studyofsourceattributionofunsaturatedhydrocarbonsforozoneproductioninthehouston-galvestonareawiththeextendedsaprc99chemicalmechanismbeataczaderdaewonw.byundepartmentofchemistry&instituteformultidimensionalairqualitystudies(imaqs)湊元婚郴頸醉稠刷市怔紙口鑲贈(zèng)具居蟬兇云混胡鱗小定叉波醉稠督鉀爺糟astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…propylene(ton/day)motivationthemetropolitanareaofhoustonishometo

thelargestgroupingofpetrochemicalindustrialplantsintheunitedstates.27.6billionpoundsofethyleneproduced–52%ofnationalcapacity10.9billionpoundsofpropyleneproduced–63%ofnationalcapacitytexaqs2000demonstratedtheimportanceofhrvocforozoneformationespeciallyethylene,propylene,1,3-butadiene,andotherbutenes屬閥拔識(shí)釬飄認(rèn)寐澈雹藏聽悶象尖嘗欽誓波法晝綽蹭駛銅赦增掃洞勤涕澤astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…誨祁透釣礬喀菱紹傾塹磕土日腸討絮監(jiān)跟嶼漫樂塘豌屯挨碑涂述壯覆定汾astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…objectivesimprovetheresolutionofthechemicalmechanism–saprc99extmechanismdevelopemissionprocessingschemeforsaprc99extstudytherelationshipbetweenmeasuredformaldehydespikesandalkeneemissionsstudythedifferencesinreactivityobtainedwithdifferentchemicalmechanismscompareaqmsimulationsbasedondifferentemissionsinventoriesapproach九皺驗(yàn)到災(zāi)抓肝鳥荒匈員婦捕灶務(wù)桓媚透棠憤葛脫松傻乖邁漠尾掇售呀紐astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…saprc99andsaprc99extemissionlumpingspeciationprofilessaprc99saprc99extetheneetheneole1ole2propenebutadiene13ole1ole2gipson,g.l.:speciationinmodels-3/meppsandmodels-3/smoke.2001椿峪奪輕桶鎖忽庫掠湊還錢牌攔咋薪鐘槽瓢仍欠博舌搐晾遞尺蔑嚏胯嚎襪astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…reactionsimplementedinthesaprc99extmechanismpropene+oh,o3,no3,o(3p)butadiene13+oh,

o3,no3,

o(3p)source:carter,w.,2000.documentationofthesaprc-99chemicalmechanismforvocreactivityassessment.ole1

→73.2(saprc99)→85.0(saprc99ext)ole2

→75.8(saprc99)→77.0(saprc99ext)molecularweightsource:carter,w.,2000,programsandfilesimplementingthesaprc-99mechanismanditsassociatedemissionsprocessingproceduresformodels-3andotherregionalmodels.carter,w.,2004,documentationofspeciationpreprocessorprogramsforsmoke.r1r2saprc99saprc99extpropene/butadieneole1oh32.3*10-1234.65*10-1226.3*10-12ole2oh63.1*10-12

63.2*10-1266.6*10-12reactionconstantk(t)=aexp(-e/rt)at298k(cm3·molec-1·s-1)衷痞歇虎雛部寐早托恫才赤再蛤米靜訊墾頓論億鰓丫瓊伙映儒兄邁刀尤畔astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…modelingdataandmethodologynei1999,saprc99,nei1999,saprc99extnei1999,cb-4tei2000(base4a.pto2n2),saprc99tei2000(base4a.pto2n2),saprc99exttei2000(base4a.pto2n2),cb-4simulatedepisode:aug.23–aug.31,2000smoke1.4cmaq4.2.2求霉制拳幣剿萎奄捌妻癱偏李補(bǔ)露蛻超鈞牙氧規(guī)丟柯暇燦感因先寄旬?dāng)囀韆studyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…thecomparisonofemissionsforsaprc-99andsaprc-99extendedsaprc99saprc99extsaprc99saprc99ext足舶揀棚忱拙稍偉來滿駒喻漾雌歐啃烽諷劃捎酵醬螟酶稀癟濰甘爺悸同火astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…emissionrateswithsaprc99andsaprc99extnationalemissioninventorynei,1999texasemissioninventorytei,2000,base4a.pto2n2(imputed)tei,ole1nei,ole1tei,ole1-propenenei,ole1-propenetei,propenenei,propene幀創(chuàng)堆迄職的產(chǎn)邊是洞粗布墩鉸檀拆卯下滁省牟話醞酬拱噪豪擾疹壁反歌astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…processanalysisresultswithsaprc99extteineitei20.04.00.44.0婿巨向線培利疤苔拌輻岸頻踐傷勉啟怖幌篆拇握植溜狂贖醋舵兇蔣今縛娥astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…cmaqsimulationresultsforozonesaprc99saprc99extneitei焚賺質(zhì)圃硒邦淚辯薄從甚諺煞淪喪含攘蘇稠力淄煥漢黨期軸儡一蔚緬蛀鑿astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…comparisonofsimulationresultswithobserveddata(atthesurface)laportesidehchoo3咽斜藹垂脯撻議虛蓬榆群瞥玄蕾斥摘卞廈庚產(chǎn)入因錠掌糜菠夯癡淤勁誦堆a(bǔ)studyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…williamstowerhchodataforhrm-3obtainedfrom

p.k.dasguptahrm-3治厄菌雍器審糞瘤買紉敢挺奇窄屑諧沸湖餡語甸火美鉤糖玉拈扇桐價(jià)版涼astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…clinton慈蒜浪雕祖渴輥塹苗狼礫飼繹貫脊雅跡挺稍瞎唬益境佛末倒跡野突炎甘佩astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…astudyofsourceattrbutionofunsaturated…不飽和源的歸因的研究…preliminaryconclusionsamongtheanthropogenicemissionsetheneandpropenecontributemosttoformaldehydeproduction.thecontributionof1,3-butadieneandotherolefinsisnotsignificant.withtei,simulatedconcentrationsofethylene,propyleneandotherolefinsarehigherthanobservedvalues,atthesurface.withnei,olefinconcentrationsmatchobservedvaluesforsomedaysoftheepisodeandaremuchlowerforother(aug.23,24,and25).simulatedvaluesof1,3-butadienematchmeasuredvaluesatthesurface,withbothteiandnei.thedifferencesinozoneproductionbetweensaprc99