1、Bok-Hee Kim (金福熙) Division of New Materials Engineering (新素材工學(xué)部) Chonbuk National University (全北大學(xué)校),Solid Oxide Fuel Cell development at Ceramic Synthesis Lab of CBNU,http:/ceramic.chonbuk.ac.kr,September, 2009,Contents,Introduction to Chonbuk National University Introduction to Synthetic Ceramic L

2、aboratory Introduction to Researches - Part 1 : Synthesis of ceramic powder - Part 2. SOFC Materials - Part 3 : International Collaboration with ARC(Canada),Personal Information,Educational Experiences: Mar., 1971 Feb., 1976 : Hanyang University., BS., Inorganic Materials Eng. Sept., 1979 Oct., 1980

3、 : Hanyang University, MS., Inorganic Materials Eng. Sept., 1981 Aug., 1985 : Hanyang University, Ph. D., Inorganic Materials Eng.,Employment Experiences: Feb., 2007 Present : Director of Hydrogen & Fuel Cell Research Center May, 1987 Present : Assistant Professor, Associate Professor, Professor Jul

4、y, 2004 June, 2006 : Director of Division of Advanced Materials Engineering July, 2002 Aug., 2003 : Visiting Professor in Rochester Institute of Technology Mar., 1998 Feb., 2000 : Director of Research Institute of Advanced Materials Development Dec., 1990 Dec., 1991 : Visiting Professor in Tokyo Ins

5、titute of Technology Oct., 1, 1982 Sept.,1983 : researcher in Tokyo Institute of Technology,Famous for foods, painting, writing and Korean traditional opera from the old time. (Wide agricultural field Much rice),Chonbuk Province,South Korea : 9 provinces and one special city (Seoul),* 4 national par

6、ks * Capital : Chonju * Chonbuk National University,One big national university in each province,Introduction to Chonbuk National University,Chonju-city, Established at 1952 One of the 10 biggest National Universities The number of undergraduate students : 19,000 The number of graduate students : 4,

7、000 The number of professor : 1000(total including all staff : 1400) Area : 2,926,215 m2 (Total Area : 23,574,312 m2 including Agricultural Experimental Field) 12 Colleges : Engineering, Agriculture & life Science, Arts, Commerce, Education, Human Ecology, Humanities, Law, Natural Sciences, Social S

8、ciences, Veterinary Medicine 3 Schools : Dentistry, Medical and Law,Chonbuk National University,Main building of Chonbuk National University,* Sisterhood Relationship between Wuhan University of Technology and Chonbuk National University,Main gate of Chonbuk National University,View in Spring from t

9、he main gate,Introduction to College of Engineering,The number of Professors : 220 The number of Students : 5,000 7 Divisions and 10 Departments Division of Mechanical System Engineering Division of Mechanical design Engineering Division of Biomedical Engineering Division of Advance Materials Engine

10、ering -Dept. of Metallurgical Eng. -Dept. of Electronic Materials Eng. -Information Materials Science Eng. Division of Electronics & Information Engineering -Dept. of Electrical -Dept. of Electronics Eng. -Dept. of Computer Eng. Division of Chemical Engineering Division of Applying System Engineerin

11、g -Dept. of Industrial electrical Eng. -Dept. of Information Eng. -Dept. of Social Basis Eng. -Dept. of Electronic Communication Eng., Dept. of Environmental Eng. Dept. of Mineral Resource & Energy Eng. Dept. of Civil Eng. Dept. of Industrial & Information System Eng. Dept. of Textile Eng. Dept. of

12、PolymerNano Science Eng. Dept. of Mechanical Eng. Dept. of Architecture Eng. Dept. of Urban Eng. Dept. of Aerospace Eng.,Main building of Engineering,Introduction to Division of Advanced Materials Engineering, 3 Departments Electronic Materials Engineering Information Materials Science & Engineering

13、 Metallurgical System Engineering, The number of students : 500 The number of professors : 21,5th Engineering building,4th Engineering building,Ph.D. course student : 1. Chen Min(陳旻) : SOFC Materials(Anode, Cathode & electrolyte) Fabrication of SOFC Single Cell 2. Sang-Hee Kim : SOFC Materials(Porou

14、s ceramic supporter for SOFC) Solar Cell Fabrication M.S. course students : 1. Byung-Hwa Moon : SOFC Cathode Materials (LNO-LSCF) 2. Kang-Sik Lee : SOFC Material(Ni,Cu)-(Ce,Zr)O2 Researcher : 1. Eun-Sil Choi : SOFC Material (LaSr2Fe3-xCryO9-(x=0.0 -1.0),Members of Synthetic Ceramic Laboratory,2008.

15、6. summer Lab Tour(Buan),2008. 01. 13.,Tape casting,CIP,Furnace,LSMCVD,Glove box,USP,HP4194,Chamber ( -70-150),Fuel cell tester,2nd battery cycler,Spin coater,Tape casting,HP4192A,pH meter,Spin coater,RTA,Freeze dryer,Centrifugal separator,HT Microscope,Pure water,Planetary mill,Lab Instru- ments,Si

16、ngle cell testing system,Past Works,Synthesis and Electrochemical Properties of Li 2nd Battery Cathode Materials by Emulsion Method(1997-2004) LiNiO2, LiNi1-xMxO2 (M : Al, Zn, Ti, Ga, In, Tl) LiMn2O4, LiMxMn2-xO4 (M : Ni, Fe) Synthesis of Thin Film Using LSMCVD Method (International Co-work with Tok

17、yo Institute of Technology, 1998-2002) TiO2, PbTiO3, (Na0.5Bi0.5)TiO3, Ti1-xNxO2 MLCC(Multi-Layered Ceramic Capacitor) Using Low-sinterable Materials (Co-work with Samsung Electric Company, 1997-2001) PMN-PT-PNW System CaZrO3-CaTiO3(SrTiO3)-TiO2 System Synthesis and Electrical Properties of Lead Fre

18、e Piezoelectric Materials-BNT (Co-work with Professor Xu Qing, 2004-2006) Development of Micro-SOFC Fuel Cell (International Co-work between ARC(CANADA)- Jeonbuk Province-Chonbuk National University) (2007-2008),Present Works,Micro-tubular SOFC (100W) Microwave dielectrics(?),Effect of substitution

19、on mixed conducting properties of La2NiO4+ (International co-work with Professor Xu Qing, 2009-1010) SOFC Materials(Supported by Korean Research Foundation, 2009-2012) Anode : Ni-YSZ, Ni-SDC, (Ni,Cu)-Ce1-xZrxO2(for CH4 gas) Electrolyte : YSZ, SDC, GDC Cathode : LSCF, LSCF-LNO Porous Ceramic Substrat

20、e for SOFC SOFC Single Cell (Coin-type),Futures Works,2007 1. The effect of oxygen pressure on the synthesis of LiNiO2, Solid State Phenomena vol. 124-126 (2007)104 2. Electrical properties of (1-x) (Bi0.5Na0.5)TiO3-xBaTiO3 synthesized by emulsion method, Ceram. Inter. 33 (2) (2007) 447 3. Fabricati

21、on and Characterization of a hydroxyapatite nanopowder by ultrasonic spray pyrolysis with salt- assisted decomposition, Materials Science and Engineering A 449-451 (2007) 821 4. Electrochemical Properties of LiNi1-yAlyO2 Cathode Materials Synthesized by Emulsion Method, J.Ceram. Soc. of Japan, 115(4

22、) (2007) 245 5. Electrochemical properties of LiNiO2 cathode material synthesized by the emulsion method, Ceram. Inter. 33(5) (2007) 837 6. Electriochemical properties of LiNi1-(x+y)AlxZnyO2 cathode materials synthesized by emulsion method, J. Ceram. Processing Research. 8(3) (2007) 167 7. Structure

23、, Piezoelectric and Ferroelectric Properties of La2O3 Added (Na0.5Bi0.5)0.93 Ba0.07TiO3 Lead-Free Ceramics, Ferroelectrics, 358 (2007) 123,Recent Publication(2007-present),2008 1. Structure and electrical properties of (Na0.5Bi0.5)1xBaxTiO3 piezoelectric ceramics, J. Europ. Ceram. Soc. 28 (2008) 843

24、 2. Effect of CoO additive on structure and electrical properties of (Na0.5Bi0.5)0.93Ba0.07TiO3 ceramics prepared by the citrate method, Acta Materialia 56 (2008) 642 3. Effect of CeO2 addition on structure and electrical properties of (Na0.5Bi0.5)0.93Ba0.07TiO3 ceramics prepared by citric method, M

25、aterials Research Bulletin 43 (2008) 1420 4. TiO2-xNx thin films synthesized by liquid spray mist chemical vapor deposition (LSMCVD) and their photoelectrical properties, J. Ceram. Processing Research. 9(1) (2008) 38 5. Structure, Electrical Conducting and Thermal Expansion Properties of Ln0.6Sr0.4C

26、o0.8Fe0.2O3 (Ln=La, Pr, Nd, Sm) Ceramics, Journal of Wuhan University of Technology-Mater. Sci. Ed. 23(3) (2008) 235 6. Effect of Ln2O3 (Ln = La, Pr, Eu, Gd) addition on structure and electrical properties of (Na0.5Bi0.5)0.93Ba0.07TiO3 ceramics, J. Alloys and Compounds 463 (2008) 275 7. Synthesis an

27、d performances of NiSDC cermets for IT-SOFC anode, J. Europ. Ceram. Soc. 28 (2008) 2947 8. Structure and Electrical Properties of (Na0.5Bi0.5)0.94Ba0.06TiO3 Ceramic with 0.5 wt% of MnO, J. Wuhan University of Technology-Mater. Sci. Ed. 23(4)2008 499 9. Structure and electrical properties of (Na0.5Bi

28、0.5)0.94Ba0.06TiO3 ceramics made by a citrate method, J. Electrocramics 21 (2008) 617,2009 1. Effect of bismuth excess on ferroelectric and piezoelectric properties of a (Na0.5Bi0.5)TiO3BaTiO3 composition near the morphotropic phase boundary, J. Alloys and Compounds 471 (2009) 310 2. Preparation and

29、 electrochemical properties of Ni.SDC thin films for IT-SOFC anode, J. Membrane Science 334 (2009) 138 3. Synthesis and electrical properties of Ce0.8Sm0.2O1.9 ceramics for IT-SOFC electrolytes by urea- combustion technique, Ceramics International 35 (2009) 1335 4. Electrode properties of porous La2

30、NiO4+ layers screen-printed on a Ce0.8Sm0.2O2- electrolyte, Journal of Ceramic Processing Research. 10(2) (2009) 202 5. The properties of a low expansion glass ceramics of Li2O-Al2O3-SiO2 system, J. Kor. Crystal Growth and Crystal Tech., 19(2) (2009) 79 6. Effect of Ni content on the microstructure

31、and electrochemical properties of Ni-SDC anodes for IT- SOFC, Electrochemica Acta Aug. 2009(Submit and review),International Collaboration(國(guó)際交流 ),International Co-Work (國(guó)際共同硏究) 1. International Co-work between Korea-China (韓中 國(guó)際 共同硏究) (2009. 6 2010. 5) Professor Xu Qing(Wuhan University of Technolog

32、y, Division of Material Science) “Effect of substitution on mixed conducting properties of La2NiO4+ (La2NiO4+ 混合 電導(dǎo)性 置換效果)” 2. International Co-work between Korea-China (韓中 國(guó)際 共同硏究) (2004. 7 2006. 6) Professor Xu Qing(Wuhan University of Technology, Division of Material Science) “Development of lead-free