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1、分析化學中常見詞匯的中英對照第一章緒論分析化學:analytical chemistry定性分析:qualitative analysis定量分析:quantitative analysis物理分析:physical analysis物理化學分析:physico-chemical analysis儀器分析法:instrumental analysis流動注射分析法:flow injection analysis;FIA順序注射分析法:sequentical injection analysis;SIA化學計量學:chemometrics第二章誤差的分析數(shù)據(jù)處理絕對誤差:absolute err
2、or相對誤差:relative error系統(tǒng)誤差:systematic error可定誤差:determinate error隨機誤差:accidental error不可定誤差:indeterminate error準確度:accuracy精確度:precision偏差:debiation,d平均偏差:average debiation相對平均偏差:relative average debiation標準偏差(標準差):standerd deviation;S相對平均偏差:relatibe standard deviation;RSD變異系數(shù):coefficient of variatio
3、n誤差傳遞:propagation of error有效數(shù)字:significant figure置信水平:confidence level顯著性水平:level of significance合并標準偏差(組合標準差):pooled standard debiation舍棄商:rejection quotient;Q化學定量分析第三章滴定分析概論滴定分析法:titrametric analysis滴定:titration容量分析法:volumetric analysis化學計量點:stoichiometric point等當點:equivalent point電荷平衡:charge bala
4、nce電荷平衡式:charge balance equation質量平衡:mass balance物料平衡:material balance質量平衡式:mass balance equation第四章酸堿滴定法酸堿滴定法:acid-base titrations質子自遞反應:autoprotolysis reaction質子自遞常數(shù):autoprotolysis constant質子條件式:proton balance equation酸堿指示劑:acid-base indicator指示劑常數(shù):indicator constant變色范圍:colour change interval混合指示
5、劑:mixed indicator雙指示劑滴定法:double indicator titration第五章非水滴定法非水滴定法:nonaqueous titrations質子溶劑:protonic solvent酸性溶劑:acid solvent堿性溶劑:basic solvent兩性溶劑:amphototeric solvent無質子溶劑:aprotic solvent均化效應:differentiating effect區(qū)分性溶劑:differentiating solvent離子化:ionization離解:dissociation結晶紫:crystal violet萘酚苯甲醇:-na
6、phthalphenol benzyl alcohol奎哪啶紅:quinadinered百里酚藍:thymol blue偶氮紫:azo violet溴酚藍:bromophenol blue第六章配位滴定法配位滴定法:compleximetry乙二胺四乙酸:ethylenediamine tetraacetic acid,EDTA螯合物:chelate compound金屬指示劑:metal lochrome indcato r第七章氧化還原滴定法氧化還原滴定法:oxidation-reduction titration碘量法:iodimetry溴量法:bromimetry溴量法:bromine
7、 method鈰量法:cerimetry高錳酸鉀法:potassium permanganate method條件電位:conditional potential溴酸鉀法:potassium bromate method硫酸鈰法:cerium sulphate method偏高碘酸:metaperiodic acid高碘酸鹽:periodate亞硝酸鈉法:sodium nitrite method重氮化反應:diazotization reaction重氮化滴定法:diazotization titration亞硝基化反應:nitrozation reaction亞硝基化滴定法:nitroza
8、tion titration外指示劑:external indicator外指示劑:outside indicator重鉻酸鉀法:potassium dichromate method第八章沉淀滴定法沉淀滴定法:precipitation titration容量滴定法:volumetric precipitation method銀量法:argentometric method第九章重量分析法重量分析法:gravimetric analysis揮發(fā)法:volatilization method引濕水(濕存水):water of hydroscopicity包埋(藏)水:occluded wat
9、er吸入水:water of imbibition結晶水:water of crystallization組成水:water of composition液-液萃取法:liquid-liquid extration溶劑萃取法:solvent extration反萃?。篶ounter extraction分配系數(shù):partition coefficient分配比:distribution ratio離子對(離子締合物):ion pair沉淀形式:precipitation forms稱量形式:weighing forms分析化學下冊儀器分析概述物理分析:physical analysis物理化學
10、分析:physicochemical analysis儀器分析:instrumental analysis第十章電位法及永停滴定法電化學分析:electrochemical analysis電解法:electrolytic analysis method電重量法:electtogravimetry庫侖法:coulometry庫侖滴定法:coulometric titration電導法:conductometry電導分析法:conductometric analysis電導滴定法:conductometric titration電位法:potentiometry直接電位法:dirext pote
11、ntiometry電位滴定法:potentiometric titration伏安法:voltammetry極譜法:polarography溶出法:stripping method電流滴定法:amperometric titration化學雙電層:chemical double layer相界電位:phase boundary potential金屬電極電位:electrode potential化學電池:chemical cell液接界面:liquid junction boundary原電池:galvanic cell電解池:electrolytic cell銀-氯化銀電極:silver
12、silver-chloride electrode液接界面:liquid junction boun不對稱電位:asymmetry potential表觀PH值:apparent PH復合PH電極:combination PH electrode離子選擇電極:ion selective electrode敏感器:sensor晶體電極:crystalline electrodes均相膜電極:homogeneous membrance electrodes非均相膜電極:heterog eneous membrance electrodes非晶體電極:non-crystalline electrod
13、es剛性基質電極:rigid matrix electr ode負極:cathrode正極:anode電池電動勢:eletromotive force指示電極:indicator electrode參比電極:reference electroade標準氫電極:standard hydrogen electrode一級參比電極:primary reference electrode飽和甘汞電極:standard calomel electrode銀-氯化銀電極:silver silver-chloride electrode液接界面:liquid junction boundary不對稱電位:a
14、symmetry potential表觀PH值:apparent PH復合PH電極:combination PH electrode離子選擇電極:ion selective electrode敏感器:sensor晶體電極:crystalline electrodes均相膜電極:homogeneous membrance electrodes非均相膜電極:heterog eneous membrance electrodes非晶體電極:non-crystalline electrodes剛性基質電極:rigid matrix electrode流流體載動電極:electrode with amo
15、bile carrier氣敏電極:gas sensing electrodes酶電極:enzyme electrodes金屬氧化物半導體場效應晶體管:MOSFET離子選擇場效應管:ISFET總離子強度調節(jié)緩沖劑:total ion strength adjustment buffer,TISAB永停滴定法:dead-stop titration雙電流滴定法(雙安培滴定法):double amperometric titration第十一章光譜分析法概論普朗克常數(shù):Plank constant電磁波譜:electromagnetic spectrum光譜:spectrum光譜分析法:spectr
16、oscopic analysis原子發(fā)射光譜法:atomic emission spectroscopy質量譜:mass spectrum質譜法:mass spectroscopy,MS第十二章紫外-可見分光光度法紫外-可見分光光度法:ultraviolet and visible spectrophotometry;UV-vis肩峰:shoulder peak末端吸收:end absorbtion生色團:chromophor助色團:auxochrome紅移:red shift長移:bathochromic shift短移:hypsochromic shift藍(紫)移:blue shift增
17、色效應(濃色效應):hyperchromic effect減色效應(淡色效應):hypochromic effect強帶:strong band弱帶:weak band吸收帶:absorption band透光率:transmitance,T吸光度:absorbance譜帶寬度:band width雜散光:stray light噪聲:noise暗噪聲:dark noise散粒噪聲:signal shot nois閃耀光柵:blazed grating全息光柵:holographic graaing光二極管陣列檢測器:photodiode array detector偏最小二乘法:partial
18、 least squares method,PLS褶合光譜法:convolution spectrometry褶合變換:convolution transform,CT離散小波變換:wavelet transform,WT多尺度細化分析:multiscale analysis供電子取代基:electron donating group吸電子取代基:electron with-drawing group第十三章熒光分析法熒光:fluorescence熒光分析法:fluorometry X-射線熒光分析法:X-ray fulorometry原子熒光分析法:atomic fluorometry分子熒
19、光分析法:molecular fluorometry振動弛豫:vibrational relexation內轉換:internal conversion外轉換:external conversion體系間跨越:intersystem crossing激發(fā)光譜:excitation spectrum熒光光譜:fluorescence spectrum斯托克斯位移:Stokes shift熒光壽命:fluorescence life time熒光效率:fluorescence efficiency熒光量子產(chǎn)率:fluorescence quantum yield熒光熄滅法:fluorescence
20、 quemching method散射光:scattering light瑞利光:Reyleith scanttering light拉曼光:Raman scattering light第十四章紅外分光光度法紅外線:infrared ray,IR中紅外吸收光譜:mid-infrared absorption spectrum,Mid-IR遠紅外光譜:Far-IR微波譜:microwave spectrum,MV紅外吸收光譜法:infrared spectroscopy紅外分光光度法:infrared spectrophotometry振動形式:mode of vibration伸縮振動:str
21、etching vibration對稱伸縮振動:symmetrical stretching vibration不對稱伸縮振動:asymmetrical stretching vibration彎曲振動:bending vibration變形振動:formation vibration面內彎曲振動:in-plane bending vibration,剪式振動:scissoring vibration,面內搖擺振動:rocking vibration,面外彎曲振動:out-of-plane bending vibration,面外搖擺振動:wagging vibration,蜷曲振動:twis
22、ting vibration,對稱變形振動:symmetrical deformation vibration,s不對稱變形振動:asymmetrical deformation vibration,as特征吸收峰:charateristic avsorption band特征頻率:characteristic frequency相關吸收峰:correlation absorption band雜化影響:hybridization affect環(huán)大小效應:ring size effect吸收峰的強度:intensity of absorption band環(huán)折疊振動:ring prckerin
23、g vibration第十五章原子吸收分光光度法原子光譜法:atomic spectroscopy原子吸收分光光度法:atomic absorption spectrophotometry,AAS原子發(fā)射分光光度法:atomic emmsion spectrophotometry,AES原子熒光分光光度法:atomic fluorescence spectrophotometry,AFS第十六章核磁共振波譜法核磁共振:nuclear magnetic resonance,NMR核磁共振波譜:NMR spectrum核磁共振波譜法:NMR spectroscopy掃場:swept field掃頻
24、:seept frequency連續(xù)波核磁共振:continuous wave NMR,CW NMR Fourier變換NMR:PFT-NMR,FT-NMR二維核磁共振譜:2D-NMR質子核磁共振譜:proton magnetic resonance spectrum,PMR氫譜:1H-NMR碳-13核磁共振譜:13C-NMR spectrum,13CNMR自旋角動量:spin angular momentum磁旋比:magnetogyric ratio磁量子數(shù):magnetic quantum number,m進動:precession弛豫歷程:relaxation mechanism局部抗
25、磁屏蔽:local diamagnetic shielding屏蔽常數(shù):shielding constant化學位移:chemical shift國際純粹與應用化學協(xié)會:IUPAC磁各向異性:magnetic anisotropy遠程屏蔽效應:long range shielding effect結面:nodal plane自旋-自旋偶合:spin-spin coupling自旋-自旋分裂:spin=spin splitting單峰:singlet,s雙峰:doublet,d三重峰:triplet,t四重峰:quartet五重峰:quintet六重峰:sextet偕偶:geminal coup
26、ling鄰偶:vicinal coupling遠程偶合:long range coupling磁等價:magnetic eqivalence自旋系統(tǒng):spin system一級光譜:first order spectrum二級光譜(二級圖譜):second order spectrum C-H光譜:C-H correlated spectroscopy,C-H COSY第十七章質譜法質譜分析法:mass spectrometry質譜:mass spectrum,MS棒圖:bar graph選擇離子檢測:selected ion monitoring,SIM直接進樣:direct probe i
27、nlet,DPI接口:interface氣相色譜-質譜聯(lián)用:gas chromatography-mass spectrometry,GC-MS高效液相色譜-質譜聯(lián)用:high performance liquid chromatography-mass spectrometry,HPLC-MS電子轟擊離子源:electron impact source,EI離子峰:quasi-molecular ions化學離子源:chemical ionization source,CI場電離:field ionization,FI場解析:field desorptiion,FD快速原子轟擊離子源:fas
28、t stom bombardment,FAB質量分析器:mass analyzer磁質譜儀:magnetic-sector mass spectrometer四極桿質譜儀(四極質譜儀):quadrupole mass spectrometer原子質量單位:amu離子豐度:ion abundance相對豐度(相對強度):relative avundance基峰:base peak質量范圍:mass range分辨率:resolution靈敏度:sensitivity信噪比:S/N分子離子:molecular ion碎片離子:fragment ion同位素離子:isotopic ion亞穩(wěn)離子:m
29、etastable ion亞穩(wěn)峰:metastable peak母離子:paren ion子離子:daughter含奇數(shù)個電子的離子:odd electron含偶數(shù)個電子的離子:even eletron,EE均裂:hom olytic cleavage異裂(非均裂):heterolytic cleavage半均裂:hemi-homolysis cleavage重排:rearragement分子量:MW-裂解:-cleavage第十八章色譜分析法概論色譜法(層析法):chromatography固定相:stationary phase流動相:mobile phase超臨界流體色譜法:SFC高效毛
30、細管電泳法:high performance capillary electroporesis,HPEC氣相色譜法:gas chromatography,GC液相色譜法:liquid cromatography,LC超臨界流體色譜法:supercritical fluid chromatography,SFC氣-固色譜法:GSC氣-液色譜法:GLC液-固色譜法:LSC液-液色譜法:LLC柱色譜法:column chromatography填充柱:packed column毛細管柱:capillary column微填充柱:icrobore packed column高效液相色譜法:high p
31、erformance liquid chromatography,HPLC平板色譜法:planar平板色譜法:plane chromatography紙色譜法:paper chromatography薄層色譜法:thin layer chromatography,TLC薄膜色譜法;thiin film chomatography毛細管電泳法:capillary electrophoresis,CE分配色譜法:partition chromatography吸附色譜法:adsorpion chromaography離子交換色譜法:ion exchange chromatography,IEC空間
32、排阻色譜法:steric exclusion chromatography,SEC親和色譜法:affinity chromatography分配系數(shù):distribution cofficient狹義分配系數(shù):partition coefficient凝膠色譜法:gel chromatography凝膠滲透色譜法:gel permeation chromatography,GPC凝膠過濾色譜法:gel filtration chromatography,GFC滲透系數(shù):permeation coefficien;Kp化學鍵合相色譜法:chemically bonded-phase chroma
33、tography分配系數(shù):distribution coefficient靛菁綠:indocyanine氣相色譜-傅立葉變換紅外光譜:GC-FTIR第十九章經(jīng)典液相色譜法薄層色譜法:TLC吸附:adsorption活化:activation脫活性:deactivation交聯(lián)度:degree of cross linking交換容量:exchange capacity薄層板:thin layer plate展開劑:developing solvent,developer臨界膠束濃度:criticak micolle concentration,CMC相對比移值:relative Rf,Rr分離
34、度:resolution,R分離數(shù):separation number,SN煅石膏:Gypsum羧甲基纖維素鈉:CMC-Na吸收光譜聯(lián)用:TLC-UV薄層色譜-熒光聯(lián)用:TLC-F薄層色譜-紅外吸收光譜聯(lián)用:TLC-IR薄層色譜法:TLC-MS紙色譜法:paper chromatography上行展開:ascending development下行法展開:descending development雙向展開:two dimensional develoooment第二十章氣相色譜法氣相色譜法:gas chromatography前延峰:leading peak拖尾峰:tailing peak對
35、稱因子:symmetry factor,fs保留時間:retention time保留體積:retention volume死時間:dead time調整保留時間:asjusted retention time半峰寬:peak width at half height,W1/2 or Y1/2峰寬:peak width,W等溫線:isotherm理論塔板高度:height equivalent to atheoretical plate化學鍵合相:chemically bonded phase丁二酸二乙二醇聚酯:polydiethylene glycol succinate,PDEGS,DEG
36、S高分子多孔微球:GDX苯乙烯:STY乙基乙烯苯:EST二乙烯苯:DVB涂壁毛細管柱:wall coated open tubular column,WCOT載體涂層毛細管柱:supprot coated open tubular column,SCOT熱導檢測器:thermal conductivity detector,TCD氫焰離子化檢測器:hydrogen flame ionization detector,FID電子捕獲檢測器:electron capture detector,ECD噪聲:noise,N漂移:drift,d靈敏度:sensitivity檢測限(敏感度):detectability,D,M分離度:resolution歸一化法:normalization method外標法:external standardization第二十一章高效液相色譜法高效液相色譜法:high performance liquid chromatography,HPLC高速液相色譜法:high speed LC,HSLC高壓液相色譜法:high pressure LC,HPLC高分辨液相色譜
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