7858AMnOre-90.05620.0600.0050.00380.0108標稱值和協(xié)同實驗總平均值沒有顯著性差異9GBW072650.46090.4600.0100.00090.0225GSB03-2589-20100.49370.4900.0200.00370.0165Na2O858AMnOre-90.71900.7900.0400.07109GBW072650.02670.0240.0020.00270.0046GSB03-2589-20100.07360.0760.0040.00240.0052倍標準偏差對應的濃度作為檢出限（detec），SA—空白試驗標準偏差；稱樣量取0.5000g，得出本方法的鈉檢出限為0.0002807%，計算得氧化鈉檢出限為Na/發(fā)射強度m8sNa=0.003%，10DLNa2O=0.0040%，ISO4571:1981（E）中規(guī)定的鈉測定得氧化鈉測定范圍為0.027%～1.35%，由于本次協(xié)同試驗驗證氧化鈉范圍為0.0267%~組織了8家實驗室參加10個水平的精密度協(xié)同實驗，每家每水平報出4個結(jié)果。實驗室樣品水平測定結(jié)果K2O/%測定結(jié)果Na2O/%12341234110.97630.97030.98490.98440.14520.14610.14330.1433920.73660.73500.74080.74410.77200.77440.77690.772734.84514.84184.76674.76791.16821.17171.19961.185442.38352.44042.42842.39991.32121.37431.36921.350351.70721.73251.73681.70020.93400.93430.93400.928663.04053.08273.06663.08820.67910.68440.68840.681073.42643.44783.54133.59030.73030.72410.72500.737980.05780.05970.05960.06230.77560.79010.80150.799290.46370.46900.46880.46690.02720.02570.02470.02440.48770.49110.49160.48890.07710.07780.07670.0762211.02421.00280.97090.99390.15610.16030.16260.167720.67830.71960.70200.72640.77160.75410.74420.777734.14804.33924.18244.53111.22761.24531.25591.217142.16412.17562.37972.22491.29881.32401.28251.272151.70211.59951.66601.63901.03181.04071.06751.062862.75312.77592.94042.91180.65230.63570.64730.630773.54813.47013.62893.44700.66980.66380.65850.651280.05910.05810.05380.06170.62400.61790.63990.616090.46400.50520.45460.50930.02820.02680.02750.02910.48770.50800.49700.54540.07900.07580.07470.0774310.94490.95340.97360.97040.17360.17930.17430.178320.72420.72900.71630.70140.73860.73440.75800.747134.73964.63354.81004.68871.14501.13311.16401.146542.31562.32872.27012.28611.29881.31461.30181.329351.72081.70281.65011.66431.07351.07071.09541.081563.07693.05532.99663.02070.65980.66810.65540.665173.45293.34663.41813.37120.70070.70580.69230.717180.06240.06080.05910.06000.77190.80070.78490.792090.46760.44920.46160.45760.02750.02830.02640.02800.49000.48880.49200.47210.06980.06710.06890.0662410.97850.96610.96340.95430.45740.43300.44280.445220.71310.70900.71260.70960.74170.74990.75500.746934.71254.82744.76084.72581.14921.13681.14381.150742.33992.35172.33762.34911.29351.29891.334351.74801.74371.73471.73050.90790.90410.91610.908363.04933.06223.04903.05920.67040.66340.66090.667573.42323.41663.42213.43440.70430.70950.70680.711180.05750.05850.06130.06050.82670.81390.82170.825490.45530.45030.46050.45800.02310.02330.02290.02430.48630.49550.49360.49770.07170.07050.06920.0709510.97370.94250.95461.00630.15970.16040.15500.152920.71710.70950.70230.71490.72310.74880.74770.730134.92854.87134.76824.73311.14261.13971.15661.154842.43122.42152.40462.37201.34761.32871.31201.321451.72351.75371.72701.75150.92660.94720.91930.921863.09643.09553.09923.08790.66120.66740.66520.653973.56323.44363.47413.48700.71550.72350.71150.725080.05960.05960.06110.05890.77700.78900.79770.798290.46560.47580.48000.47640.02440.02480.02360.02530.51040.52320.51380.51200.07750.07760.08130.0824611.00601.00201.00700.99900.13100.12590.13200.128120.65600.66000.66010.65800.73900.75390.74300.736034.84414.85904.84124.85501.21601.21811.22401.218642.40502.38312.39022.40101.31301.29301.30501.296051.73591.74901.74201.74590.87500.85890.85500.873063.03013.04703.05593.05700.66740.65630.66630.669373.51203.51303.51003.49200.70920.70770.70380.717880.05000.05300.05180.05000.79600.79600.78490.787990.43800.43990.43290.44000.03500.03800.02600.02660.48400.49300.49500.47890.07820.07580.08100.0737710.96030.94460.96870.95610.17960.17890.17430.176320.71410.72370.70980.71990.75310.75780.74030.746534.74944.73084.76034.72541.15691.16141.150742.32812.34562.31482.33891.32391.31241.31961.303151.72031.72571.74381.74981.08901.06841.08411.092363.06223.04553.03473.05750.67080.65540.67490.667073.43703.42313.44233.41770.70610.69580.71470.712780.05140.05890.04940.04770.58760.57710.59380.583490.46520.46110.45680.46370.03260.02930.02590.03070.49090.48520.47880.49290.07170.07980.06440.0696810.94630.94790.95330.93830.17850.18430.19900.202320.70940.72320.73190.73650.72950.74760.75340.760734.66834.69134.66954.77171.13991.12631.15631.170342.30702.32202.33292.27951.30011.32271.28521.326851.66781.65521.66641.69321.09481.09501.10721.089063.02463.01293.00752.99900.66350.67580.65770.648773.38903.37963.40403.38200.71590.72970.69210.695880.04970.04710.04660.05080.55590.56790.55240.561490.46440.47890.47230.46440.02840.03140.02880.02550.49650.49360.50740.49260.06510.06440.06580.0690實驗室水平12345678916.99875E-034.12098E-034.39886E-022.60113E-021.81810E-022.13958E-027.74450E-021.85203E-032.45628E-031.83916E-0322.20657E-022.14716E-021.75002E-019.93154E-024.33235E-029.44878.24987E-023.28773E-032.79987E-022.53150E-0231.37036E-021.20774E-027.51205E-022.67968E-023.28835E-023.57033E-024.75242E-021.40089E-037.71838E-039.17873E-0349.98645E-032.07425E-035.13930E-026.87380E-038.03383E-036.78104E-037.46430E-031.75404E-034.36759E-034.94259E-0352.78250E-026.59166E-039.04203E-022.59886E-021.58805E-024.83080E-035.08508E-029.27362E-046.18466E-035.73730E-0363.69685E-031.94143E-038.52697E-031.00088E-025.64683E-031.24349.91211.46969E-033.32966E-037.58304E-0371.00276.15054E-031.62229E-021.34602E-021.41306E-021.23751.15353E-024.93727E-033.67967E-036.33745E-0386.20403E-031.19193E-024.88247E-022.31457E-021.60560E-021.07210E-021.09829E-022.02402E-037.00524E-036.78792E-03聯(lián)合單元內(nèi)標準差1.46280E-029.44210E-037.85468E-023.91507E-022.19006E-023.71440E-024.73486E-022.41544E-031.07905E-021.05089E-02實驗室水平12345678910.4780.4360.5600.6640.8300.5760.7670.2280.17522.2742.2282.5372.5442.5952.40930.9370.9560.6840.9610.5800.7150.87340.6830.2200.6540.1760.3670.1830.1580.7260.4050.47050.6980.6640.7250.1300.3840.5730.54660.2530.2060.1090.2560.2580.3350.2090.6080.3090.72270.6850.6510.2070.3440.6450.3330.2442.0440.3410.60380.4240.6220.5910.7330.2890.2320.8380.6490.6465超出顯著性水平1%的臨界值1.81（圖中紅實線），結(jié)合科克倫檢驗確定是否是離群實驗室水平/方差12345678914.89825E-051.69825E-051.93500E-036.76588E-043.30549E-044.57780E-045.99773E-033.43002E-066.03333.382524.86895E-044.61030E-043.06257E-029.86355E-031.87693E-038.92786.80604E-031.08092E-057.83927E-046.40849E-0431.87789E-041.45864E-045.64309E-037.18068E-041.08132E-031.27473E-032.25855E-031.96249E-065.95734E-058.424949.97292E-054.30252.64124E-034.72496.45424E-054.59825E-055.57158E-053.07666E-061.90758E-052.44292E-0557.74234.34500E-058.17583E-036.75407E-042.52190E-042.33366E-052.58580E-038.60000E-073.82500E-053.29166E-0561.36667E-053.76915E-067.27092E-051.00176E-043.18867E-051.54607E-049.82499E-052.15999E-061.10866E-055.75025E-0571.00543E-043.78292.63182E-047E-041.99674E-041.53143E-041.33063E-042.43766E-051.35400E-054.01633E-0583.84900E-051.42070E-042.38385E-035.35723E-042.57795E-041.14940E-041.20624E-044.09666E-064.90734E-054.60759E-05方差和1.75033E-038.55297E-045.17406E-021.27979E-024.09489E-033E-021.80558E-025.07716E-059.80560E-049.29568E-04最大方差7.74234.61030E-043.06257E-029.86355E-031.87693E-038.92786.80604E-032.43766E-057.83927E-046.40849E-04C0.4420.5390.5920.7710.4580.8010.3770.4800.7990.689值C（8，4）：0.521（1%），0.438（5%）實驗室水平/方差12345678914.89825E-051.69825E-051.93500E-036.76588E-043.30549E-044.57780E-045.99773E-033.43002E-066.03331E-063.38251E-0624.86895E-040.00046103*0.0306257*0.00986355*1.87693E-030.00892781*6.80604E-031.08092E-050.000783927*0.000640849*31.87789E-041.45864E-045.64309E-037.18068E-041.08132E-031.27473E-032.25855E-031.96249E-065.95734E-058.42491E-0549.97292E-054.30252.64124E-034.72496.45424E-054.59825E-055.57158E-053.07666E-061.90758E-052.44292E-0557.74234.34500E-058.17583E-036.75407E-042.52190E-042.33366E-052.58580E-038.60000E-073.82500E-053.29166E-0561.36667E-053.76915E-067.27092E-051.00176E-043.18867E-051.54607E-049.82499E-052.15999E-061.10866E-055.75025E-0571.00543E-043.78292.63182E-047E-041.99674E-041.53143E-041.33063E-042.43766E-051.35400E-054.01633E-0583.84900E-051.42070E-042.38385E-035.35723E-042.57795E-041.14940E-041.20624E-044.09666E-064.90734E-054.60759E-05方差和1.75033E-033.94267E-049E-022.93439E-034.09489E-032.22452E-031.80558E-025.07716E-051.96633E-042.88719E-04最大方差7.74231.45864E-048.17583E-037.18068E-041.87693E-031.27473E-036.80604E-032.43766E-055.95734E-058.42491E-05C0.4420.3700.3870.2450.4580.5730.3770.4800.3030.292值C（7，4）：0.568（1%），0.480（5%）C（6，4），0.626（1%），0.532（5%）實驗室水平/方差12345678914.89825E-051.69825E-051.93500E-036.76588E-043.30549E-044.57780E-045.99773E-033.43002E-066.03331E-063.38251E-0624.86895E-040.00046103**0.0306257**0.00986355**1.87693E-030.00892781**6.80604E-031.08092E-050.000783927**0.000640849**31.87789E-041.45864E-045.64309E-037.18068E-041.08132E-030.00127473*2.25855E-031.96249E-065.95734E-058.42491E-0549.97292E-054.30252.64124E-034.72496.45424E-054.59825E-055.57158E-053.07666E-061.90758E-052.44292E-0557.74234.34500E-058.17583E-036.75407E-042.52190E-042.33366E-052.58580E-038.60000E-073.82500E-053.29166E-0561.36667E-053.76915E-067.27092E-051.00176E-043.18867E-051.54607E-049.82499E-052.15999E-061.10866E-055.75025E-0571.00543E-043.78292.63182E-047E-041.99674E-041.53143E-041.33063E-042.43766E-051.35400E-054.01633E-0583.84900E-051.42070E-042.38385E-035.35723E-042.57795E-041.14940E-041.20624E-044.09666E-064.90734E-054.60759E-05方差和1.75033E-033.94267E-049E-022.93439E-034.09489E-039.49789E-041.80558E-025.07716E-051.96633E-042.88719E-04最大方差7.74231.45864E-048.17583E-037.18068E-041.87693E-034.57780E-046.80604E-032.43766E-055.95734E-058.42491E-05C0.4420.3700.3870.2450.4580.4820.3770.4800.3030.292值C（7，4）：0.568（1%），0.480（5%）C（6，4），0.626（1%），0.532（5%）實驗室水平12345678911.40564E-032.18021.43230E-022.40306E-022.75363E-034.08768E-036.33739E-031.17476E-021.26227E-036.757723.60624E-032.36882.74357E-027.35393.32340E-031.17380E-025.16188E-031.68999E-021.13137E-031.90919E-0332.84411.04211.27321.39191.10735.63261.03701.21738.34661.64315E-036E-028E-026E-022E-024E-033E-020E-026E-047E-0341.00333E-025.56619E-036.29146E-032.77966E-025.03587E-034.22572.99819E-035.75406E-036.21825E-041.04363E-0353.63593E-031.28300E-028.51523E-031.50874E-021.26837E-025.93373E-036.44690E-039.92686E-037.18215E-042.52323E-0362.77909E-037.82746E-033.40820E-039.06918E-031.00055.81686E-035.90614E-035.67627E-036.01997E-033.14364E-0372.43909E-037.64782E-038.65987E-039.10110E-031.05838E-028.39459E-038.51680E-037.03012.82769E-036.40020E-0381.14430E-021.33254E-021.91705E-021.95774E-027.65681.13541.76483E-026.77003E-032.41575E-032.03204E-03聯(lián)合單元內(nèi)標準差5.93266E-031.20800E-021.45181.72262E-028.64743E-037.68524E-038.97067E-031.01914E-022.61113E-032.94176E-03實驗室水平12345678910.2370.1800.9870.3180.5320.7060.4830.23020.6080.4270.3840.5750.4330.64930.4790.8630.8770.8080.7330.3200.55940.4610.4330.5820.5500.3340.5650.2380.35550.6130.5870.8760.7720.7190.9740.2750.85860.4680.6480.2350.5260.7570.6580.5572.30670.4110.6330.5960.5280.9490.6902.17680.8850.6640.9250.691），實驗室水平/方差12345678911.97582E-064.75332E-062.05148E-045.77470E-047.58248E-061.67094.01625E-051.38006E-041.59333E-064.56666E-0721.30050E-055.61126E-047.52718E-045.40800E-051.10450E-051.37782.66450E-052.85607E-041.28000E-063.645038.08919E-061.08610E-041.62124E-041.93755E-041.22616E-043.17266E-051.07543E-041.48182E-046.96667E-072.700041.00667E-043.09825E-053.95825E-057.72652.53600E-051.78566E-058.98914E-063.31092E-053.86666E-071.08916E-0651.32200E-051.64609E-047.25092.27630E-041.60876E-043.52092E-054.15625E-059.85425E-055.15833E-076.36669E-0667.72334E-066.12691.16158E-058.22500E-051.00102E-043.38359E-053.48825E-053.22200E-053.62400E-059.88247E-0675.94916E-065.84892E-057.49933E-058.28300E-051.12017E-047.04697.25359E-054.94224E-057.99583E-064.09626E-0581.30942E-041.77566E-043.67508E-043.83275E-045.86267E-051.28916E-043.11462E-044.58333E-055.83585E-064.12919E-06方差和2.81572E-041.16741.68620E-032.37394E-035.98225E-044.72504E-046.43783E-048.30922E-045.45442E-056.92318E-05最大方差1.30942E-045.61126E-047.52718E-047.72651.60876E-041.37783.11462E-042.85607E-043.62400E-054.09626E-05C0.4650.4810.4460.3250.2690.2920.4840.3440.6640.592值C（8，4）：0.521（1%），0.438（5%）實驗室水平/方差12345678911.97582E-064.75332E-062.05148E-045.77470E-047.58248E-061.67094.01625E-051.38006E-041.59333E-064.56666E-0721.30050E-055.61126E-047.52718E-045.40800E-051.10450E-051.37782.66450E-052.85607E-041.28000E-063.64501E-0638.08919E-061.08610E-041.62124E-041.93755E-041.22616E-043.17266E-051.07543E-041.48182E-046.96667E-072.70001E-0641.00667E-043.09825E-053.95825E-057.72652.53600E-051.78566E-058.98914E-063.31092E-053.86666E-071.08916E-0651.32200E-051.64609E-047.25092.27630E-041.60876E-043.52092E-054.15625E-059.85425E-055.15833E-076.36669E-0667.72334E-066.12691.16158E-058.22500E-051.00102E-043.38359E-053.48825E-053.22200E-050.00003624*9.88247E-0675.94916E-065.84892E-057.49933E-058.28300E-051.12017E-047.04697.25359E-054.94224E-057.99583E-060.0000409626*81.30942E-041.77566E-043.67508E-043.83275E-045.86267E-051.28916E-043.11462E-044.58333E-055.83585E-064.12919E-06方差和2.81572E-041.16741.68620E-032.37394E-035.98225E-044.72504E-046.43783E-048.30922E-041.83042E-052.82692E-05最大方差1.30942E-045.61126E-047.52718E-047.72651.60876E-041.37783.11462E-042.85607E-047.99583E-069.88247E-06C0.4650.4810.4460.3250.2690.2920.4840.3440.4370.350值C（7，4）：0.568（1%），0.480（5%）C（6，4），0.626（1%），0.532（5%）實驗室水平12345678910.978980.739134.805382.413051.719183.069503.501450.059850.467100.4898320.997950.706584.300182.236081.651652.845303.523530.058180.483280.5095330.960580.717734.717952.300131.684503.037383.397200.060580.459000.4857340.96550.71104.75662.34451.73923.05493.42400.05940.45600.4932883833853850.969280.710954.825282.407331.738933.094753.491980.059800.474450.5148561.003500.658534.849832.394831.743203.047503.506750.051200.437700.4877370.957430.716884.741482.331851.734903.049983.430030.051850.461700.4869580.946450.725254.700202.310351.670653.011003.388650.048550.470000.49753總平均值0.972470.710774.712122.342281.710283.026293.457960.056180.463660.49568水平標準差1.98449E-022.34412E-021.74512E-016.11673E-023.60568E-027.69966E-025.36553E-024.81652E-031.36857E-021.09618E-02實驗室水平12345678910.978980.739134.805382.413051.719183.06953.501450.059850.467100.4898320.997950.70658*4.30018*2.23608*1.651652.8453*3.523530.058180.48328*0.50953*30.960580.717734.717952.300131.684503.03738*3.397200.060580.459000.4857340.965580.711084.756632.344581.739233.054933.424080.059450.456030.4932850.969280.710954.825282.407331.738933.094753.491980.059800.474450.5148561.003500.658534.849832.394831.743203.047503.506750.051200.437700.4877370.957430.716884.741482.331851.734903.049983.430030.051850.461700.4869580.946450.725254.700202.310351.670653.0113.388650.048550.470000.49753總平均值0.972470.711364.770962.357451.710283.054613.457960.056180.460850.49370水平標準差1.98449E-022.52534E-025.66382E-024.70844E-023.60568E-022.75930E-025.36553E-024.81652E-031.20488E-021.01806E-02實驗室水平12345678910.3280.6080.2470.5400.8110.7620.519-0.3802///-1.626/0.415//3-0.5990.252-0.936-1.217-0.715/-1.1320.914-0.154-0.7834-0.347-0.011-0.253-0.2730.8030.012-0.6310.679-0.400-0.0415-0.161-0.0160.9590.7950.6340.7522.0776-2.0920.7940.913-0.2580.909-1.034-1.921-0.5867-0.7580.219-0.520-0.5440.683-0.168-0.521-0.8990.071-0.6638-1.3110.550-1.249-1.000-1.099-1.580-1.292-1.5840.7590.376），實驗室水平12345678910.978980.739134.805382.413051.719183.069503.501450.059850.467100.4898320.997950.70658*4.30018*2.23608*1.651652.8453*3.523530.058180.48328*0.50953*30.960580.717734.717952.300131.684503.037383.397200.060580.459000.48573*40.965580.711084.756632.344581.739233.054933.424080.059450.456030.4932850.969280.710954.825282.407331.738933.094753.491980.059800.474450.5148561.003500.658534.849832.394831.743203.047503.506750.051200.437700.4877370.957430.716884.741482.331851.734903.049983.430030.051850.461700.4869580.946450.725254.700202.310351.670653.011003.388650.048550.470000.49753平均值0.972470.711364.770962.357451.710283.054613.457960.056180.460850.49370標準偏差0.019840.025250.056640.047080.036060.027590.053660.004820.012050.01018最大值1.003500.739134.849832.413051.743203.094753.523530.060580.474450.51485最小值0.946450.658534.700202.300131.651653.011003.388650.048550.437700.48573GMAX0.9130.9132.078GMIN2.0920.783G臨界值G（8），2.274（1%），2.216（5%）；G（7），2.139（1%），2.020（5%）；G（6），1.973（1%），1.887（5%）無岐小岐無岐無岐無岐無岐無岐無岐無岐大岐離，無離，無離，無離，無離，無離，無離，無離，無離，無離，無離群離群離群離群離群離群離群離群離群離群序號水平12345678910.946450.658534.700202.300131.651653.011003.388650.048550.437700.4857320.957430.710954.717952.310351.670653.047503.397200.051200.456030.4869530.960580.711084.741482.331851.684503.049983.424080.051850.459000.4877340.965580.716884.756632.344581.719183.054933.430030.058180.461700.4898350.969280.717734.805382.394831.734903.069503.491980.059450.467100.4932860.978980.725254.825282.407331.738933.094753.501450.059800.470000.4975370.997950.739134.849832.413051.73923/3.506750.059850.474450.5148581.00350///1.74320/3.523530.06058//離差平方和2.75673E-033.82641.92473E-021.33016E-029.10063E-033.80686E-032.01522E-021.62392E-048.71045E-046.21869E-04A4E-042.51569E-036.52988E-035.49578E-036.54082E-031.21685E-031.12923E-021.18763E-044.99123E-043.50775E-05B1.57264E-034.67692E-048.36505.61818E-032.48344E-034E-038.83730E-035.27890E-051.55090E-044.69450E-04GMAX,20.2220.6570.3390.4130.7190.3200.5600.7310.5730.056GMIN,20.5700.4350.4220.2730.3180.4390.3250.1780.755臨界值G（8），0.0563（1%），0.1101（5%）；G（7），0.0308（1%），0.0708（5%）；G（6），0.0116（1%），0.0349（5%）實驗室水平123456789180.774001.181231.353750.932730.683230.729330.791600.025500.0769520.165150.760951.236501.277301.065150.639000.654850.627950.028300.0760530.176380.744531.1471531.080280.662100.703980.787380.027550.0680040.444600.748381.145131.319450.909100.665550.707930.821930.023400.0705850.157000.737431.148431.327430.928730.661930.718880.790480.024530.0797060.129250.742981.219181.301750.865480.664830.709630.791200.031400.0771870.177280.749431.152601.314751.083450.667030.707330.585480.029630.0713880.191030.747801.148201.308701.096500.661430.708380.559400.028530.06608總平均值0.198150.750691.172301.314280.995180.663140.705040.719430.027360.07324水平標準差1.01494E-011.15704E-023.64663E-022.17890E-029.46743E-021.20452E-022.18682E-021.08530E-012.69690E-034.9015實驗室水平12345678910.144480.774001.181231.353750.932730.683230.729330.791600.025500.0769520.165150.760951.236501.277301.065150.639000.654850.627950.028300.0760530.176380.744531.147151.080280.662100.703980.787380.027550.0680040.444600.748381.145131.319450.909100.665550.707930.821930.023400.0705850.157000.737431.148431.327430.928730.661930.718880.790480.024530.0797060.129250.742981.219181.301750.865480.664830.709630.791200.03140*0.0771870.177280.749431.152601.314751.083450.667030.707330.585480.029630.07138*80.191030.747801.148201.308701.096500.661430.708380.559400.028530.06608總平均值0.198150.750691.172301.314280.995180.663140.705040.719430.026780.07351水平標準差1.01494E-011.15704E-023.64663E-022.17890E-029.46743E-021.20452E-022.18682E-021.08530E-012.31709E-035.23163E-03實驗室水平1234567891-0.5292.0150.245-0.6600.665-0.5520.6582-0.3250.887-1.6970.739-2.004-2.295-0.8430.6560.4863-0.214-0.532-0.690-0.1450.899-0.086-0.0480.6260.332-1.05342.428-0.200-0.7450.237-0.9090.2000.1320.944-1.459-0.5605-0.405-1.146-0.6550.604-0.702-0.1000.6330.655-0.9716-0.679-0.666-0.575-1.3700.1400.2100.661/0.7027-0.206-0.109-0.5400.0220.9320.3230.105-1.234/8-0.070-0.250-0.661-0.2560.153-1.4750.755-1.420），實驗室水平12345678910.144480.774001.181231.353750.932730.683230.729330.791600.025500.0769520.165150.760951.236501.277301.065150.639000.654850.627950.028300.0760530.176380.744531.147151.080280.662100.703980.787380.027550.0680040.444600.748381.145131.319450.909100.665550.707930.821930.023400.0705850.157000.737431.148431.327430.928730.661930.718880.790480.024530.0797060.129250.742981.219181.301750.865480.664830.709630.791200.03140*0.0771870.177280.749431.152601.314751.083450.667030.707330.585480.029630.07138*80.191030.747801.148201.308701.096500.661430.708380.559400.028530.06608平均值0.198150.750691.172301.314280.995180.663140.705040.719430.026780.07351標準偏差0.101490.011570.036470.021790.094670.012050.021870.108530.002320.00523最大值0.444600.774001.236501.353751.096500.683230.729330.821930.029630.07970最小值0.129250.737431.145131.277300.865480.639000.654850.559400.023400.06608GMAX2.4282.0150.944GMIN0.6790.7452.0032.295G臨界值G（8），2.274（1%），2.216（5%）；G（7），2.139（1%），2.020（5%）最大離群無離群無離群無離群無離群無離群最小離群無離群無離群無離群實驗室水平123456789180.774001.181231.353750.932730.683230.729330.791600.025500.0769520.165150.760951.236501.277301.065150.639000.65485*0.627950.028300.0760530.176380.744531.1471531.080280.662100.703980.787380.027550.0680040.4446*0.748381.145131.319450.909100.665550.707930.821930.023400.0705850.157000.737431.148431.327430.928730.661930.718880.790480.024530.0797060.129250.742981.219181.301750.865480.664830.709630.791200.03140*0.0771870.177280.749431.152601.314751.083450.667030.707330.585480.029630.071380.191030.747801.148201.308701.096500.661430.708380.559400.028530.06608平均值0.162940.750691.172301.314280.995180.663140.712210.719430.026780.07351標準偏差0.021180.011570.036470.021790.094670.012050.008840.108530.002320.00523最大值0.191030.774001.236501.353751.096500.683230.729330.821930.029630.07970最小值0.129250.737431.145131.277300.865480.639000.703980.559400.023400.06608GMAX2.0150.944GMIN0.7452.0030.931G（8），2.274（1%），2.216（5%）；G（7），2.139（1%），2.020（5%）；界值G（6），1.973（1%），1.887（5%）無岐無岐無岐無岐無岐無岐無岐無岐無岐無岐離，無離，無離，無離，無離，無離，無離，無離，無離，無離，無離群離群離群離群離群離群離群離群離群離群序號水平12345678910.129250.737431.145131.277300.865480.639000.703980.559400.023400.06608280.742981.147151.301750.909100.661430.707330.585480.024530.0680030.157000.744531.148201.308700.928730.661930.707930.627950.025500.0705840.165150.747801.1484330.932730.662100.708380.787380.027550.0760550.176380.748381.152601.314751.065150.664830.709630.790480.028300.0769560.177280.749431.181231.319451.080280.665550.718880.791200.028530.0771870.191030.760951.219181.327431.083450.667030.729330.791600.029630.079708/0.774001.236501.353751.096500.68323/0.82193//離差平方和2.69127E-039.37117E-049.30853E-033.32333E-036.27426E-021.01564.68774E-048.24518E-023.22135E-051.64220E-04A1.33636E-031.00445E-049.33433E-041.13140E-033.86933E-025.00874E-041.79030E-056.16509E-021.67597E-059.28727E-05B6.71769E-046.28695E-047.48122E-031.38994E-033.07520E-023.18752E-043.42905E-042.44975E-029.43228E-064.53215E-05GMAX,20.4970.1070.1000.3400.6170.4930.0380.7480.5200.566GMIN,20.2500.6710.8040.4180.4900.3140.7310.2970.2930.276臨界值G（8），0.0563（1%），0.1101（5%）；G（7），0.0308（1%），0.0708（5%）水平1實驗室1234檢測次數(shù)平均值方差10.97630.97030.98490.984440.978984.89825E-0521.02421.00280.97090.993940.997954.86897E-0430.94490.95340.97360.970440.960581.87789E-0440.97850.96610.96340.954340.965589.97292E-0550.97370.94250.95461.006340.969287.74229E-0461.00601.00201.00700.999041.003501.36667E-0570.96030.94460.96870.956140.957431.00543E-0480.94630.94790.95330.938340.946453.84900E-05總平均值0.97247（單元均值間方差*檢測次數(shù)）總和0.001575276平均檢測次數(shù)4重復性方差0.000218791實驗室間方差0.000339121再現(xiàn)性方差0.000557912水平2實驗室1234檢測次數(shù)平均值方差10.73660.73500.74080.744140.739131.69825E-0530.72420.72900.71630.701440.717731.45862E-0440.71310.70900.71260.709640.711084.30250E-0650.71710.70950.70230.714940.710954.34500E-0560.65600.66000.66010.658040.658533.76917E-0670.71410.72370.70980.719940.716883.78292E-0580.70940.72320.73190.736540.725251.42070E-04總平均值0.71136（單元均值間方差*檢測次數(shù)）總和0.002550938平均檢測次數(shù)4重復性方差5.63236E-05實驗室間方差0.000623654再現(xiàn)性方差0.000679977水平3實驗室1234檢測次數(shù)平均值方差14.84514.84184.76674.767944.805381.93500E-0334.73964.63354.81004.688744.717955.64310E-0344.71254.82744.76084.725844.756632.64124E-0354.92854.87134.76824.733144.825288.17583E-0364.84414.85904.84124.855044.849837.27092E-0574.74944.73084.76034.725444.741482.63183E-0484.66834.69134.66954.771744.700202.38385E-03總平均值4.77096（單元均值間方差*檢測次數(shù)）總和0.012831555平均檢測次數(shù)4重復性方差0.003016416實驗室間方差0.002453785再現(xiàn)性方差0.005470201水平4實驗室1234檢測次數(shù)平均值方差12.38352.44042.42842.399942.413056.76590E-0432.31562.32872.27012.286142.300137.18069E-0442.33992.35172.33762.349142.344584.72492E-0552.43122.42152.40462.372042.407336.75409E-0462.40502.38312.39022.401042.394831.00176E-0472.32812.34562.31482.338942.331851.81177E-0482.30702.32202.33292.279542.310355.35723E-04總平均值2.35745（單元均值間方差*檢測次數(shù)）總和0.008867752平均檢測次數(shù)4重復性方差0.000419199實驗室間方差0.002112138再現(xiàn)性方差0.002531337水平5實驗室1234檢測次數(shù)平均值方差11.70721.73251.73681.700241.719183.30549E-0421.70211.59951.66601.639041.651651.87692E-0331.72081.70281.65011.664341.684501.08133E-0341.74801.74371.73471.730541.739236.45425E-0551.72351.75371.72701.751541.738932.52189E-0461.73591.74901.74201.745941.743203.18867E-0571.72031.72571.74381.749841.734901.99673E-0481.66781.65521.66641.693241.670652.57797E-04總平均值1.71028（單元均值間方差*檢測次數(shù)）總和0.005200359平均檢測次數(shù)4重復性方差0.000511861實驗室間方差0.001172124再現(xiàn)性方差0.001160821水平6實驗室1234檢測次數(shù)平均值方差13.04053.08273.06663.088243.069504.